The problem of casing deformation caused by large-scale hydraulic fracturing in shale oil wells severely restricts the efficient development of Gulong shale oil. In order to clarify the mechanism of casing deformation in shale oil wells, comprehensive analysis was conducted on engineering factors, multi-arm caliper logging, seismic attributes, and the distribution characteristics of casing deformations. This study shows that casing strength, cementing quality, and wellbore curvature are not the main controlling factors for casing deformation. Casing deformation is caused by the communication between hydraulic fractures and natural fractures during the fracturing process, which increases the fluid pressure in the natural fracture and induces shear slip, resulting in casing deformation due to shear stress. Based on the understanding of the mechanism of casing deformation in shale oil wells, two targeted casing deformation prevention and control methods are proposed. First, temporary plug... [more]

For tight reservoirs, horizontal wells and multi-stage fracturing can generate a complex fracture network that realizes economic and effective development. The volume and complexity of the fracture network are of great significance to accurately predicting the productivity of tight oil wells. In this work, a mathematical model of a multiphase flow is proposed to evaluate the stimulation effect based on the early flowback data. The model showing the early slope of the material balance time (MBT) and production balance pressure (RNP) can help estimate the effective stimulated volume of the horizontal well. The linear flow region can be determined from the slope of the log−log plot of the MBT versus RNP curve, which equals 1. The method is verified by commercial simulation software, and the calculated stimulated volume is consistent with the statistical results of simulation results. Results also show that the flow pattern of the fracture−matrix system can be judged by the slope of the fl... [more]

The utilization of data-driven methods in chemical process modeling has been extensively acknowledged due to their effectiveness. However, with the increasing complexity and variability of chemical processes, predicting and warning of anomalous conditions have become challenging. Extracting valuable features and constructing relevant warning models are critical problems that require resolution. This research proposed a novel fused method that integrates K-means density-based spatial clustering of applications with noise (DBSCAN) clustering and bi-directional long short-term memory multilayer perceptron (Bi-LSTM-MLP) to enable early warning of abnormal conditions in chemical processes. The paper applied the proposed method to analyze the early warning using actual process data from Eastman Tennessee and the atmospheric pressure reduction unit as an example. In the TE model and example, the root mean square error (RMSE) of this method is 0.006855 and 0.052546, respectively, which is quit... [more]

Energy generation using microbial fuel cells (MFC) and removing toxic metal ions is a potentially exciting new field of study as it has recently attracted a lot of interest in the scientific community. However, MFC technology is facing several challenges, including electron production and transportation. Therefore, the present work focuses on enhancing electron generation by extracting sugarcane waste. MFC was successfully operated in a batch mode for 79 days in the presence of 250 mg/L Pb2+ and Hg2+ ions. Sugarcane extract was regularly fed to it without interruption. On day 38, the maximum current density and power density were recorded, which were 86.84 mA/m2 and 3.89 mW/m2, respectively. The electrochemical data show that a sufficient voltage generation and biofilm formation produce gradually. The specific capacitance was found to be 11 × 10−4 F/g on day 79, indicating the steady growth of biofilm. On the other hand, Pb2+ and Hg2+ removal efficiencies were found to be 82% and 74.85... [more]

Tangential effusion cooling of a combustor liner has a large difference from traditional effusion cooling on a plate. In this paper, numerical simulation is carried out to study the flow field, heat transfer characteristics and the factors affecting the cooling effectiveness of tangential effusion cooling of a combustor liner. It is found that the cooling film formed by the tangential jet is distributed in a divergent “horsetail” shape and adheres tightly to the inner wall of the liner, which increases the cooling area and effectiveness. Three different tangential inlet cooling hole arrangements and their cooling efficiencies are studied, and several important parameters that affect the cooling effectiveness are summarized. Then, an improved cooling hole arrangement is proposed, and its cooling efficiency is studied and compared with those of the original three arrangements. The results show that the new arrangement significantly improves the comprehensive cooling efficiency and decrea... [more]

Energy harvesting using the piezoelectric material in the development of compact vibration energy harvesters can be used as a backup power source for wireless sensors or to fully replace the use of fossil-resource-wasting batteries and accumulators to power a device or sensor. Generally, the coefficient is used as the metric for evaluating the property in materials. Recent research reports that accurate measurement and calculation of the coefficient in materials, especially in polymers, can be challenging for various reasons. From the reviewed references, different methods, including the quasi-static, dynamic, interferometric, and acoustic methods, are discussed and compared based on the direct and indirect effect, accuracy, repeatability, frequency range, and so on. A development of an ultrasound piezoelectric transducer is conducted to estimate d33 coefficient with a reference value. The purpose of the method was mainly to measure the values of piezoelectric material in order to meas... [more]

The cooling performance of motorized spindles plays an important role in accuracy in high-speed machining. Aiming at improving the cooling performance of traditional motorized spindles, convex columns were built in the cooling channel. Based on field synergy, the effects of quadrilateral, circular and triangular convex columns on the heat transfer performance of the cooling channel were analyzed numerically. We also compared the pressure drop between the inlet and outlet under the same conditions. The results show that the cooling channels with triangular convex columns provide the best cooling effect with the smallest increase in area compared to quadrilateral convex columns and circular convex columns. The pressure drop in the cooling channels with a circular convex column is minimized. By optimizing the spacing of the convex column, the best effect was found at a spacing of 7 mm. By optimizing the angle of the top angle of the triangular column, it is found that the enhanced heat tr... [more]

Biological interactions often involve the transport of molecules, ions, or other species across biological membranes or between interacting proteins. The understanding of these transport phenomena is crucial for the development of therapies for various diseases. Atomic force microscopy is a powerful tool that has been increasingly used to study biological systems at the nano scale. The high resolution, quantitative measurements, and the ability to probe biological interactions under near-physiological conditions make AFM an attractive tool for investigating transport phenomena in biological systems. In this article, we focus on the use of AFM in the study of the transport phenomena in biological systems. We discuss the principles of AFM, its instrumentation, and its application in the study of biomolecules and biological systems. We also provide a comprehensive overview of recent articles that have utilized AFM in the study of biomarkers in biological systems.

As an efficient heat exchange component, the gravity heat pipe can effectively control the accumulated temperature inside gangue dumps and enable reuse of transferred heat. This study establishes a similar simulation experimental platform for gravity heat pipes to control gangue dumps and thermoelectric generation. The influence of wind speed on the start-up performance and isothermal performance of gravity heat pipes is analyzed, along with the impact of wind speed on their thermoelectric generation performance. Initially, the optimal working fluid height and heating height are determined, followed by a comparison and analysis of the isothermal performance, start-up performance, and thermoelectric generation performance of the gravity heat pipe under different wind speeds. The results indicate that at a wind speed of 1.0 m/s, the gravity heat pipe exhibits better start-up and isothermal performance. At a wind speed of 2.0 m/s, the thermoelectric power generation reaches its peak. In t... [more]

An analytical method with no need for laborious sample preparation before determining the total Sn in canned tomatoes by hydride generation (HG) coupled to inductively coupled plasma optical emission spectrometry (ICP OES) was developed. The ultrasound-assisted extraction with various reagents (acidic media: HCl, HNO3, CH3COOH or aqua regia and alkaline: TMAH) that could replace the traditional wet sample digestion in the presence of a concentrated HNO3-H2O2 mixture was tested and compared. Tin hydride was generated directly from the prepared sample solution in the reaction with 1% NaBH4 or via prior acidification with a 1 mol L−1 HCl. The effect of the sample pretreatment before HG-ICP OES measurements on the Sn signal was also examined. The best results were obtained with aqua regia as the extraction medium, followed by a simple two-fold dilution of the sample extract combined with the addition of L-cysteine. The developed method was characterized by a detection limit of Sn at 0.74 n... [more]

The volcanic rocks of the Es3 Formation (the third member of the Eocene Shahejie) in the Liaohe Eastern Sag can be divided into four facies and twelve subfacies. The porosity spectrum, porosity bin, variation coefficient (VC), and porosity width derived from electrical imaging log data were applied to study and characterize the heterogeneity of four facies and nine subfacies, both qualitatively and quantitatively. However, the VC and porosity width cannot be used to quantitatively classify heterogeneity when the VC is small and the porosity width is large. In the present study, the authors propose a new parameter, Pvcd = variation coefficient × porosity width. Based on this parameter, using a combination of porosity spectra, porosity bin features, VC, and porosity width, lithofacies heterogeneity is divided into three categories. The first is weak heterogeneity, which has a Pvcd < 1.1, a VC < 0.15, and a porosity width < 6. The second is moderate heterogeneity, which has a Pvcd 1... [more]

Aquathermolysis is a promising process for improving the quality of heavy oil under reservoir conditions. However, the application of catalysts during the process can significantly promote the transformation of the heavy fragments and heteroatom-containing compounds of crude oil mixtures into low-molecular-weight hydrocarbons. This research paper conducted a comparative analysis of the catalytic effectiveness of water-soluble metal salts like NiSO4 and FeSO4 in the process of aquathermolysis to upgrade heavy oil samples extracted from the Ashal’cha reservoir. The temperature of the experiment was 300 °C for a duration of 24 h. Compared to the viscosity of the native crude oil, the Fe nanoparticles contributed to a 60% reduction in viscosity. The viscosity alteration is explained by the chemical changes observed in the composition of heavy oil after catalytic (FeSO4) aquathermolysis, where the asphaltene and resin contents were altered by 7% and 17%, accordingly. Moreover, the observed... [more]

Conventionally, methanol is derived from a petroleum base and natural gas, but biomethanol is obtained from biobased sources, which can provide a good alternative for commercial methanol synthesis. The fermentation of molasses to produce biomethanol via the production of biohydrogen (H2 and CO2) was studied. Molasses concentrations of 20, 30, or 40 g/L with the addition of 0, 0.01, or 0.1 g/L of trace elements (TEs) (NiCl2 and FeSO4·7H2O) were investigated, and the proper conditions were a 30 g/L molasses solution combined with 0.01 g/L of TEs. H2/CO2 ratios of 50/50% (v/v), 60/40% (v/v), and 70/30% (v/v) with a constant feed rate of 60 g/h for CO2 conversion via methanol synthesis (MS) and the reverse water−gas shift (RWGS) reaction were studied. MS at temperatures of 170, 200, and 230 °C with a Cu/ZnO/Al2O3 catalyst and pressure of 40 barg was studied. Increasing the H2/CO2 ratio increased the maximum methanol product rate, and the maximum H2/CO2 ratio of 70/30% (v/v) resulted in met... [more]

This paper presents the results of tests on elastomer coatings based on polyurea−polyurethane formulation with increased fire parameters. Coatings modified with flame retardants: bis(phenylphosphate) resorcinol (RDP), trischloropropyl phosphate (TCPP), and aluminum hydroxide (ATH) were tested. Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA/DTG) were used to investigate the structure and thermal stability. The effectiveness of resorcinol bis(phenylphosphate) (RDP), tris chloropropyl phosphate (TCPP), and aluminum hydroxide (ATH) on heat release rate (HRR), smoke release rate (RSR), and oxygen consumption was evaluated using cone calorimetry. The cone calorimetry results were correlated with the mechanical properties of the coatings. The cone calorimetry analysis showed suitable organophosphorus flame retardant (FR) performance, significantly decreasing HRR and oxygen consumption. Additionally, 15% TCPP caused a reduction of HRR by over 50%, obtaining... [more]

The rock composition of thick-layer, coarse-grained clastic reservoirs is complex. There are large variations in granularity and poor selectivity. Reservoirs of thick-layer, coarse-grained clastic rocks are extremely heterogeneous. Current conventional parameters for quantitative characterization of reservoir heterogeneity, such as the calculation values of the permeability variation coefficient, the permeability rush coefficient, and the permeability contrast, are unbounded, have different representation angles, and the quantification degree of the characterization method is not high. This study takes the thick layer of the coarse-clastic rock reservoir developed in the western slope of the Badaowan Formation in the Mahu Depression of the Junggar Basin as an example. Through core observation, microscopic characteristics, and analysis of laboratory data, a new quantitative characterization parameter of heterogeneity is proposed, and a reservoir interpretation parameter model is establi... [more]

In the waterflooding development of fractured ultra-low permeability reservoirs, the heterogeneity is becoming increasingly serious. The development of large fracture channels leads to serious water channelling and low recovery, and the effect of conventional profile control is not ideal. This paper proposed gel foam composite profile control and flooding technology to solve the above problems. Herein, the new intelligent gel and foaming agent systems were optimized through laboratory experiments, and their performance was evaluated. The new intelligent gel system has the characteristics of low viscosity, easy preparation, good injection, slow cross-linking, high strength, and long-term effectiveness. The injection parameters were optimized, and the indoor injection scheme was formulated, that is, the optimal injection volumes of gel and foam slugs were 0.3 and 0.6 PV, respectively. The injection sequence of composite slugs was to inject gel slugs first, then foam slugs. The injection... [more]

The lack of accurate black soil simulation model parameters in the design and optimization of soil remediation equipment has led to large errors in simulation results and simulation outcomes, which to some extent restricts the development of soil remediation equipment. Accurate discrete element parameters can improve the efficiency of soil remediation equipment. To improve the reliability of the discrete element contact parameters for black soil, a set of optimal discrete element contact parameters was found that could comprehensively represent a variety of particle sizes and minimize error. In this paper, the best discrete element contact parameters were selected by using a multi-indicator total evaluation normalization method combined with the response surface method, combined with black soil solid and simulated stacking tests. First, the physical parameters of the black soil and the accumulation angle were determined. Next, Plackett−Burman tests were carried out for each grain size... [more]

During the startup process of a centrifugal pump, the vibration and noise problems caused by unsteady flow are the focus of attention, and pressure pulsation is one of the main reasons for this problem. In the current research, a special impeller with blade pressure side trimming was proposed to reduce the strong pressure pulsation phenomenon during the startup process of centrifugal pumps. This article uses numerical simulation methods to simulate three typical blade trailing edges: original trailing edge (OTE), pressure side long linear (LLPS), and pressure side short linear (SLPS), and verifies them with experimental results. The results indicate that although the head of the centrifugal pump after filing has been reduced, its efficiency has been improved to a certain extent. Thirteen monitoring points were set up near the impeller outlet circumference and volute tongue to analyze the changes in pressure pulsation, verifying that blade trimming has a significant inhibitory effect on... [more]

The significant vertical heterogeneity, variations in ground stress directions, and irregular bedding interfaces make it extremely challenging to predict fracture propagation in continental shale reservoirs. In this article, we conducted a series of triaxial laboratory experiments on continental shale outcrop rocks to investigate the effects of formation dip angle and wellbore orientation on crack propagation under horizontal well conditions. Our study revealed that fracture propagation features can be categorized into four distinct types: (1) hydraulic fractures pass through the bedding interface without activating it; (2) fractures pass through and activate the bedding interface; (3) hydraulic fractures open and penetrate the bedding interface while also generating secondary fractures; and (4) hydraulic fractures open but do not penetrate the bedding interface. We found that as the dip angle decreases, the likelihood of fractures penetrating through the bedding interface increases. C... [more]

In recent years, the discrete element method (DEM) has gradually been applied to the traditional fluidization simulation of fine particles in a micro fluidized bed (MFB). The application of DEM in the simulating fast fluidization of fine particles in MFB has not yet received attention. This article presents a drag model that relies on the surrounding environment of particles, namely the particle circumstance-dependent drag model or PCDD model. Fast fluidization in an MFB of fine particles is simulated using DEM based on the PCDD model. Simulations indicate that the local structure in an MFB exhibits particle aggregation, which is a natural property of fast fluidization, forming a structure where a continuous dilute phase and dispersed concentrated phase coexist. There exists a strong effect of solid back-mixing in an MFB, leading to relatively low outlet solid flux. The gas back-mixing effect is, however, not so distinct. The axial porosity shows a monotonically increasing distribution... [more]

This paper aims to optimize the quality characteristics of the drilling process in glass fiber-reinforced polymer (GFRP) composites. It focuses on optimizing the drilling parameters with drill point angles concerning delamination damage and energy consumption, simultaneously. The effects of drilling process parameters on machinability were analyzed by evaluating the machinability characteristics. The cutting power was modeled through drilling parameters (speed and feed), drill point angle, and laminate thickness. The response surface analysis and artificial neural networks enhanced by the particle swarm optimization algorithm were applied for modeling and evaluating the effect of process parameters on the machinability of the drilling process. The most influential parameters on machinability properties and delamination were determined by analysis of variance (ANOVA). A multi-response optimization was performed to optimize drilling process parameters for sustainable drilling quality cha... [more]

The ozonation reaction in a bubble column reactor (BCR) has been widely used in the removal of phenol from wastewater, but the phenol removal efficiency in this type of reactor is limited because of low ozone solubility and reactivity in the system. In the present study, the phenol degradation in the BCR was enhanced by using α-Al2O3 as a packing material and a ZnO nanocatalyst. The reactor diameter and height were 8 cm and 180 cm, respectively. The gas distributor was designed to include 52 holes of a 0.5 mm diameter. Also, the gas holdup, pressure drop, and bubble size were measured as a function of the superficial gas velocity (i.e., 0.5, 1, 1.5, 2, 2.5, and 3 cm/s). The evaluation of the hydrodynamic parameters provided a deeper understanding of the ozonation process through which to select the optimal operating parameters in the reactor. It was found that the best superficial gas velocity was 2.5 cm/s. A complete (100%) phenol removal was achieved for phenol concentrations of 15,... [more]

With immense potential to enhance oil recovery, CO2 has been extensively used in the exploitation of unconventional tight oil reservoirs. Significant variations are observed to occur in the oil’s composition as well as in its physical properties after interacting with CO2. To explore the impacts of oil properties on CO2 extraction efficiency, two different types of crude oil (light oil and heavy oil) are used in CO2 huff-n-puff experiments. Moreover, numerical simulation is implemented to quantitatively inspect the impacts of different influencing factors including production time, reservoir pressure and reservoir temperature on physical properties as well as on the oil composition variation of the crude oil. The findings of the experiments demonstrate that, whether for the light oil sample or for the heavy oil sample, hydrocarbon distribution becomes lighter after interacting with CO2 compared with the original state. In addition, it is also discovered that the hydrocarbon distributio... [more]

In deep coal mine strata, characterized by high ground stress and extensive fracturing, predicting the strength of fractured rock masses is crucial for stability analysis of the surrounding rock in coal mine strata. In this study, rock samples were obtained from construction sites in deep coal mine strata and intact, as well as fissured, rock specimens were prepared and subjected to triaxial compression tests. A numerical model based on the discrete element method was then established and the micro-parameters were calibrated. A total of 288 triaxial compression tests on the rock specimens under different conditions of confining pressure, loading rate, fissure dip angle, and fissure length, were conducted to obtain the triaxial compressive strength of the fractured rock specimens under different conditions. To address the limitations of traditional back propagation (BP) neural networks in solving stochastic problems, a modified BP neural network model was developed using a random factor... [more]

Fibre Metal Laminates (FMLs) are very interesting materials due to their light weight coupled with their high stiffness, high fatigue resistance, and high damage tolerance. However, the presence of the polymeric matrix in the composite layers and of polymeric adhesive at the metal/composite interface can constitute an Achille’s heel for this class of materials, especially when exposed to a hot environment or water. Therefore, in the present article, aluminium/carbon fibre FML specimens were produced, aged by considering different hydrothermal conditions, and then, subjected to mechanical testing. The End-Notched Flexure (ENF) test was considered for this activity. It was found that the first ageing stage, consisting of submersion in saltwater, was very detrimental to the specimens, while the second stage, composed of high and low temperature cycles, showed an increase in the maximum load, probably due to a post-curing effect of the resin during the higher temperatures of the ageing cyc... [more]