The properties of foams are often affected by environmental variables such as salt contamination. The objective of this study is to investigate the impact of salt on the drainage behavior of aqueous foams. To accomplish this objective, drainage experiments were conducted on aqueous foams. Test variables were foam quality (40−65%), and salt content (0% to 18%), and type. To investigate drainage, the foam was generated in a flow loop and trapped in a vertical test section. Then, the pressure profile in the foam column was measured using ten pressure sensors. Foam drainage is determined as a function of time using measured pressure profiles. The results show that the drainage of NaCl-containing foams decreased with foam quality, whereas the CaCl2-containing foams did not exhibit a clear trend with foam quality. The effect of salt content on foam rheology was minimal.

We synthesized CsPbBr3 perovskite nanocrystals (NCs) at different reaction temperatures and tracked their growth kinetics on the basis of their optical properties and estimated size. The energies of the absorption and fluorescence (FL) peaks with increasing reaction temperature for the CsPbBr3 perovskite NCs were tuned within the regions of 2.429−2.570 eV and 2.391−2.469 eV, respectively, depending on size of the NCs (9.9−12.5 nm). The Stokes shifts of CsPbBr3 perovskite NCs with increasing NC size decreased from 101 meV to 38 meV. The full-width at half-maximum of the FL peaks for the CdSe NCs decreased from 150 meV to 90 meV because of the improved size uniformity of the CsPbBr3 perovskite NCs. The energy spacing of CsPbBr3 perovskite NCs synthesized at various reaction temperatures was calculated from Tauc plots; this information is critical for determining the bandgap energy and enables the size of the CsPbBr3 perovskite NCs to be estimated using the effective mass approximation.

This present study was undertaken to investigate the ultrasonic delignification of switchgrass (Panicum virgatum L.) and the effects of ultrasonic irradiation on the molecular and microstructure of switchgrass. We investigated this question using response surface methodology (RSM) featuring a four-factor, three-level Box−Behnken experimental design with acoustic power (120, 180, and 240 W), solid−solvent ratio (1/25, 1/20, and 1/15 g/mL), hammer mill screen size (1.6, 3.2, and 6.4 mm), and sonication time (10, 30, and 50 min) as factors, while delignification (%) was the response variable. The native and treated switchgrass samples were further characterized through crystallinity measurements and electron microscopy. The results of lignin analysis show that the percent delignification ranged between 1.86% and 20.11%. The multivariate quadratic regression model developed was statistically significant at p < 0.05. SEM and TEM micrographs of the treated switchgrass grinds resulted in c... [more]

This article presents theoretical and experimental calculations of the minimum thickness of a compensation lip used in external gear pumps. Pumps of this type are innovative technical solutions in which circumferential backlash (clearance) compensation is used to improve their volumetric and overall efficiency. However, constructing a prototype of such a pump requires long-lasting research, and the compensation lip is its key object, due to the fact that it is an element influenced by a notch and that it operates in unfavorable conditions of strong fatigue stresses. The theoretical calculations presented in this article are based on identifying maximum stress values in a fatigue cycle and on implementing the stress failure condition and the conditions related to the required value of the fatigue safety factor. The experimental research focuses on static bending tests of the lips as well as on the fatigue loading of the lips in series of tests at increasing stress values until lip failu... [more]

Recently, the spread of smart metering infrastructures has enabled the easier collection of building-related data. It has been proven that a proper analysis of such data can bring significant benefits for the characterization of building performance and spotting valuable saving opportunities. More and more researchers worldwide are focused on the development of more robust frameworks of analysis capable of extracting from meter-level data useful information to enhance the process of energy management in buildings, for instance, by detecting inefficiencies or anomalous energy behavior during operation. This paper proposes an innovative anomaly detection and diagnosis (ADD) methodology to automatically detect at whole-building meter level anomalous energy consumption and then perform a diagnosis on the sub-loads responsible for anomalous patterns. The process consists of multiple steps combining data analytics techniques. A set of evolutionary classification trees is developed to discove... [more]

Positively charged (cetylpyridinium chloride), negatively charged (sodium dodecyl sulfate), and non-charged (polyethylene glycol) surfactants are used as potential foulant in reverse electrodialysis systems supplying seawater and river freshwater. Fouling tendency of the foulants to ion-exchange membranes is investigated in terms of the adsorption by electromigration, electrostatic attraction, and macromolecule interaction in reverse electrodialysis systems. According to theoretical prediction of fouling tendency, charged foulants in seawater streams could foul ion-exchange membranes significantly. However, the worst fouling behavior is observed when the charged foulants are present in river streams. As a result of zeta potential measurement, it is found that the Debye length of the charged foulants decreases due to the higher ionic strength of seawater streams and causes to lower net electrostatic effect. It finally results in less fouling tendency in reverse electrodialysis.

An abundance of research has been performed to understand the physics of latent thermal energy storage with phase change material. Some analytical and numerical findings have been validated by experiments, but there are few free and open-source models available to the general public for use in systems simulation and analysis. The Modelica programming language is a good avenue to make such models available, because it is object-oriented, equation-based, declarative, and acausal. These characteristics have enabling the creation of component model libraries that can be used to build larger system simulations for design analysis. The authors have previously developed a numerical framework to model phase change thermal storage and have validated model predictions with experiments. The objectives of this paper are to describe the transfer of the numerical framework to an implementation in a Modelica component model and to validate the Modelica model with data from the experiment and the orig... [more]

This paper details an experimental study that was performed to investigate the specific heat of microencapsulated phase change material (mPCM) slurry and its heat of fusion at the PCM phase change transition temperature. Six samples (mPCM slurry concentrate with the water solution of propylene glycol used as a main base liquid) were prepared. As the concentrate contains 43.0% mPCM, the actual mass fraction amounts to 8.6, 12.9, 17.2, 21.5, 25.8, and 30.1 wt%, respectively. The thermal delay method was used. Samples were cooled from 50 °C to 10 °C. A higher concentration of microcapsules caused a proportional increase in the specific heat of slurry at the main peak melting temperature. The maximum value of the specific heat changed from 9.2 to 33.7 kJ/kg for 8.6 wt%, and 30.1 wt%, respectively. The specific heat of the mPCM slurry is a constant quantity and depends on the concentration of the microcapsules. The specific heat of the slurry (PCM inside microcapsules in a liquid form) decr... [more]

In recent years, various types of installations such as floating photovoltaic (PV) and agri-voltaic systems, and BIPV (building integrated photovoltaic system) have been implemented in PV systems and, accordingly, there is a growing demand for new PV designs and materials. In particular, in order to install a PV module in a building, it is important to reduce the weight of the module. The PV module in which low-iron, tempered glass is applied to the front surface, which is generally used, has excellent electrical output and reliability characteristics; however, it is heavy. In order to reduce the weight of the PV module, it is necessary to use a film or plastic-based material, as opposed to low-iron, tempered glass, on the front surface. However, if a material other than glass is used on the front of the PV module, various problems such as reduced electrical output and reduced reliability may occur. Therefore, in this paper, a PV module using a film instead of glass as the front surfac... [more]

Electrochemical-mechanical modelling is a key issue to estimate the damage of active material, as direct measurements cannot be performed due to the particles nanoscale. The aim of this paper is to overcome the common assumptions of spherical and standalone particle, proposing a general approach that considers a parametrized particle shape and studying its influence on the mechanical stresses which arise in active material particles during battery operation. The shape considered is a set of ellipsoids with variable aspect ratio (elongation), which aims to approximate real active material particles. Active material particle is divided in two domains: non-contact domain and contact domain, whether contact with neighbouring particles affects stress distribution or not. Non-contact areas are affected by diffusion stress, caused by lithium concentration gradient inside particles. Contact areas are affected simultaneously by diffusion stress and contact stress, caused by contact with neighbo... [more]

The depth and layout of a horizontal borehole repository has the potential to offer strong isolation of nuclear waste from the surface. However, the isolation may be compromised by the borehole used to access the repository, as it could provide a direct fast-flow path transporting radionuclides from the disposal section to the accessible environment. Thus, backfilling the disposal section and sealing the access hole are considered essential engineered safety components. To analyze the importance of plugging the open space between canisters and sealing the access hole, we numerically calculate non-isothermal fluid flow and radionuclide transport through the borehole and the surrounding geosphere for a variety of scenarios, which include backfill materials with different sealing properties and configurations that potentially induce strong driving forces along both the horizontal and vertical sections of the borehole. The simulations indicate that the dose contribution of radionuclides re... [more]

Thermoacoustic devices are the systems which use acoustic power to transport heat through a stack in a resonance tube. The stack is one of the most important parts of the thermoacoustic systems. It can have different geometries, like parallel plates, circular pores, or pin arrays. However, the fabrication of stacks with regular geometries is sometimes impractical due to material and assembly costs. These problems can be solved by using stack fabricated with random and easily accessible porous materials. In this paper an experimental investigation on the thermoacoustic effect in easily accessible porous materials is presented. The measurements with the stacks were made in a standing wave device filled with air at atmospheric pressure. The reported results confirm that some of the materials with high porosity can be an alternative to a traditional stack geometries and materials.

Cooling by impinging droplets has been the subject of several studies for decades and still is, and, in the last few years, the potential heat transfer enhancement obtained thanks to nanofluids’ use has received increased interest. Indeed, the use of high thermal conductivity fluids, such as nanofluids’, is considered today as a possible way to strongly enhance this heat transfer process. This enhancement is related to several physical mechanisms. It is linked to the nanofluids’ rheology, their degree of stabilization, and how the presence of the nanoparticles impact the droplet/substrate dynamics. Although there are several articles on droplet impact dynamics and nanofluid heat transfer enhancement, there is a lack of review studies that couple these two topics. As such, this review aims to provide an analysis of the available literature dedicated to the dynamics between a single nanofluid droplet and a hot substrate, and the consequent enhancement or reduction of heat transfer. Final... [more]

This paper examines the impact of the effective stresses that develop during depletion of a faulted reservoir. The study is based on finite element modeling using 2D plane strain deformation analysis with pore pressure and elastoplastic deformation of the reservoir and sealing shale layers governed by the Drucker−Prager plasticity model. The mechanical properties and response of the rock formations were derived from triaxial test data for the sandstone reservoirs and correlation functions for the shale layers. A normal fault model and a reverse fault model were built using seismic data and interpretation of field data. The estimated tectonic in-situ stress field was transformed to the plane of the modeled geometry. Sensitivity studies were performed for uncertainties on the values of the initial horizontal stress and for the friction of the fault surfaces. It was found that the stress path during depletion is mainly controlled by the initial lateral stress ratio (LSR). The developed ef... [more]

This paper presents an algorithm applied for determining temperature distribution inside the gas turbine blade in which the external surface is coated with a protective layer. Inside the cooling channel, there is a porous material enabling heat to be transferred from the entire volume of the channel. This algorithm solves the nonlinear problem of heat conduction with the known: heat transfer coefficient on the external side of the blade surface, the temperature of gas surrounding the blade, coefficients of heat conduction of the protective coating and of the material the blade is made of as well as of the porous material inside the channel, the volumetric heat transfer coefficient for the porous material and the temperature of the air flowing through the porous material. Based on these data, the distribution of material porosity is determined in such a way that the temperature on the boundary between the protective coating and the material the blade is made of is equal to the assumed d... [more]

Rock salt is characterized by specific geomechanical and rheological properties. Layers of rock salt at depths of over 900 m cause problems with shaft lining deformation. Methods of shaft lining protection used to date (e.g., in the Sieroszowice mine) have not been effective enough. The research presents a patented and copyright protected concept of a shaft lining construction that can be used in rock masses with strong rheological properties and susceptibility to leaching. A high value of convergence in salt rock mass is a reason for serious problems with shaft lining stability. Numerous trials have been done to provide appropriate shaft lining for salt layers, especially to ensure proper geometry of shaft members and conveyance guidance. In the new shaft lining concept, the excessive rock creep into the outbreak inside the shaft diameter is removed by local and controlled leaching of the shaft cheeks by means of fresh water through a porous medium at the contact layer behind the wate... [more]

This article presents direct σDC and alternating σ(f) current conductivity measurements obtained by the frequency domain spectroscopy (FDS) method on cellulose-transformer oil−water nanoparticle composite with a moisture content of (5.0 ± 0.2)% by weight in a temperature range from 293.15 to 333.15 K with step of 8 K. The uncertainty of temperature maintenance during measurements was below ±0.01 K. The sample was prepared for testing in a manner as close as possible to the cellulose insulation moisturizing process in power transformers. For the analysis of the results obtained, a model of alternating and direct current hopping conductivity was used, based on the quantum phenomenon of electron tunneling between the potential wells and nanodrops of water. It was observed that on the d(logσ)/d(logf)-derived waveforms there was a clear low-frequency maximum, and a tendency to reach the next maximum in the high-frequency area was visible. On this basis it was established that the increase i... [more]

Hygrothermal assessment is essential to the production of healthy and energy efficient buildings. This has given rise to the demand for the development of a hygrothermal laboratory, as input data to hygrothermal modeling tools can only be sourced and validated through appropriate empirical measurements in a laboratory. These data are then used to quantify a building’s dynamic characteristic moisture transport vis-a-vis a much more comprehensive energy performance analysis through simulation. This paper discusses the methods used to establish Australia’s first hygrothermal laboratory for testing the water vapor resistivity properties of construction materials. The approach included establishing a climatically controlled hygrothermal test room with an automatic integrated system which controls heating, cooling, humidifying, and de-humidifying as required. The data acquisition for this hygrothermal test room operates with the installation of environmental sensors connected to specific and... [more]

In order to study the influence of different confining pressures on the stability and airtightness of dolomite underground gas storage, a permeability test under hydrostatic confining pressure, conventional triaxial compression test and gas−solid coupling test under triaxial compression were carried out on MTS815 test machine. During the tests, an acoustic emission (AE) monitoring system was also employed to estimate the rock damage. The experimental results showed that the relationships between permeability, porosity and hydrostatic confining pressure were exponential function and power function, respectively. Increasing confining pressure reduced the porosity and permeability of dolomite, and increased its triaxial compressive strength, but the addition of nitrogen reduced the compressive strength of dolomite by 10~30%, the higher the confining pressure, the smaller the difference. Compared with the maximum permeability under 15 MPa, confining pressure in the gas−solid coupling exper... [more]

Drying beds are a simple and economical means to dewater municipal sludge and are widely used in places with a suitable climate for air-drying. However, research-based information on drying thickness/drying depth effects on nutrient content and land size requirements for sludge drying is scarce. In this study, aerobically digested (AeD), and anaerobically digested without polymer (AnDP0) and with polymer (AnDP1) sludge types were dried in sand drying beds at 5, 10, 15, 20 and 25 cm depths in South Africa. Measured nitrogen (N) fractions and other parameters were more strongly influenced by sludge types than by drying depth. Total N content followed the order of AeD > AnDP1 > AnDP0. Polymeric material addition tended to increase total and inorganic N content and reduce the length of sludge drying period and land size requirement. The study showed that larger land size is required to dry sludge at shallower depths, even though the sludge dried more quickly. Drying sludge at 15 cm was the... [more]

Modification of a cement matrix using additives and admixtures has been a common practice for many years. The use of some mineral additives as substitutes for the cement, e.g., the siliceous fly ashes (FAs), has a positive effect on reducing the energy used in cement production. On the other hand, such activities may have negative effects due to the lowering of strength parameters of composites in early stages of curing. In order to solve this problem, over the last few years, thanks to the patented "seedings" technology, a branch of industry connected with the production of admixtures that accelerate the binding process has developed significantly. Therefore, the paper presents the results of research aimed at analyzing the parameters of FA cement matrix with the nanoadmixture containing the nanometric C-S-H seeds (nanoadmixture (NA)). By using the modern NA, an attempt was made to neutralize the negative influence of the used industrial waste on the structure of the cement matrix in... [more]

Lithium-ion batteries are currently one of the most important mobile energy storage units for portable electronics such as laptops, tablets, smartphones, etc. Their widespread application leads to the generation of large amounts of waste, so their recycling plays an important role in environmental policy. In this work, the process of leaching with sulfuric acid for the recovery of metals from spent Li-ion batteries in the presence of glutaric acid and hydrogen peroxide as reducing agents is presented. Experimental results indicate that glutaric-acid application improves the leaching performance compared to the use of just hydrogen peroxide under the same conditions. Obtained samples of leaching residues after mixed inorganic-organic leaching were characterized with Scanning Electron Microscopy, Fourier Transform Infrared Spectroscopy, and X-ray diffraction.

Metal halide perovskites nanocrystals (NCs) represent an emerging class of materials that find increasing application in optoelectronic and photovoltaic devices, thanks to their intriguing optical properties, including high absorption coefficient, high fluorescence quantum yield (PL QY) and fast charge carrier separation. However, their opening to market is still hindered by their limited reliability, due to an intrinsic structural instability and degradation of their photophysical properties upon air, moisture, and light exposure. The incorporation of perovskite NCs in polymer matrix can limit some of the NC instability issues, with advantages in film processability, device fabrication and mechanical performance, being also useful for fundamental studies. In this regard, here, nanocomposites based on polymethylmethacrylate or polystyrene embedding all-inorganic CsPbBr3 NCs have been prepared and processed in the form of flexible free-standing films. A systematic spectrofluorimetric st... [more]

In this article, we presented the results of the tests performed on three sets of samples of glass-reinforced epoxy (GRE) core rods used in alternating current (AC) composite insulators with silicone rubber housing. The objective of this examination was to test the aging resistance of the rod material when exposed to direct current (DC) high voltage. We hypothesized that the long-term effects of the electrostatic field on the GRE core rod material would lead to a gradual degradation of its mechanical properties caused by ionic current flow. Further, we hypothesized that reducing the mechanical strength of the GRE core rod would lead to the breakage of the insulator. The first group of samples was used for reference. The samples from the second group were subjected to a temperature of about 50 °C for 6000 h. The third group of samples were aged by temperature and DC high voltage for the same time. The samples were examined using the 3-point bending test, micro-hardness measurement and m... [more]

The demand for high-speed servomotors is increasing, and minimal losses in both high-speed and high-torque regions are required. Copper loss reduction in permanent magnet motors can be achieved by configuring concentrated winding, but there are more spatial harmonics compared with distributed winding. At high-speed rotation, the eddy current loss of the rotor increases, and efficiency tends to decrease. Therefore, we propose a motor in which a composite ring made from resin material mixed with magnetic powder is mounted on the stator to suppress spatial harmonics. This paper describes three characteristic motor types, namely, open-slot motors, composite-ring motors, and closed-slot motors. Spatial harmonics are reduced significantly in composite-ring motors, and rotor eddy current loss is reduced by more than 50% compared with open-slot motors. Thermal analysis suggests that the saturation temperature rise value is reduced by more than 30 K. The use of a composite ring is effective in... [more]