This study aims to elucidate the mechanism by which the ultrasonic loading of metal affects the extraction of small molecular phase substances (low molecular compounds) in tar-rich coal. Tar-rich coal samples were collected from the Huangling mining area in the southeastern Ordos Basin, China. The coal, the leaching solution of the coal, the extraction products, and the extraction residual coal samples with different metal ions loaded by ultrasound were analyzed using field emission scanning electron microscopy, pH detection, gas chromatography−mass spectrometry, a Fourier transform infrared spectrometer, and an X-ray diffractometer. The obtained results indicated that the ultrasonic loading of coal samples with different metal ions (Mn2+, Co2+, Cu2+, Fe2+, and Ni2+) promoted the extraction of small molecular phase substances in coal and increased the proportion of extracted aliphatic hydrocarbons, alkylbenzene, naphthalene, phenanthrene, and other compounds. The extraction rate of Mn2... [more]

This paper investigates the decentralized fuzzy control problems for nonlinear-state-unmeasured interconnected descriptor systems (IDSs) that utilize the observer-based-feedback approach and the proportional−derivative feedback control (PDFC) method. First of all, the IDS is represented as interconnected Takagi−Sugeno (T−S) fuzzy subsystems. These subsystems can effectively capture the dynamic behavior of the system through fuzzy rules. For the stability analysis of the system, this paper uses the free-weighing Lyapunov function (FWLF), which allows the designer to set the weight matrix, to achieve the desired control performance and design the controller more easily. Furthermore, the control problem can be transformed into a set of linear matrix inequalities (LMIs) through the Schur complement, which can be solved using convex optimization methods. Simulation results confirm the effectiveness of the proposed method in achieving the desired control objectives and ensuring system stabil... [more]

This paper proposes a high-efficiency and compact fuel cell−battery hybrid power system without DC/DC converters. Generally, fuel cells supply power to charge lithium batteries or loads using DC/DC converters. The disadvantages of a DC/DC converter are its complex design, poor efficiency, and large volume. Therefore, improvements in the volume, weight, and efficiency are the main objectives of the proposed topology, which is suitable for stable operation in power equipment. This paper proposes a novel topology without DC/DC converters for a fuel cell−battery hybrid forklift system and analyzes, discusses, and verifies it with experimental measurements. Additionally, the proposed topology uses an average charging method to charge the Li-ion battery. The dynamic response of fuel cells is slower than that of Li-ion batteries. By properly configuring the voltages of a fuel cell and a lithium battery, we propose a hybrid system that can maintain a stable output and high efficiency in differ... [more]

Titanium carbide has attracted widespread attention due to its excellent properties. This study investigates the process of carbon thermally reducing TiO2 to prepare TiC through a combination of thermodynamic analysis and experiments. The effects of temperature, TiO2/C molar ratio, and time on the phase transformation and morphology evolution of the products are investigated. The synthesis of titanium carbide involves the main reduction path of TiO2−Magnéli−Ti3O5−Ti2O3−TiCxO1−x. With the increase in reaction temperature and TiC content, the microstructure transitions from a smooth disc-like structure to a loose and porous layered structure, while the particle size decreases significantly. The carburisation rate of the reduced product is more affected by temperature, according to chemical analysis. The carburisation rate increased from 18.37% to 36.09% for 2 h−10 h of holding time at 1400 °C, and from 51.43% to 77.57% for 2 h−10 h of holding time at 1500 °C. The quantification of the ca... [more]

Electrostatic precipitators (ESP) are especially known for the efficient separation of micron and submicron particles from aerosols. Wet electrostatic precipitators are particularly suitable for highly resistive materials. Using these, particles can be directly transferred into a liquid for further processing or safer handling, which is advantageous for either hazardous or valuable materials. In this work, a wet ESP, which enables the separation of highly resistive particles into a heated liquid, was designed and investigated. To do this, spray-dried drug particles were embedded in a molten sugar alcohol to enhance the drug dissolution rate. After cooling, the solidified product showed advantageous properties such as a high drug dissolution rate and easy handling for further processing. For the design of the wet ESP, different discharge electrode configurations were tested. A wall film served as the collection electrode, which was generated by a specially designed distributer die. A la... [more]

The research program “Engineered Artificial Minerals (EnAM)” addresses the challenge of recycling valuable elements from battery waste streams. These elements, such as lithium (Li), often migrate in the slag phase, in some cases as crystals. EnAM crystals represent concentrated reservoirs of these elements, which can only be effectively recycled if they are extracted from the slag matrix and then separated. Selective wet agglomeration is a separation process based on a three-phase system and is often used in coal and ore processing. The produced agglomerates in this process can be easily separated from the remaining suspension. The precise quantification of the wetting properties and adhesion strength between suspended particles and binding liquid droplets is a scientific challenge. An accurate technique suitable for adhesion force measurements in three-phase systems with micrometer-scale particles is Fluidic Force Microscopy (FluidFM®). An experimental setup with optical control is be... [more]

In this study, the effects of ultrasonic power, drying temperature, and slice thickness on the drying rate, chromatism, water migration law, gingerol content, flavor, and antioxidant activity of ginger were investigated by using a direct-contact ultrasound and far infrared combined drying technology. The results showed that compared with single far infrared drying, direct-contact ultrasound and far infrared combined drying accelerated the free water migration rate of ginger (7.1~38.1%), shortened the drying time (from 280 min to 160 min), reduced the loss of volatile components in ginger, and significantly increased the antioxidant activity of ginger (p < 0.05). Furthermore, after ultrasound intervention, the gingerol content decreased in slices of 4 mm thickness (0.1226 ± 0.0189 mg/g to 0.1177 ± 0.0837 mg/g) but increased in slices of 6 mm thickness (0.1104 ± 0.0162 mg/g to 0.1268 ± 0.0112 mg/g). This drying technology has a certain reference significance for the drying process of... [more]

A pumping-while-tripping method is proposed to mitigate pressure swabs during tripping out in wells with a narrow mud density window and extended reach. In the proposed tripping-out process, the fluid circulation is started by using a special pump from a customized circulation line before tripping is initiated. During the tripping out, drilling fluid is circulated in the wellbore simultaneously while the drilling string is moving. A model to simulate the dynamic pressure changes in this process is developed based on the Navier−Stokes (N-S) equations and a damped free vibration system. The model was initially developed for Herschel−Bulkley (H-B) fluid; however, it can be applied to other fluid models by eliminating the non-existing terms. An analysis was conducted to investigate the effect of tripping velocity and circulation pumping rate on the pressure changes. The results show that pumping-while-tripping is effective in mitigating the pressure swab during tripping out, which is espec... [more]

Organobentonites have been applied for the removal of two common non-steroidal anti-inflammatory drugs, ibuprofen (IBU) and diclofenac sodium (DS), from aqueous solutions. Two surfactants, one with and the other without benzyl group (octadecyldimethylbenzylammonium chloride, ODMBA, and hexadecyltrimethylammonium bromide, HDTMA), in amounts equivalent to 50, 75, and 100% of the cation exchange capacity of bentonite were used for the preparation of organobentonites. Successful modification of bentonite was confirmed by several methods: X-ray powder diffraction (XRPD), point of the zero charge (pHPZC), determination of exchanged inorganic cations in bentonite, determination of textural properties, and scanning electron microscopy (SEM). Kinetic and thermodynamic data on the adsorption of IBU and DS showed that drug adsorption was controlled by the type and the amount of surfactant incorporated into the bentonite and by their arrangement in the interlayer space and at the surface of organo... [more]

Well deviation is a prevalent problem in deep oil and gas exploration, leading to a significant increase in drilling costs. The conventional bottom-hole assembly (BHA) anti-deviation design method does not consider the impact of the BHA structure on lateral vibration. This paper proposes an integrated BHA design method that takes into account both anti-deviation and vibration reduction. This method evaluates the BHA’s anti-deviation ability using the drilling trend angle. A negative value of the drilling trend angle indicates that the BHA can correct well deviation. A finite element linearized dynamics method is used to evaluate the lateral vibration intensity of the BHA. This method involves calculating the bending displacement caused by mass imbalance and then determining the magnitude of the bending strain energy based on this displacement. The structural factors affecting the anti-deviation ability and potential lateral vibration intensity of pendulum BHAs and bent-housing mud moto... [more]

Due to improved mechanical properties, nano-alumina (NA) addition has been considered as an interesting method to promote the performance of cement composites. To investigate the enhancing effect of NA on the fire resistance of cement-based composites, the physical and mechanical properties of NA-modified cement composites (NAMCCs) were experimentally measured after exposure to high temperatures (up to 800 °C). The variation mechanism of the physical properties of NAMCCs with increasing temperature was explored using X-ray diffraction (XRD) and scanning electron microscopy (SEM) methods. Increasing temperature leads to a gradual decrease in density and ultrasonic wave velocity but an overall increase in mass loss. The addition of NA particles effectively improved the mechanical properties of hardened cement pastes after heat treatment at all the temperatures studied. The compressive strength, elastic modulus and flexural strength all gradually decrease with increasing temperature. Comb... [more]

Backstepping-based fixed-time tracking control is proposed for a robotic arm system to solve the problem of trajectory tracking control under system uncertainties, which ensures the robotic arm system can realize stable tracking control within a fixed time independent of the initial state of the system. In addition, to address the uncertainties in the robotic arm system, a control strategy based on disturbance observer compensation is designed, which provides feed-forward compensation through the accurate estimation of the system uncertainties and enhances the system’s robustness. Finally, a two-link robotic arm model is used for simulation experiments, and the comparison results show that the control scheme designed in this article can effectively improve the robotic arm’s tracking accuracy and convergence speed.

A series of theoretical and experimental studies was carried out with the aim of a direct comparison of the thermal and microwave destruction of peat during pyrolysis. Different heating mechanisms in these processes were investigated in the framework of simulations conducted using a commercial 3D software package, CST Studio Suite, to define their specific features. Based on these simulations, identical reactors were constructed exploiting an electric element and a microwave complex as a heat source, and an experimental technique was developed that allows these processes to be correctly compared under similar conditions. Using these reactors based on different heat sources, comparative experiments on peat pyrolysis were performed, and the results of the theoretical analysis were confirmed. As a result, the advantages of microwave exposure were demonstrated to achieve a more uniform and deep fragmentation of peat, increase the reaction rate and reduce the processing time, with high ener... [more]

Due to the growth in the consumption of avocado in recent years, the amount of waste caused by avocado peel and seed has increased. Avocado waste can be transformed into valuable products such as energy, biofuels, and biological products using integrated processes in a biorefinery. This paper considers the detailed modeling, simulation, and optimization of a biorefinery for the production of phenolic compounds, bioethanol, biological xylitol, syngas, and electrical power from avocado seed and peel, using Aspen Plus in equation-oriented mode as a process simulation tool. For a biorefinery in nominal conditions, it is possible to achieve a gross profit of approximately 30×106 USD/year for capital costs of USD 31.4×106, while the combined effect of process optimization and heat integration allows reaching a gross profit of 37×106 USD/year for capital costs of USD 30.7×106. These results of the optimized plant show its potential to take advantage of avocado seed and peel in a profitable an... [more]

Reducing carbon emissions and increasing the integration of new energy sources are key steps towards achieving sustainable development. Virtual power plants (VPPs) play a significant role in enhancing grid security and promoting the transition to clean, low-carbon energy. The core equipment of the VPP, the CHP unit, utilizes a thermal engine or power station to generate electricity and useful heat simultaneously. However, the intermittent and volatile nature of renewable energy sources, as well as the “heat-driven power generation” mode of combined heat and power (CHP) units, presents contradictions that severely affect their peak-shifting capability and lead to high carbon emissions. To address these issues, a novel VPP is established by integrating traditional power plants with carbon capture and hydrogen energy storage. This approach utilizes a “hydrogen energy storage−electric boiler” decoupling method to address the operational mode of CHP, strengthens the coupling relationship be... [more]

Solar photovoltaic (PV) generation will play a crucial role in the global clean energy transition toward carbon neutrality. While the development of solar PV generation has been explored in depth, the development of high-proportion solar PV generation has yet to be discussed. Considering the back force of the constraint of achieving carbon neutrality within the specified timeframe, this paper establishes a unified, multi-dimensional, and achievable framework through which to perform a system analysis for exploring the potential risks and challenges involved in the development process of high-proportion solar PV generation and investigating possible pathways to fostering the development of high-proportion solar PV generation. The results show that the critical risks and challenges include a low conversion efficiency, poorer resource endowment, more limited land resources, a low use of rooftop resources, an increasing complexity of power system scheduling, and low public awareness. These... [more]

Three-compartment septic tanks are a prominently advocated environmentally sustainable sanitation facility in rural China. However, the comprehensive elimination efficacy and underlying mechanisms of pathogenic bacteria within septic tanks remain incompletely understood. In particular, the operational performance in low-temperature conditions has received limited attention in the existing literature. In this work, a simulation of the three-compartment septic tank treatment system was conducted under low-temperature conditions (15 °C). The operational results exemplify the synergistic interplay of volatile fatty acids (VFAs), NH3-N, and bacterial communities, culminating in a partial reduction in Enterococcus faecalis, Escherichia coli, Staphylococcus aureus, and Salmonella enteritidis, within the three-compartment septic tank. Their respective population abundances were decreased by magnitudes of 2.2, 1.3, 0.03, and 1.46 logarithmic units (copies/mL), respectively. Through the utilizat... [more]

A prevalent metal surface defect is hot-rolled iron oxide; thus, it is critical to regulate the production and growth of oxidized iron during the hot-rolling process. To analyze the influence of Si content on the growth laws of the oxidized layer in carbon steel during heating, three types of carbon steel with significant differences in Si content were selected for research on the growth laws of the oxidized layer at different heating temperatures. The production law and micromorphology of the oxidized layer were analyzed using methods such as scanning electron microscopy and thermodynamic phase diagram calculation, and an oxidation dynamic model was obtained. The predicted control values of the model are highly consistent with the measured values. This study reveals that the heating temperature significantly impacts the thickness of the oxidized layer of carbon steel. At temperatures below 500 °C, the oxidation is not evident, and the layer is thin. Between 500 °C and 900 °C, the stee... [more]

The problems of large deformations, failures, and fractures that agricultural tillage tools may encounter during the cultivation process has long been a concern in the field of agricultural machinery design and manufacturing. It is important to establish a more accurate numerical model to effectively predict tools’ plastic deformation failures and ductile fracture failures. This research develops a numerical model for predicting the plastic deformation failure and ductile fracture failure of agricultural tillage tools using the smoothed particle hydrodynamics (SPH) method and the Johnson−Cook constitutive model. The model uses the Drucker−Prager criterion to describe the elastic−plastic constitutive behavior of the soil, the von Mises criterion to describe the Johnson−Cook constitutive model of the tool, and the coupling condition with the Lennard-Jones repulsive force to describe the interaction between the tool and soil. The numerical results show that the proposed model can effectiv... [more]

The treatment of chabazite (CHA), a natural zeolite, with the alkaline hydrothermal method to improve its ion-exchange capacity is a widely adopted route by environmental scientists for the purpose of better ammonium (NH4+) removal from wastewater. This work addresses a noteworthy trend in environmental science, where researchers, impressed by the increased ion-exchange capacity achieved through alkaline hydrothermal treatment, often bypass the thorough material characterization of treated CHA. The prevalent misconception attributes the improved features solely to the parent zeolitic framework, neglecting the fact that corrosive treatments like this can induce significant alterations in the framework and those must be identified with correct nomenclature. In this work, alkaline-mediated hydrothermally treated CHA has been characterized through X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), solid-state magic-angle spinning nuclear magnetic resonance (MAS... [more]

Currently, the focus of integrated energy system scheduling research is the multi-objective’s optimized operational strategies that take into account the economic benefits, carbon emissions, and new energy consumption rates of such systems. The integration of electric trucks with battery charging and swapping capabilities, along with their corresponding battery swapping stations, into an integrated energy system can not only optimize system operation, but also reduce investment costs associated with building energy storage equipment. This study first constructs an operational model for the electric trucks, as well as an electric truck battery swapping station, of the flexible charging and discharging; then, an optimized scheduling model of an integrated energy system is proposed, including an electric truck battery swapping station and using stepped carbon trading. On the basis of meeting the charging and battery swapping needs of electric trucks and coordinating the system’s electrica... [more]

Alpha particle-emitting radiopharmaceuticals are in high demand for use in targeted alpha therapy. Ac-225 is currently produced using Th-229, but its annual production remains low, approximately 63 GBq. Previously, we produced a large amount of Ac-225 via the (n,2n) reaction in fast reactors; however, it required repetitive irradiation. In this work, we investigated a method to produce Th-229 via the (3n,x) reaction through long-term irradiation using neutrons from Pressurized Water Reactors. As target nuclides, Ra-226, which is commonly used for Ac-225 production, and Th-230, which is not widely used but is abundant, were selected. The evaluation was conducted under mixed conditions of Th-230 and Th-232. Ra-226 and Th-230 produce Th-229 (T1/2 = 7920 years) after long-term neutron irradiation. Th-229, which has a long half-life, the α-decays to produce Ra-225, and the β-decays of Ra-225 to produce Ac-225. These processes are semi-permanent owing to the long half-life of Th-229. Further... [more]

Considering energy conversion efficiency, pollution emissions, and economic benefits, combining biomass with fossil fuels in power generation facilities is a viable approach to address prevailing energy deficits and environmental challenges. This research aimed to investigate the thermodynamic and exergoeconomic performance of a novel power and cooling cogeneration system based on a natural gas−biomass dual fuel gas turbine (DFGT). In this system, a steam Rankine cycle (SRC), a single-effect absorption chiller (SEAC), and an organic Rankine cycle (ORC) are employed as bottoming cycles for the waste heat cascade utilization of the DFGT. The effects of main operating parameters on the performance criteria are examined, and multi-objective optimization is accomplished with a genetic algorithm using exergy efficiency and the sum unit cost of the product (SUCP) as the objective functions. The results demonstrate the higher energy utilization efficiency of the proposed system with the therma... [more]

FeNi films were prepared using the DC magnetron sputtering technique with an oblique deposition arrangement. Multilayers with different orientations of the magnetic anisotropy axes were obtained thanks to a rotary sample holder inside the vacuum chamber. Magnetic properties were studied using magneto−optical Kerr microscopy and a vibrating sample magnetometer. Single-layered FeNi films having thicknesses as high as 10 nm and 40 nm show in-plane uniaxial easy magnetization axes produced by the oblique incidence of incoming components of the beams. Magnetic anisotropy field for four-layered samples with orthogonal uniaxial magnetic anisotropy axes in the adjacent layers and the thickness of individual layers of 10 nm and 40 nm turned out to be less than in single-layered films. The magnetic properties peculiarities of the eight-layered sample FeNi (10 nm) × 8 obtained by rotation of the sample holder by 45° before deposition of each subsequent layer suggest the formation of a helix-like... [more]

The automotive air conditioning (AC) electromagnetic clutch plays a crucial role in accurately controlling power transmission between the engine and the compressor, ensuring the proper operation of the AC system. The aim of this paper is to provide high-quality experimental data for researchers who are interested in simulating the dynamic process of an AC electromagnetic clutch and also to assess the adaptiveness of empirical equations to describe the AC electromagnetic clutch performance that is limited in discussion in existing studies. In this study, an automotive AC electromagnetic clutch characteristic test system was employed along with an infrared (IR) camera to conduct comprehensive experimental analyses. The test system enabled the evaluation of various parameters, including the clutch torque output, compressor exhaust pressure, and temperature of the friction surface. The results revealed that the torque and exhaust pressure were closely associated with the on/off time and ro... [more]