Enhancing the extraction rate is one of the key objectives in optimization of extraction of substances from biogenic raw materials. Ultra-fine grinding of plant raw materials (to achieve particle size less than 300 µm) is a very appealing method for increasing the extraction rate using relatively simple equipment. However, this approach often fails to yield the desired result. This study focuses on the kinetics of melanin extraction from two types of raw materials: fungus Ganoderma applanatum and buckwheat husk. Particle size is shown to be just one of the key factors. The degree of order of plant-based feedstock strongly affects the intraparticle diffusion constants and can be a parameter controlling the diffusion rate. It has been shown that there exist optimal degrees of disorder of the crystal structure of plant raw materials, which have a dome-shaped dependence pattern and allow one to increase the diffusion coefficient by several dozen times. The kinetics of melanin extraction wa... [more]

The composition of purified vanadyl porphyrins recovered from the resins of heavy oils possessing high and low vanadium contents was investigated. Vanadium content in the resins of the heavy oils under study differs by a factor of ca. 15. To recover and purify vanadyl porphyrins from the resins, extraction by N,N−dimethylformamide (DMF) with subsequent two-stage column chromatography on silica gel and sulfocationite were employed. The change of structural-group composition and content of vanadyl porphyrins in the products obtained at each stage was evaluated using Fourier IR and UV-Vis spectroscopy. Analysis of the purified vanadyl porphyrins using MALDI mass spectrometry determined distribution of their most abundant types (etio- and DPEP) and identified C27−C39 homologs for the resins possessing high vanadium content and C28−C39 homologs for the resins with low vanadium content.

Self-healing concrete has emerged as one of the prospective materials to be used in future constructions, substituting conventional concrete with the view of extending the service life of the structures. As a proof of concept, over the last several years, many studies have been executed on the effectiveness of the addition of self-healing agents on crack sealing and healing in mortar, while studies on the concrete level are still rather limited. In most cases, mix designs were not optimized regarding the properties of the fresh concrete mixture, properties of the hardened concrete and self-healing efficiency, meaning that the healing agent was just added on top of the normal mix (no adaptations of the concrete mix design for the introduction of healing agents). A comprehensive review has been conducted on the concrete mix design and the impact of healing agents (e.g., crystalline admixtures, bacteria, polymers and minerals, of which some are encapsulated in microcapsules or macrocapsul... [more]

Prostate cancer is a dominant global threat to society. It affects nearly 4000 men in South Africa annually, making it the second most threatening cancerous disease after lung cancer. A potential serological biomarker to monitor early diagnosis of prostate cancer is prostate specific antigen (PSA). We used the PSA biomarker in our work to develop an extremely sensitive electrochemical immunosensor to achieve low detection limits. The fabrication steps followed with the combination of thioglycolic acid capped osmium telluride quantum dots (TGA-OsTe2QD)-polypyrrole (PPy) nanocomposite and prostate specific antigen modified on a glassy carbon electrode. The UV-Vis signatures of TGA-OsTe2QD-PPy showed an absorption band at 262 nm which is attributed to the PPy and TGA-OsTe2QD composite. This band corresponds to the energy band gap of 4.4 and 5.4 eV. The CV responses of BSA|Ab|TGA-OsTe2QD|PPy|GCE modified electrode to prostate specific antigen (PSA) was studied within a range of 0−16 ng/mL... [more]

Solid heterogeneous rocket propellants (SHRP) containing ammonium perchlorate (AP) emit a lot of hydrogen chloride (HCl) during combustion, which poses various environmental issues and makes the detection of the rockets easier. Part of the AP can be replaced by ammonium nitrate (V) (AN), which does not lead to the production of HCl. AN is a commonly used environmentally friendly oxidizer, but it is not usually applied in SHRP due to its disadvantages. One of these disadvantages is a phase transition near room temperature, which causes the density change of AN. Three types of phase stabilized ammonium nitrate (V) (PSAN) with inorganic potassium salts were obtained in order to shift this transition into higher temperatures (above the temperature range of the storage and the usage of SHRP). The SHRP with the PSAN were obtained, and the measurements of the heat of combustion, density, hardness, the sensitivity to mechanical stimuli and the thermomechanical properties were performed. The ob... [more]

Heavy metal contamination of drinking water is a public health concern that requires the development of more efficient bioremediation techniques. Absorption technologies, including biosorption, provide opportunities for improvements to increase the diversity of target metal ions and overall binding capacity. Microorganisms are a key component in wastewater treatment plants, and they naturally bind metal ions through surface macromolecules but with limited capacity. The long-term goal of this work is to engineer capsule polymerases to synthesize molecules with novel functionalities. In previously published work, we showed that the Neisseria meningitidis serogroup W (NmW) galactose−sialic acid (Gal−NeuNAc) heteropolysaccharide binds lead ions effectively, thereby demonstrating the potential for its use in environmental decontamination applications. In this study, computational analysis of the NmW capsule polymerase galactosyltransferase (GT) domain was used to gain insight into how the e... [more]

The application of phase change materials (PCMs) has been verified as an effective strategy for improving energy efficiency and reducing greenhouse gas emissions. Biocomposite PCMs (Bc-PCM) exhibit large latent heat, chemical stability, and a wide temperature range. In this study, thermal conductivity improved Bc-PCM (TBc-PCM) was made via vacuum impregnation with graphene nanoplatelets (GNPs). Chemical stability analysis and thermal performance analyses of the Bc-PCM and TBc-PCM were carried out as well as building energy simulations and thermal comfort analyses. Our results show Bc-PCM showed a higher heat storage capacity and enthalpy value compared to TBc-PCM. TBc-PCM exhibited a 378% increase in thermal conductivity compared to Bc-PCM. Building energy simulation results revealed that annual heating and cooling energy consumption decreased as the thickness of the PCM layer increased. In addition, the Bc-PCM with a larger PCM capacity was more effective in reducing energy consumptio... [more]

In this study, hydrothermally produced Fe-doped Co3O4 nanostructured particles are investigated as electrocatalysts for the water-splitting process and electrode materials for supercapacitor devices. The results of the experiments demonstrated that the surface area, specific capacitance, and electrochemical performance of Co3O4 are all influenced by Fe3+ content. The FexCo3-xO4 with x = 1 sample exhibits a higher BET surface (87.45 m2/g) than that of the pristine Co3O4 (59.4 m2/g). Electrochemical measurements of the electrode carried out in 3 M KOH reveal a high specific capacitance of 153 F/g at a current density of 1 A/g for x = 0.6 and 684 F/g at a 2 mV/s scan rate for x = 1.0 samples. In terms of electrocatalytic performance, the electrode (x = 1.0) displayed a low overpotential of 266 mV (at a current density of 10 mA/cm2) along with 52 mV/dec Tafel slopes in the oxygen evolution reaction. Additionally, the overpotential of 132 mV (at a current density of 10 mA/cm2) and 109 mV wi... [more]

Nanotechnology is a rapidly developing science and is applied in a variety of diagnostic and treatment technologies. Colorectal cancer is one of the deadliest human diseases, and hence, wide research is underway regarding its preventative measures. This review demonstrated that “nano” drug delivery systems have successfully transferred pharmaceutical drug particles at the nanoscale as compared to larger particles. Research has shown a higher rate of disease progression among patients who receive conventional drugs compared to those who were given nanoscale drugs. However, the behavior of the cellular components differs from the performance of larger cellular components of the same type; these differences are due to the physical interactions between the nanoparticles (NPs). The review aimed to discuss several recent research studies focused on delivering NPs for the treatment of colorectal cancer (CRC). The reviewed experiments have primarily compared the use of NPs alone or with the ad... [more]

Oily sludge (OS) contains a large number of hazardous materials, and froth flotation can achieve oil recovery and non-hazardous disposal of OS simultaneously. The influence of flotation parameters on OS treatment and the flotation mechanism were studied. OS samples were taken from Shengli Oilfield in May 2017 (OSS) and May 2020 (OST), respectively. Results showed that Na2SiO3 was the suitable flotation reagent treating OSS and OST, which could reduce the viscosity between oil and solids. Increasing flotation time, impeller speed and the ratio of liquid to OS could enhance the pulp shear effect, facilitate the formation of bubble and reduce pulp viscosity, respectively. Under the optimized parameters, the oil content of OST residue could be reduced to 1.2%, and that of OSS could be reduced to 0.6% because of OSS with low heavy oil components and wide solid particle size distribution. Orthogonal experimental results showed that the impeller speed was the most significant factor of all pa... [more]

The removal of pharmaceuticals from wastewater is critical due to their considerable risk on ecosystems and human health. Additionally, they are resistant to conventional chemical and biological remediation methods. Two-dimensional nanomaterials are a promising approach to face this challenge due to their combination of high surface areas, high electrical conductivities, and partially optical transparency. This review discusses the state-of-the-art concerning their use as adsorbents, oxidation catalysts or photocatalysts, and electrochemical catalysts for water treatment purposes. The bibliographic search bases upon academic databases including articles published until August 2021. Regarding adsorption, high removal capacities (>200 mg g−1) and short equilibrium times (<30 min) are reported for molybdenum disulfide, metal-organic frameworks, MXenes, and graphene oxide/magnetite nanocomposites, attributed to a strong adsorbate-adsorbent chemical interaction. Concerning photocatalysis... [more]

In this paper, a simple precomputing procedure is proposed to improve the numerical performance of the technological application of critical state soil models. In these models, if associated plasticity is assumed, the normalization of the stress space allows both the yield surface and the plastic components of the elastoplastic matrix to be defined as a function of a single variable. This approach facilitates their parameterization and precomputation, preventing the repetition of calculations when the boundary value problems appear at the yield surface with the calculation of plastic strain. To illustrate the scope of the procedure, its application on a modified Cam Clay model is analysed, which shows that the method allows a significant reduction of about 50% (as compared with the conventional explicit integration algorithm) in the computational time without reducing the precision. Although it is intended for critical state models in soils, the approach can be applied to other materia... [more]

The application of nanotechnology has been an important tool in the development of sustainable analytical procedures which have been developed in agreement with the principles of sustainability and green chemistry. In this sense, such materials have been widely applied in the area of food analysis providing important improvements in terms of specificity, efficiency, and simplicity. Besides, in recent years, the discovery of other innovative materials developed in the framework of green chemistry, such as deep eutectic solvents (DESs), has gained special attention from the scientific community for whom the design and successful application of sustainable strategies is a huge challenge. In this sense, the recent combination of nanomaterials and DESs have resulted in the performance of suitable approaches in the area of food sciences bringing about interesting alternatives in food analysis. The aim of this review article is to revise the application of nanomaterials combined with DESs in... [more]

For the first time, a universally applicable and methodical approach from characterization to a PAT concept for complex mixtures is conducted—exemplified on natural products extraction processes. Bearberry leaf (Arctostaphylos uva-ursi) extract is chosen as an example of a typical complex mixture of natural plant origin and generalizable in its composition. Within the quality by design (QbD) based process development the development and implementation of a concept for process analytical technology (PAT), a key enabling technology, is the next necessary step in risk and quality-based process development and operation. To obtain and provide an overview of the broad field of PAT, the development process is shown on the example of a complex multi-component plant extract. This study researches the potential of different process analytical technologies for online monitoring of different component groups and classifies their possible applications within the framework of a QbD-based process. O... [more]

The ciprofloxacin (CIP) removal ability of a Fe-Cu electrolytic material was examined with respect to pH (2−9), time (15−150 min), shaking speed (100−250 rpm), material mass (0.2−3 g/L), temperature (298, 308, 323) and initial CIP concentration (30−200 mg/L). The Fe-Cu electrolytic materials were fabricated by the chemical plating method, and Fe-C materials were mechanically mixed from iron powder and graphite. The results show that at a pH value of 3, shaking time 120 min, shaking speed 250 rpm, a mass of Fe-Cu, Fe-C material of 2 g/L and initial CIP concentration of 203.79 mg/L, the CIP removal efficiency of Fe-Cu material reached 90.25% and that of Fe-C material was 85.12%. The removal of CIP on Fe-Cu and Fe-C materials follows pseudo-first-order kinetics. The activation energy of CIP removal of Fe-Cu material is 14.93 KJ/mol and of Fe-C material is 16.87 KJ/mol. The positive ΔH proves that CIP removal is endothermic. A negative entropy of 0.239 kJ/mol and 0.235 kJ/mol (which is nea... [more]

Mesoporous Al/MCM-41 was synthesized by extracting silicon carbide sludge and granite sludge as the sources of silicon and aluminum. Different concentrations of aminosilane (2.5, 5, 7.5 vol.%) were used to reflux the grafted NH2-Al/MCM-41 with amine functional groups (NH2-Al/MCM-41). The physical and chemical characteristics were analyzed. The results confirmed that silicon carbide sludge and granite sludge can effectively synthesize Al/MCM-41 with low cost and environmental protection. Reflow grafted amine functional groups can effectively improve the surface properties of NH2-Al/MCM-41. The moisture adsorption and desorption capacity of grafted NH2-Al/MCM-41 with amine functional groups was also studied. Based on moisture adsorption and desorption capacity, the surface properties of NH2-Al/MCM-41 were studied. When 5 vol.% of NH2-Al/MCM-41 amine functional groups is added, the moisture adsorption and desorption capacity is best. When the relative humidity = 95%, the equilibrium moist... [more]

To improve the thermal stability of pectate lyase for ramie degumming, we modified the novel pectate lyase gene (pelG403) derived from the Dickeya dadantii DCE-01 high-efficiency ramie degumming strain by site-directed mutagenesis. Twelve mutants were acquired, wherein a prospective mutant (A129V) showed better enzyme activity and thermal stability. Compared with the wild type (PelG403), the specific enzyme activity and the optimal reaction temperature of A129V in the fermentation broth increased by 20.1%, and 5 °C, respectively. Under the conditions of 55 °C and pH 9.0, the weightlessness rate of ramie raw materials of A129V increased by 6.26%. Therefore, this study successfully improved the enzyme activity and heat resistance of PelG403 in an alkaline environment, which may contribute to the development of enzyme preparations and the elucidation of the mechanism for ramie bio-degumming.

The development of a new drilling fluid system with hydrate inhibition is of great significance for drilling safety in gas hydrate-bearing sediments. Considering the importance of the selection of a suitable thickener for drilling fluid systems under weak and strong driving forces, the hydrate inhibition of 0.1−0.5 wt% modified starch (MS), carboxymethylcellulose sodium (CMC), and xanthan gum (XG) aqueous solutions was studied. The applicability of these three thickeners were investigated through hydrate formation experiments, mesostructure observations, water activity tests, bubble retention observations, and rheological property tests. The results show that (1) under weak driving force, 0.3 wt% or higher concentration CMC and 0.3 wt% XG can almost completely inhibit hydrate formation due to the interactions between relatively small amounts of free water and CH4 molecules. Furthermore, the hydrate inhibition of higher XG concentrations was decreased due to their strong foam stability,... [more]

Background: Common buckwheat (Fagopyrum esculentum Moench) is an annual spring-emerging crop that is classified among the dicotyledons, due to the manner of its cultivation, use, and chemical composition of seeds. The use of buckwheat straw for energy purposes—for example, for the production of second generation bioethanol—might enable its wider application and increase the cost-effectiveness of tillage. Methods: In this study, we examined the usability of buckwheat straw for the production of bioethanol. We pretreated the raw material with ionic liquids and subsequently performed enzymatic hydrolysis and alcoholic fermentation. The obtained chemometric data were analyzed using the Partial Least Squares (PLS) regression model. PLS regression in combination with spectral analysis within the near-infrared (NIR) spectrum allowed for the rapid determination of the amount of cellulose in the raw material and also provided information on the changes taking place in its structure. Results: We... [more]

Aiming to better understand the biomass pyrolysis and gasification processes, a detailed experimental study of the mixing characteristics is conducted in a fluidized bed with binary mixtures. Rapeseed is used as biomass, and silica sand or resin as inert material. The effect of mixture composition, initial packing manner, and superficial gas velocity on the concentration distribution is investigated in a rectangular fluidized bed by means of photography and sampling methods. The results show that the mixture composition plays an important role in the axial solids profile of binary mixtures. The mixing behavior of binary mixture is dominated by the bubble movement. The axial distribution of binary mixtures becomes uniform with increasing superficial gas velocity, whilst no obvious effect of initial packing manner is observed in this study.

Solar-driven water desalination technologies are rapidly developing with various links to other renewable sources. However, the efficiency of such systems severely depends on the design parameters. The present study focused on using graphene oxide (GO) with the Φ = 0.2, 0.4 and 0.6 wt.% dispersed in paraffin, as phase-change materials (PCMs), to improve the productivity of a solar still for desalination applications. The outcomes showed that by adding more graphene oxide to paraffin, the melting temperature got reduced. Solar still with GO/paraffin showed 25% productivity improvement in comparison with the solar still with only PCM. The obtained Nusselt number during the melting time also represented that free convection heat transfer into the melted region of the solar still has been enhanced by adding dispersed GO to the PCM, compared to the base paraffin. Also, increasing the hot wall temperature augments the Nusselt number. Finally, an empirical equation was derived to correlate th... [more]

Nowadays, besides the use of conventional insulations (plastic foams and wool materials), aerogels are one of the most promising thermal insulation materials. As one of the lightest solid materials available today, aerogels are manufactured through the combination of a polymer with a solvent, forming a gel. For buildings, the fiber-reinforced types are mainly used. In this paper, the changes both in the thermal performance and the material structure of the aerogel blanket are followed after thermal annealing. The samples are put under isothermal heat treatments at 70 °C for weeks, as well as at higher temperatures (up to 210 °C) for one day. The changes in the sorption properties that result from the annealing are presented. Furthermore, the changes in the thermal conductivity are followed by a Holometrix Lambda heat flow meter. The changes in the structure and surface of the material due to the heat treatment are investigated by X-ray diffraction and with scanning electron microscopy.... [more]

Glass waste used in mortars or concretes behaves similar to cement, with resulting environmental benefits. In this light, the behavior of glass powder of various particle sizes has been analyzed as a cement replacement in mortars, in an attempt to minimize the loss of strength and durability, and maximize the amount of materials replaced. The dry density, water accessible porosity, water absorption by immersion, capillary absorption coefficient, ultrasonic pulse velocity and both compressive and flexural strengths were studied in the mortars. Furthermore, a statistical analysis of the obtained results and a greenhouse gases assessment were also performed. In view of the results obtained, glass powder of 38 microns allows up to 30% of the cement to be replaced, due to the filler effect combined with its pozzolanic activity. Moreover, it has been observed that glass powder size is one of the factors with the greatest influence among the properties of porosity, absorption and capillarity.... [more]

Waste heat recovery via Organic Rankine Cycle (ORC)-based power units represents one of the most promising solutions to counteract the effects of CO2 emissions on climate change. Nevertheless, several aspects are still limiting its development on the on-the-road transportation sector. Among these aspects, the significant variations of the conditions of the hot source (exhaust gases) are a crucial point. Therefore, the components of the ORC-based unit operate far from the design point if the main operating parameters of the plant are not suitably controlled. The maximum pressure of the cycle is one of the most important variables to be controlled for the importance it has on the effectiveness of the recovery and on safety of operation. In this paper, a wide experimental and theoretical activity was performed in order to define the operating parameters that mostly affect the maximum pressure of the recovery unit. The results showed that the mass flow rate provided by the pump and the exp... [more]

Thermal loading can induce mechanical stresses in the windings of electrical machines, especially those impregnated with epoxy resins, which is mostly the case in modern traction motors. Although designers look for cooling techniques that give better performance in terms of the power density and efficiency of the machine, several thermal cycles can lead to fatigue and the degradation of the copper insulation, epoxy and consequently the windings. In this paper, the performance of different cooling techniques has been compared based on the temperature distribution and the mechanical stress induced in the windings. Three-dimensional finite element thermo-mechanical models were built to perform the study. Two different variants of water jacket cooling, two configurations of direct coil cooling and two cases of combined water jacket and direct coil cooling methods have been considered in the paper. The results show that the combined water jacket and direct coil cooling perform the best in t... [more]