The mechanism and kinetic parameters of the interaction of the FLiNaK−CeF3 melt with water vapors and oxygen in the air atmosphere were determined using Raman and IR spectroscopy, XRD analysis, and thermodynamic modeling of processes. The presence of the 4CeF3(solution) + 6H2O (gas) + O2(gas) = 4CeO2(solid) + 12HF(gas) reaction, which disturbs the fluoride melt homogeneity, was verified in situ by Raman spectroscopy adopted for high-temperature, chemically aggressive fluoride systems. Based on the obtained spectral data, the type of the kinetic equation, order, and rate constant of the chemical reaction were determined. The concentration of cerium dioxide was found to increase linearly in time and a zero reaction order with respect to CeO2 was detected. The change in the concentration of CeO2 over time at T = 510 °C is described by the equation C = 0.085t; the reaction rate constant is 0.085 mol. %∙min−1. The obtained kinetic parameters may be used to model emergencies related with the... [more]

Microfluidics, as one of the most valuable analytical technologies of this century, has played an important role in various fields. Particularly, out-of-channel microfluidics, often referred to as open microfluidics (OMF) has recently drawn wide research attention among scholars for its great potential in convenient manual intervention. Much recent research has been geared toward bare droplets and particle-armed droplets (namely liquid marbles, LMs), which could serve as independent systems in OMF. Their versatile applications include but are not limited to nanomaterials preparation, energy harvesting, cell culture and environment monitoring. These applications are mainly attributed to the excellent independence, low reagent consumption and short reaction time of separate droplets and LMs. In addition, more operation features, such as diverse handling options, flexible controllability and high precision, further enable droplets and LMs carrying small liquid biochemical samples to be ma... [more]

Waste glass (WG), as a nonbiodegradable material, poses a threat to environmental protection. The reuse of WG as a raw material to replace cement or aggregate in concrete production is gaining attention for recycling purposes. However, the optimal proportion of WG in concrete mixtures and its particle size distribution are hard to determine. Large glass particles are prone to leading to the undesirable alkali−silica reaction (ASR) in concrete. Therefore, in this study, cement and aggregate in concrete mixtures are partially replaced by combinations of glass powder (<30 μm) and glass beads (0.2−1.7 mm), respectively. Glass concretes (GCs) containing waste glass at various replacement ratios (0, 10, 15, 20, and 30%) are prepared, and their flowability and compressive strength are evaluated and compared. Finally, steel tubes filled by ordinary concrete (OCFSTs) and steel tubes filled by glass concrete (GCFSTs) are fabricated and tested in axial compression. The test results show that t... [more]

Green hydrogen is set to become the energy carrier of the future, provided that production technologies such as electrolysis and solar water splitting can be scaled to global dimensions. Testing these hydrogen technologies on the MW scale requires the development of dedicated new test facilities for which there is no precedent. This perspective highlights the challenges to be met on the path to implementing a test facility for large-scale water electrolysis, photoelectrochemical and photocatalytic water splitting and aims to serve as a much-needed blueprint for future test facilities based on the authors’ own experience in establishing the Hydrogen Lab Leuna. Key aspects to be considered are the electricity and utility requirements of the devices under testing, the analysis of the produced H2 and O2 and the safety regulations for handling large quantities of H2. Choosing the right location is crucial not only for meeting these device requirements, but also for improving financial viabi... [more]

Conventionally accessible silicon solar cells experience two major drawbacks, such as reduced efficiency and increased fabrication costs. The prospects for the reduction in the cost of the photovoltaic form of energy conversion are bifacial solar cells. Bifacial solar cells show potential opportunity in reducing the cost of solar energy conversion when analyzed with respect to monofacial cells. The bifacial solar cells exploit sunlight occurrence on both sides of the cell more efficiently. Bifacial-based solar photovoltaic (PV) is a technology that increases the generation of electrical energy per square meter of PV module through the utilization of light absorption from the albedo. This technology can generally be categorized based on the type of solar cell material and the fabrication technique. PV devices are classified as a silicon-based, thin film, organic, and advanced nano PV. This paper takes a second look at some recent initiatives and significant issues in enhancing the effic... [more]

The constant development of the electrical engineering sector, especially in the transmission of electrical energy under high-voltage direct current (HVDC), requires research on new insulation materials and investigations of physical phenomena under ultrahigh electrical fields in solid dielectrics. One of the current problematic issues is the formation of space charge in HV insulation systems, which affects the operational electrical field distribution and can lead to faster insulation degradation. There are several problems that have to be considered before every space charge measurement, such as the attenuation and dispersion of sound waves in tested dielectric materials, reflections at the interfaces, and the spatial resolution of the measured charge profile. The spatial resolution is one of the most important technical factors of the PEA measurement stand. The spatial resolution, as it is assumed, depends on several factors, such as the width of the pulser and the pulse rise time,... [more]

The Crofer 22 APU alloy is a frequently used metallic material to manufacture interconnects in solid oxide fuel cells. However, the formation and evaporation of Cr2O3 not only increases the electrical resistance but also leads to the Cr-related degradation over the service time. In order to investigate the growth kinetics of Cr-oxide, i.e., Cr2O3, the multi-phase field model coupled with reliable CALPHAD databases is employed. The phase field simulation results are benchmarked with the predictions of Wagner’s theory. Moreover, we evidence the influence of the temperature and Cr concentration on the ferritic matrix phase and the oxygen concentration at the Cr2O3/gas interface on the growth kinetics of Cr-oxide, paving the way for further investigations of Cr-related solid oxide fuel cell degradation processes.

Naphtha is an important distillation product of crude oil, and is used as a raw material for first-generation products such as ethylene, propylene, gasoline, xylene (BTX), and others. However, due to the different sources of crude oil, differences in naphtha composition impact the quality of conversion processes. Parameters such as pressure, charge flow, and temperature need to be adjusted for conversion efficiency. This work aims to compare naphtha samples from different origins, through the analysis of distillation curve (ASTM D86), density (ASTM D4052), total sulfur (ASTM D4294), and n-paraffins, iso-paraffins, olefins, naphthene, and aromatics (PIONA, ASTM D5134). Among these parameters evaluated in naphtha, the ones that showed the greatest correlation with the type of oil and its origin was the amount of total sulfur, number of aromatics, and paraffins. The three imported evaluated naphtha presented values greater than 200 mg/kg of total sulfur, aromatics above 9%w, and paraffins... [more]

The construction industry is particularly responsible for the appearance of the earth and the environment and for its partial degradation related to climate warming through the production of cement, brick burning, and the processing of substrates for the production of building materials (lime, gypsum, polystyrene, processed materials, etc.). An important aspect of the 21st century has been the overproduction and excessive use of natural resources, including sand. The purpose of this article is to analyze the possibility of using glass sand as a substitute for quartz sand in the production of materials resulting from hydrothermal treatment (so-called silicate bricks). The article is a review of the research conducted since 2016 on laboratory tests on the modification of silicate mass with glass sand from recycled bottle glass, the properties of the mass modified in this way (hydration temperature, consistency, and humidity of the mixture), its physical and mechanical properties, and its... [more]

MXenes are progressively evolving two-dimensional (2D) materials with an expanding wide range of applications in the field of energy storage. They rank among the best electrode materials for cutting-edge energy storage systems. Energy storage device performance is greatly enhanced by MXenes and their composite materials. As technology has improved over the last several decades, the demand for high-capacity energy storage devices that are versatile, sturdy, and have cheap production costs has increased. MXene, which is based on Nb2CTx, is the most current material to emerge for energy storage applications. Nb2CTx MXene is now the most sought-after material in the 2D family due to its flexibility, high conductivity, superior electrochemical nature, superior hydrophilicity, tunable surface functional groups, great mechanical properties, and 2D layered structure. Examples include gas and biosensors, water splitting, water purification, antimicrobial coatings, electromagnetic interference s... [more]

Despite its immense natural resources, Angola struggles to significantly improve its economy to reduce poverty. Carbon emissions have been increasing over the years, even though the country plans to reduce them by 35% by 2030. This paper attempts to assess the carbon emissions of several sectors (industries, transport, services, and residences) on economic growth, intending to find a balance between environmental protection that requires carbon emissions reduction and economic development that may add to environmental degradation. The study employed time series data on GDP, CO2, CH4, and N2O covering 1971 to 2021 and ARDL and ECM models. This is the first study at the state level in Angola on the relationship between economic development and environmental sustainability considering methane and nitrous oxide emissions. Additionally, the paper assesses the responses of GDP to deviation shock of GDP, CO2, CH4, and N2O by 2032. Phillip Perron and Augmented Dickey-Fuller tests showed that a... [more]

Total organic carbon (TOC) and hydrocarbon generation potential (Pg) are essential parameters for the qualitative evaluation of source rock and the basis for evaluating hydrocarbon resources in petroliferous basins. However, there will be some deviations in evaluating hydrocarbon resources of overmature source rock by using TOC and Pg. The super-thick overmature source rock of the Early Cretaceous Laiyang Formation was found in well LK-1, the Riqingwei Basin. To accurately understand the oil and gas potential of the Riqingwei Basin, this paper conducted a systematic organic geochemical analysis of the overmature source rock of the Early Cretaceous Laiyang Formation found in well LK-1. Combined with the results of previous thermal simulation tests on hydrocarbon generation of low-maturity samples in the Jiaolai Basin, the original total organic carbon (TOC0) content of source rock in well LK-1 was recovered and the evaluation criteria of overmature source rock was established. Results:... [more]

The need to effectively control and reduce energy consumption in buildings has become a global concern, prompting an increasing number of studies on the energy efficiency of straw buildings. However, previous review articles on straw research have primarily focused on fragmented material properties such as thermal insulation and mechanical strength and have lacked a comprehensive review of straw materials in building energy efficiency, as well as a thorough analysis of the development lineage of straw building materials. To fill this research gap, this study conducted a bibliometric analysis of 338 papers on the energy efficiency of straw materials published in the WOS core database between 1992 and 2022. The study constructed and visualized multifaceted co-occurrence networks representing the research literature on the energy efficiency of straw building materials, providing a comprehensive understanding of current research efforts, development trends, hot research directions, and the... [more]

More than 25% of the total energy consumption in Finland has been produced with wood fuels. Since 2012, the share has been greater than that of oil, coal, or natural gas. Internal carbon pricing is used to manage the risks in wood procurement after wood import from Russia ended. Further, the EU announced plans to sell more carbon emission permits to fund the EU’s exit from Russian energy. To manage these challenges, a data-driven internal carbon pricing mechanism (DDICPM) has been developed for wood procurement optimization. Particularly, local changes are considered via available information about growth-based carbon sinks (GBCS). The results of the new scenario were compared to the basic national scenario that ensures carbon neutrality in forestry. The DDICPM may provide the optimum wood-procurement operations maintaining carbon neutrality in the integrated energy and material industry (IEMI). In this study, the use of DDICPM increased profitability b 16.2, 16.1, and 16.0% between ad... [more]

The geometrical configuration is one of the main factors that affect the thermoelectric performance of a device. Research on the trapezoidal thermoelectric generator (TTEG) with varied cross section is mainly based on finite element simulation and experiment. In this paper, an explicit analytical solution of the maximum output power of annular thermoelectric generators (ATEG) is proposed, which has been proved to have high accuracy. Then, the maximum output power between ATEG and TTEG is compared. Results show that, for the appropriate geometric parameter δ, the relative error of maximum output power between explicit analytical ATEG and the simulated solution of TTEG can reach the order of 10−3. When the hot end is at the a side, the high temperature and θ is 510 K and 10°, respectively. For Bi2Te3 material and PbTe material, the relative error of maximum output power between the explicit analytical and simulated solution is 0.0261% and 0.074%, respectively. Under suitable working cond... [more]

In thermal cracking and collision-induced dissociation (CID) processes, molecules/ions mainly undergo cleavage reactions. In theory, the cleavage reaction is preferred for weak bonds in both processes. The present study investigates the thermal cracking and CID behavior of polar compounds in vacuum residue. By controlling the thermal reaction temperature and collision energy, different degrees of fragmentation were achieved. The molecular composition before and after the cracking process was analyzed through electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS). There was a correlation between the reaction temperature and the collision energy for the average carbon number value. Both desulfurization and decarboxylation were also observed in two processes due to the low C-S bond energy and poor stability of carboxylic acid groups. Nevertheless, the two processes still had some differences in reaction selectivity. Polar species tended to be d... [more]

Naturally fractured reservoirs are indescribable systems to characterize and difficult to produce and forecast. For the development of such reservoirs, the role of naturally forming fractures in the different development stages needs to be recognized, especially for the pressure maintenance and enhanced oil recovery stages. Recent development in the field of naturally carbonate fractured aimed at fracture characterization, fracture modeling, and fracture network impact of fracture networks on oil recovery were reviewed. Consequently, fracture identification and characterization played pivotal roles in understanding production mechanisms by integrating multiple geosciences sources and reservoir engineering data. In addition, a realistic fracture modeling approach, such as a hybrid, can provide a more accurate representation of the behavior of the fracture and, hence, a more realistic reservoir model for reservoir production and management. In this respect, the influence of different fra... [more]

Brush seals can improve engine performance by reducing leakage. Wear models of brush seals provide methods to predict wear and leakage. However, rotor eccentricity, radial deformation, and hysteresis effect of bristles are not considered systematically in the existing models, which may lead to large errors in some cases. To investigate the influence of rotor-stator eccentricity and radial deformation on the wear process and leakage performance of brush seal, a brush seal test was planned and executed, in which the air leakage rates were measured at different testing times and operating conditions, the eccentricity and radial deformation was measured using eddy current sensors. The test results showed that the eccentricity and radial deformation significantly affected the wear behavior and leakage performance. In the theoretical research, the abrasive wear equation is adopted to describe the material loss of bristles, and a simplified description is used to express the rotor-stator ecce... [more]

The European steel industry is experiencing new challenges related to the market situation and climate policy. Experience from the period of pandemic restrictions and the effects of Russia’s armed invasion of Ukraine has given many countries a basis for including steel along with raw materials (coke, iron ore, electricity) in economic security products (CRMA). Steel is needed for economic infrastructure and construction development as well as a material for other industries (without steel, factories will not produce cars, machinery, ships, washing machines, etc.). In 2022, steelmakers faced a deepening energy crisis and economic slowdown. The market situation prompted steelmakers to impose restrictions on production volumes (worldwide production fell by 4% compared to the previous year). Despite the difficult economic situation of the steel industry (production in EU countries fell by 11% in 2022 compared to the previous year), the EU is strengthening its industrial decarbonisation pol... [more]

The increased voltage loading of transformers has led to research on improving transformers’ lifespans to meet demand. Insulation oil acts as cooling medium that can significantly affect the performance of a transformer. This paper discusses an experimental study on the influences of the doping of carbon nanotube (CNT) particles and magnetic fields on the electrical properties of mineral oil (MO). An analysis of electrical properties was conducted using AC breakdown tests, Tan Delta tests, Raman measurements, and simultaneous thermal analysis. Proper preparation was considered before starting the analysis of the electrical properties. The AC breakdown voltages before and after modification were measured. The experiment results indicated that the AC breakdown of mineral oil with a suitable amount of carbon nanotube particles (0.005 g/L) and a suitable magnetic field (0.45 T) gives the highest breakdown voltage. It was found that the proper treatment of nanofluid also greatly influences... [more]

Lightweight design is a common approach to reduce energy demand in the use stage of vehicles. The production of lightweight materials is usually associated with an increase in energy demand, so the environmental impacts of lightweight structures need to be assessed holistically using a life cycle assessment. To estimate the life cycle environmental impacts of a product in its developmental stage, for example, by life cycle engineering, future changes in relevant influencing factors must be considered. Prospective life cycle assessment provides methods for integrating future scenarios into life cycle assessment studies. However, approaches for integrating prospective life cycle assessment into product development are limited. The objective of this work is to provide the methodological foundation for integrating future scenarios of relevant influencing factors in the development of lightweight structures. The applicability of the novel methodology is demonstrated by a case study of a str... [more]

Electric vehicles (EVs) have been garnering wide attention over conventional fossil fuel-based vehicles due to the serious concerns of environmental pollution and crude oil depletion. In this article, we have conducted a systematic literature survey to explore the battery raw material supply chain, material processing, and the economy behind the commodity price appreciation. We present significant areas of concern, including resource reserves, supply, demand, geographical distribution, battery reuse, and recycling industries. Furthermore, details of the battery supply chain and its associated steps are illustrated. The authors believe the presented study will be an information cornerstone in boosting manufacturing and understanding the key components and materials required to facilitate EV battery production. Further, this study discusses the major industries, and their policies and global market share in each material category.

Aspects concerning resonance and global stability of a wind turbine blade must be carefully considered in its optimal design. In this paper, a composite wind turbine blade with an external geometry based on the NREL 5 MW model was subjected to multi-objective structural optimization considering these aspects. Four multi-objective structural optimization problems are formulated considering the blade mass, the maximum blade tip displacement, the natural frequencies of vibration, and the critical load factor as objective functions. The design variables are the number of plies, material, and fiber orientation. The design constraints are the materials’ margin of safety, the blade’s allowable tip displacement, and the minimum load factor. The blade model is submitted to the loads determined by the actuator lines theory and discretized in a finite element parameterized model using the Femap software according to geometric design variables. Among many multi-objective evolutionary algorithms av... [more]

To explore the influence of electrothermal aging on the properties of HVAC XLPE cable during its normal operation, two circuits of 110 kV XLPE cable were subjected to a combined electrothermal accelerated aging test for 180 days. The test voltage was set at 95 kV, and the test temperature was set at 90 °C. The constant temperature aging mode was adopted for one circuit, and the periodic thermal cycle aging mode was adopted for the other circuit. The dielectric property of the cable was diagnosed with dielectric spectroscopy measurement, and the thermal property was diagnosed with thermal parameters (thermal capacity and thermal resistance) measurement. Combined with Fourier infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC) measurements, morphological changes in the insulation under different electrothermal aging modes were analyzed to construct the correlation with the dielectric and thermal properties. The results show that the short-term electrothermal constant... [more]

The field of energy harvesting is expanding to power various devices, including electric vehicles, with energy derived from their surrounding environments. The unique mechanical and electrical qualities of composite materials make them ideal for energy harvesting applications, and they have shown tremendous promise in this area. Yet additional studies are needed to fully grasp the promise of composite materials for energy harvesting in electric vehicles. This article reviews composite materials used for energy harvesting in electric vehicles, discussing mechanical characteristics, electrical conductivity, thermal stability, and cost-effectiveness. As a bonus, it delves into using composites in piezoelectric, electromagnetic, and thermoelectric energy harvesters. The high strength-to-weight ratio provided by composite materials is a major benefit for energy harvesting. Especially important in electric vehicles, where saving weight means saving money at the pump and driving farther betwe... [more]