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Records with Subject: Energy Systems
426. LAPSE:2023.36399
A Feasibility Study on the Use of Injection Molding Systems for Mass Production of 100W Class Wind Turbine Blades
July 13, 2023 (v1)
Subject: Energy Systems
Keywords: injection molding, mass production, Moldflow, small wind turbine
A feasibility study on the mass production of a small wind turbine blade using an injection molding process was conducted. The blade was divided into three sections suitable for injection molding, and the mold was designed and analyzed using Moldflow CAE S/W. The optimal feedstock material was selected through comparison and analysis of three candidate materials. A mold was manufactured to test the injection molding process and evaluate related parameters. The resulting blade was assembled with other components, and a generator was installed to assess its durability, safety, and performance under various conditions. The results indicated the feasibility of producing a blade for a small wind turbine through injection molding, which predicted higher productivity and lower costs compared to traditional manufacturing methods that rely heavily on manual labor.
427. LAPSE:2023.36396
A Review of Third Generation Solar Cells
July 13, 2023 (v1)
Subject: Energy Systems
Keywords: dye-sensitized, organic photovoltaics, Perovskite, quantum dot, Shockley–Queisser limit, tandem solar cells, third generation
Third-generation solar cells are designed to achieve high power-conversion efficiency while being low-cost to produce. These solar cells have the ability to surpass the Shockley−Queisser limit. This review focuses on different types of third-generation solar cells such as dye-sensitized solar cells, Perovskite-based cells, organic photovoltaics, quantum dot solar cells, and tandem solar cells, a stacked form of different materials utilizing a maximum solar spectrum to achieve high power conversion efficiency. Apart from these solar cells, other third-generation technologies are also discussed, including up-conversion, down-conversion, hot-carrier, and multiple exciton. This review provides an overview of the previous work in the field, alongside an introduction to the technologies, including their working principles and components. Advancements made in the different components and improvements in performance parameters such as the fill factor, open circuit voltage, conversion efficienc... [more]
428. LAPSE:2023.36394
Operating and Thermal Efficiency Boundary Expansion of Argon Power Cycle Hydrogen Engine
July 13, 2023 (v1)
Subject: Energy Systems
Keywords: argon power cycle, indicated thermal efficiency, knock, stratified combustion, water injection
The efficiency enhancement of argon power cycle engines through theoretical means has been substantiated. However, the escalation of in-cylinder temperatures engenders abnormal combustion phenomena, impeding the augmentation of compression ratios and practical efficiency. This study presents a comprehensive investigation employing experimental and simulation techniques, aiming to extend the boundaries of thermal efficiency and operational capabilities for hydrogen-powered argon cycle engines. The impact of hydrogen direct injection, intake boost, and port water injection is evaluated in conjunction with an argon power cycle hydrogen engine. The hydrogen direct injection, particularly at an engine speed of 1000 rpm, significantly increases the indicated mean effective pressure from 0.39 MPa to 0.72 Mpa, surpassing the performance of the port hydrogen injection. Manipulating the hydrogen direct injection timing results in the formation of a stratified mixture, effectively attenuating the... [more]
429. LAPSE:2023.36392
D-Limonene as a Promising Green Solvent for the Detachment of End-of-Life Photovoltaic Solar Panels under Sonication
July 13, 2023 (v1)
Subject: Energy Systems
Keywords: D-limonene, detachment, ethylene vinyl acetate (EVA), photovoltaic solar panels, recycling, treatment
Consumption of photovoltaic solar panels is expected to increase, so the growing amount of end-of-life (EOL) solar panels will require large spaces for their disposal, which at the moment costs around 200 euros/ton. Thus, a proper treatment technique to recover secondary materials from this waste, which are mainly copper, aluminum, silicon, high-transmittance glass, and plastics, must be developed. The last three components are strongly attached to each other; hence, their detachment is necessary for recovery. To achieve this objective, a chemical route was chosen; in fact, solvent extraction is highly recommended, as it has a high separation efficiency. In this study, D-limonene as a bio-solvent was examined for detaching different components of solar panels from each other. A high efficiency for ethylene vinyl acetate (EVA) dissolution and components’ detachment under different conditions was achieved with the help of sonication power. The effects of sonication power, thermal pre-tre... [more]
430. LAPSE:2023.36376
Latest Advances in Thermal Energy Storage for Solar Plants
July 13, 2023 (v1)
Subject: Energy Systems
Keywords: solar energy plant, storage, thermal energy system
To address the growing problem of pollution and global warming, it is necessary to steer the development of innovative technologies towards systems with minimal carbon dioxide production. Thermal storage plays a crucial role in solar systems as it bridges the gap between resource availability and energy demand, thereby enhancing the economic viability of the system and ensuring energy continuity during periods of usage. Thermal energy storage methods consist of sensible heat storage, which involves storing energy using temperature differences; latent heat storage, which utilizes the latent heat of phase change materials; and thermochemical heat storage, which utilizes reversible chemical reactions through thermochemical materials. The objective of this review paper is to explore significant research contributions that focus on practical applications and scientific aspects of thermal energy storage materials and procedures. For each type of storage, different materials have been examine... [more]
431. LAPSE:2023.36369
Using Lean-and-Green Supersaturated Poly-Factorial Mini Datasets to Profile Energy Consumption Performance for an Apartment Unit
July 13, 2023 (v1)
Subject: Energy Systems
Keywords: apartment unit energy screening, energy consumption, entropic mutual information, main effect plot, partial least squares, performance improvement, supersaturated datasets
The Renovation Wave for Europe initiative aspires to materialize the progressive greening of 85−95% of the continental older building stock as part of the European Green Deal objectives to reduce emissions and energy use. To realistically predict the energy performance even for a single apartment building is a difficult problem. This is because an apartment unit is inherently a customized construction which is subject to year-round occupant use. We use a standardized energy consumption response approach to accelerate the setting-up of the problem in pertinent energy engineering terms. Nationally instituted Energy Performance Certification databases provide validated energy consumption information by taking into account an apartment unit’s specific shell characteristics along with its installed electromechanical system configuration. Such a pre-engineered framework facilitates the effect evaluation of any proposed modifications on the energy performance of a building. Treating a vast bu... [more]
432. LAPSE:2023.36360
A Review of the Efficiency Improvement of Hydraulic Turbines in Energy Recovery
July 13, 2023 (v1)
Subject: Energy Systems
Keywords: Box–Behnken design, efficiency, energy recovery optimization, hydraulic turbines, NSGA-II genetic algorithm
Turbine energy recovery is a process energy saving technology, and understanding turbine efficiency has important operational and economic benefits for the operator of a power plant. There are three main areas of research into turbine energy efficiency: the structural performance of the turbine itself, the configuration of the recovery device and the regulation of operating conditions. This paper summarizes recent research advances in hydraulic turbine energy efficiency improvement, focusing on the design factors that can affect the overall efficiency of a hydraulic turbine. To quantify the impact of these factors, this paper investigates the effects of surface roughness, flow rate, head and impeller speed on overall efficiency. Methods for optimizing improvements based on these design factors are reviewed, and two methods, the Box−Behnken Design method and the NSGA-II genetic algorithm, are described with practical examples to provide ideas for future research.
433. LAPSE:2023.36357
Numerical Simulation of Optimized Step-Wise Depressurization for Enhanced Natural Gas Hydrate Production in the Nankai Trough of Japan
July 13, 2023 (v1)
Subject: Energy Systems
Keywords: gas production, Nankai Trough, nature gas hydrate, step-wise depressurization
The utilization of natural gas hydrates as an alternative energy source has garnered significant attention due to their proven potential. Despite the successful offshore natural gas hydrate production tests, commercial exploitation has not been achieved. This study aims to enhance the understanding of gas production behavior through simulations from a single vertical well in the Nankai Trough and assess the effectiveness of the step-wise depressurization method for gas production using TOUGH + HYDRATE. The simulation results showed that the effective permeability for the water phase decreased as the hydrates were decomposed, and the invasion of the pore water from the underburden eliminated this effect. Compared with the direct depressurization method, the step-wise depressurization method significantly increased the cumulative gas production by more than 10% and mitigated the rapid generation of gas and water production during the moment of depressurization. The results also indicated... [more]
434. LAPSE:2023.36352
Steel Slag Decorated with Calcium Oxide and Cerium Oxide as a Solid Base for Effective Transesterification of Palm Oil
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: biodiesel, calcium oxide, cerium oxide, steel slag, transesterification
For further resource utilization of solid waste steel slag and the reduction in biodiesel production costs, this study used steel slag as a carrier to synthesize a CaO-CeO2/slag solid base catalyst for the effective transesterification of palm oil into fatty acid methyl esters (FAMEs). The synthesis involved a two-step impregnation of steel slag with nitrate of calcium and cerium and thermal activation at 800 °C for 180 min. Then, the catalysts’ textural, chemical, and CO2 temperature-programmed desorption properties were characterized. The catalytic activity depended highly on the ratio of Ca-Ce to steel slag mass; the CaO-CeO2/slag-0.8 catalyst showed outstanding performance. Characterization showed that the surface area and total basicity of the Ca-Ce/slag-0.8 catalyst were 3.66 m2/g and 1.289 mmol/g, respectively. The reactivity results showed that FAMEs obtained using 7 wt.% catalyst, 9:1 of methanol-to-palm-oil molar ratio, 180 min reaction duration, and 70 °C reaction temperatur... [more]
435. LAPSE:2023.36349
Active Power-Decoupling Methods for Photovoltaic-Connected Applications: An Overview
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: power decoupling, ripple-port, stacked switched capacitor, voltage capacitor active power decoupling
This study compares ripple port, stacked switched capacitor, and capacitive energy storage architectures for active power decoupling, comparing the number of components, performance, energy density, DC-link capacitor reduction, efficiency, and frequency operation to highlight their main benefits and drawbacks for single-phase grid-connected applications. The overview reveals equivalent effective energy density without electrolytic capacitors, as well as enhanced simplicity, performance, and durability, thereby providing stacked switched capacitors as an attractive power-decoupling alternative for multi-stage connected applications, based on the principle that its individual buffer capacitors absorb and deliver energy without tightly constraining their individual terminal voltages, while maintaining a narrow range voltage at the buffer DC port.
436. LAPSE:2023.36343
Research on Micromechanical Behavior of Current Collector of Lithium-Ion Batteries Battery Cathode during the Calendering Process
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: crystal plasticity, electrode calendering, stress of the current collector
Calendering is a crucial process in the manufacturing of lithium-ion battery electrodes. However, this process introduces several challenges to the current collector, including uneven stress distribution, stress concentration, and plastic pits, which ultimately impact electrode consistency and safety. It is important to note that the load exerted on the current collector during calendering cannot be determined solely through experimental means. Moreover, due to the extremely thin nature of the current collector, there is a size effect problem. To address these issues, this study establishes a lithium-ion battery cathode model based on real experimental data and conducts a numerical simulation of the calendering process. By obtaining the load applied to the current collector and incorporating it into the crystal plasticity model, we investigate the mechanical behavior of the current collector at the crystal level during calendering. The results demonstrate that the lithium battery catho... [more]
437. LAPSE:2023.36339
Study on the Internal Flow Characteristics of Long and Short Blade Runners of a 1000 MW Francis Turbine under Different Opening Conditions
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: 1000 MW Francis turbine, dynamic and static interference, long and short blade runner, pressure pulsation, vortex
The 1000 MW Francis turbine unit at the Baihetan hydropower station is the maximum capacity unit in the world at present, and it has adopted the runner type with long and short blades. For this ultra-high output Francis turbine, especially with the breakthrough runner structure, the hydraulic excitation phenomenon caused by internal dynamic and static interference is the key factor for the stability of the unit. In this study, the 1000 MW Francis turbine unit is taken as the research object, and the rated output conditions with different guide vane openings are selected for comparative analysis. The flow field structure and the pressure pulsation characteristics inside the guide vane and runner under different openings are obtained. The distribution characteristics and evolution law of the vortex in the runner under different guide vane openings are analyzed. The results show that the dynamic and static interference between the runner and the guide vane induces the local high-speed flo... [more]
438. LAPSE:2023.36332
Pd-M (M = Ni, Co) Bimetallic Catalysts with Tunable Composition for Highly Efficient Electrochemical Formic Acid Oxidation
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: bimetallic alloy, electrocatalysts, formic acid oxidation, fuel cell
Bimetallic Pd-based catalysts for formic acid oxidation (FAO) are one of the most promising anode materials for the next generation of direct formic acid fuel cells (DFAFC). It is imperative to develop a simple strategy for preparing efficient, stable, and clean nanoparticle catalysts. Herein, we prepared a series of Pd, PdNi, and PdCo nanoparticle catalysts using the nanoparticle beam composite deposition system, which revealed good catalytic activity and stability in the process of FAO. The incorporation of Ni or Co prevents the adsorption of active intermediates and the accumulation of toxic intermediates in the process of FAO. Therefore, more Pd active centers can be used to decompose formic acid directly by dehydrogenation. The results indicate that PdNi-2 (Pd0.9Ni0.1) and PdCo-3 (Pd0.89Co0.11) catalysts exhibit the optimal catalytic performance, with the mass activity of 1491.5 A g−1Pd and 1401.7 A g−1Pd, respectively, which is 2.1 and 2 times that of the pure Pd sample. By optim... [more]
439. LAPSE:2023.36330
Enhancing Power Generation Stability in Oscillating-Water-Column Wave Energy Converters through Deep-Learning-Based Time Delay Compensation
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: Artificial Intelligence, deep learning algorithm, maximum power point tracking, optimal control, oscillating-water-column wave energy converter, output power performance, rated power control, Renewable and Sustainable Energy, time delay
Oscillating-water-column wave energy converters (OWC-WECs) are gaining attention for their high energy potential and environmental friendliness. However, their irregular input energy characteristics pose challenges to achieving stable power generation, particularly due to high peak power compared to average power. This study focuses on stable rating control to enable continuous power generation in the presence of irregular wave energy. It is difficult to precisely configure the existing rated power controllers due to physical time delays; this impacts system stability and utilization. To address this, we propose a rated power controller that compensates for system time delays using a deep learning algorithm. By predicting the valve control angle in advance and analyzing the input data for angle estimation, we successfully compensate for the physical time delay. The performance of the proposed rated power controller, incorporating the deep learning algorithm, is evaluated by analyzing t... [more]
440. LAPSE:2023.36325
Investigation on the Catalytic Cracking Mechanism of CuO on Dimethyl Sulfoxide (C2H6OS) and Surface Modification Effects: Insights from Density Functional Theory Calculations
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: catalytic activity, decomposition mechanism, dimethyl sulfoxide, nano copper oxide, oil shale, pyrolysis
To explore the catalytic cracking mechanism of CuO on oil shale and the catalytic activity of surface modifications of CuO on oil shale, dimethyl sulfoxide (C2H6OS) is used as a model molecule representative of organic sulfur compounds in oil shale, and the adsorption and dissociation behaviors of C2H6OS molecules on pure and OH pre-adsorbed CuO(111) surfaces were investigated by density functional theory calculations. The results indicate that C2H6OS selectively adsorbs at the Cusub sites via the S atom and decomposes through cleavage of the C−H bond prior to the breaking of the C-S bond on both surfaces. The presence of OH on the CuO(111) surface promoted the dissociation of C2H6OS. The energy barriers of dehydrogenation and desulfurization of C2H6OS on the OH pre-adsorbed CuO(111) surface were 20.0 and 19.3 kcal/mol, respectively, which are 41% and 49% lower than those on pure surfaces. The present results provide crucial guidance for the synthesis and improvement of high-performanc... [more]
441. LAPSE:2023.36319
Design and Performance Evaluation of Liquid-Cooled Heat Dissipation Structure for Lithium Battery Module
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: analytic network process, liquid cooling heat dissipation, NCM battery, system dynamics, thermal management scheme
The current global resource shortage and environmental pollution are becoming increasingly serious, and the development of the new energy vehicle industry has become one of the important issues of the times. In this paper, a nickel−cobalt lithium manganate (NCM) battery for a pure electric vehicle is taken as the research object, a heat dissipation design simulation is carried out using COMSOL software, and a charging heat generation model of the battery pack is established. Combined with the related research on the thermal management technology of the lithium-ion battery, five liquid-cooled temperature control models are designed for thermal management, and their temperature control simulation and effect analysis are carried out. Finally, the performance evaluation system of the thermal management scheme of the lithium-ion battery pack is established based on the analytic network process (ANP) and system dynamics (SD), and the performance of the above five thermal management design mo... [more]
442. LAPSE:2023.36313
Robust Cascade MRAC for a Hybrid Grid-Connected Renewable Energy System
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: cascade model reference adaptive control, hybrid grid-connected renewable energy system, nonlinear time-varying systems, robust adaptive control
Hybrid grid-connected renewable energy systems have gained significant importance in sustainably responding to an increased electrical energy demand. These are time-varying nonlinear dynamical plants, where the value of their parameters depends on changing weather conditions and the alternating grid voltage with randomly fluctuating amplitude. This paper proposes a robust cascade MRAC for nonlinear plants representing a class of these systems, which includes n renewable energy converts and a DC/AC single-phase full bridge inverter. The proposal reduces commissioning time by avoiding linearization and knowledge of the plant parameters. Moreover, it includes specific formulas for tuning the controller parameters that decrease their adjustments based on trial and error. Finally, it uses a direct adaptive method with adaptive laws having σθ modification and an inner loop at least five times faster than the outer loop. The proposition validation includes the theoretical stability proof base... [more]
443. LAPSE:2023.36309
Recent Progress on Hydrogen-Rich Syngas Production from Coal Gasification
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: Carbon Dioxide Capture, char–CO2 gasification, coal gasification, hydrogen production
Coal gasification is recognized as the core technology of clean coal utilization that exhibits significant advantages in hydrogen-rich syngas production and CO2 emission reduction. This review briefly discusses the recent research progress on various coal gasification techniques, including conventional coal gasification (fixed bed, fluidized bed, and entrained bed gasification) and relatively new coal gasification (supercritical water gasification, plasma gasification, chemical-looping gasification, and decoupling gasification) in terms of their gasifiers, process parameters (such as coal type, temperature, pressure, gasification agents, catalysts, etc.), advantages, and challenges. The capacity and potential of hydrogen production through different coal gasification technologies are also systematically analyzed. In this regard, the decoupling gasification technology based on pyrolysis, coal char−CO2 gasification, and CO shift reaction shows remarkable features in improving comprehensi... [more]
444. LAPSE:2023.36303
Automatic Optimization of Multi-Well Multi-Stage Fracturing Treatments Combining Geomechanical Simulation, Reservoir Simulation and Intelligent Algorithm
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: automatic optimization, fracture propagation, hydraulic fracturing, reservoir simulation
Shale reserves have become an ever-increasing component of the world’s energy map. The optimal design of multi-well multi-stage fracturing (MMF) treatments is essential to the economic development of such resources. However, optimizing MMF treatments is a complex process. It requires geomechanical simulation, reservoir simulation, and automatic optimization. In this work, an integrated workflow is proposed to optimize MMF treatments in an unconventional reservoir, and the net present value (NPV) of reserves was treated as the objective function. The forward model consists of two submodels: a hydraulic fracturing model and a reservoir simulation model. The stochastic simplex approximation gradient (StoSAG) is used with the steepest ascent algorithm to maximize the NPV function. The computational results show that optimizing the fracture design can achieve a 20% higher NPV than that obtained with the field reference case. The drainage area of the optimal design is larger than that of the... [more]
445. LAPSE:2023.36295
Research on Electromagnetic Adsorption Technology Based on Composite Shaft Lining Structure
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: coal mine shaft, composite shaft lining, effective mapping point, electromagnetic adsorption, equivalent adsorption area, fitness function, safety monitoring
The working conditions and environment of coal mine shafts are intricate and special. Currently, manual inspections or fixed-point monitoring is generally applied for daily safety monitoring, and intelligent and automated inspection equipment and its supporting technologies are not available. Starting from the technical requirements of the electromagnetic adsorption device of the wall-climbing robot for safety monitoring of the coal mine shaft, based on the structural characteristics and chemical composition of the composite shaft lining of the coal mine, the fundamental structure of the electromagnetic array and the electromagnetic unit are clarified, and a multi-layer matrix simulation point overlap mapping analysis method is proposed. Based on the system modeling and simulation calculations in MATLAB software, the number and distribution law of effective mapping points between the endpoints of the electromagnetic array and the reinforced frame in the shaft lining are inferred, which... [more]
446. LAPSE:2023.36292
Formic Acid in Hydrogen: Is It Stable in a Gas Container?
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: analytical chemistry, formic acid, fuel cell electrical vehicles, gas stability, gas standards, hydrogen fuel, hydrogen quality, ISO 14687, trace analysis
Formic acid is an intermediate of the steam methane reforming process for hydrogen production. According to International Standard ISO 14687, the amount fraction level of formic acid present in the hydrogen supplied to fuel cell electric vehicles must not exceed 200 nmol·mol−1. The development of formic acid standards in hydrogen is crucial to validate the analytical results and ensure measurement reliability for the fuel cell electric vehicles industry. NPL demonstrated that these standards can be gravimetrically prepared and validated at 4 to 100 µmol·mol−1, with a shelf-life of 1 year (stability uncertainty < 7%; k = 2). Stability was not affected over 1 year or by low temperature or pressure. At sub-µmol·mol−1 level, formic acid amount fraction was found to decrease due to adsorption on the gas cylinder surface; however, it is possible to certify the formic acid amount fraction after a period of 20 days and ensure the certified value validity for 1 year with an uncertainty below 7%... [more]
447. LAPSE:2023.36286
The Influence of Interlayer on the Development of Steam Chamber in Steam Stimulation during Heavy Oil Recovery
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: cyclic steam stimulation, interlayer, preparation method, top water
Cyclic steam stimulation is an effective thermal recovery method for heavy oil recovery. The key potential mechanism is the growth of the steam chamber after steam injection. Taking the LD5X heavy oil reservoir as an example, besides the interlayer developed in this area, the top water and bottom water distribute above and below the interlayer. These factors may have adverse effects on the development of the steam chamber, thus affecting the final heavy oil exploitation. In this work, our goal is to study the effects of interlayer permeability and well−interlayer distance on CSS performance (in the presence of top and bottom water). We developed a high-temperature-resistant interlayer. Based on the simulated interlayer, the field scale model was converted into a laboratory element model through the similarity criterion. In order to quantitatively evaluate the performance of steam stimulation, a thermal detector was used to measure the dynamic growth of the steam chamber and record the... [more]
448. LAPSE:2023.36285
Evaluation of Reconstruction Potential for Low-Production Vertical Wells of CBM in the Southern Qinshui Basin
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: CBM vertical well, low production, Qinshui Basin, reconstruction potential evaluation
Production practice has shown that not all low-production coalbed methane (CBM) wells can be reconstructed into high-production wells through secondary stimulation, so it is necessary and timely to establish an evaluation index system, form an evaluation method, and evaluate the reconstruction potential of low-production wells. Based on the development practice of CBM in the southern Qinshui Basin, this paper analyzes the influencing factors of low production in vertical wells from the aspects of coal and rock reservoir conditions, drilling and completion engineering, and drainage engineering. It is proposed that the evaluation of the reconstruction potential of low-production wells should focus on the quality of CBM resources, the difficulty of CBM desorption and diffusion, and the degree of damage to coal reservoirs caused by the initial reservoir stimulation. Twelve parameters, including gas content, gas saturation, reservoir pressure gradient, critical desorption−reservoir pressure... [more]
449. LAPSE:2023.36281
Column-Hemispherical Penetration Grouting Mechanism for Newtonian Fluid Considering the Tortuosity of Porous Media
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: column-hemispherical diffusion, Newtonian fluid, penetration grouting mechanism, porous media, tortuosity effect
The intricate morphology of porous media can considerably affect the progression of penetration and the diffusion of grouting slurry. In this study, a Newtonian fluid’s refined seepage motion equation was proposed to incorporate the impact of tortuosity on the grouting process into gravel soil, and the column-hemispherical penetration grouting mechanism was analyzed using the method of theoretical analysis. Utilizing secondary-development programming techniques, a numerical simulation program was developed with COMSOL Multiphysics to model the penetration grouting mechanism of a Newtonian fluid in a column-hemispherical pattern, considering a medium’s tortuosity. The penetration grouting process of Newtonian cement into gravel soils was then simulated. Finally, the theoretical analysis, experimental values, and numerically simulated values were compared.The findings suggested that incorporating the tortuosity of porous media is more efficacious in depicting the penetration and diffusio... [more]
450. LAPSE:2023.36276
Crude Glycerol Hydrogenolysis to Bio-Propylene Glycol: Effect of Its Impurities on Activity, Selectivity and Stability
July 7, 2023 (v1)
Subject: Energy Systems
Keywords: 1,2-propylen glycol, biodiesel, crude glycerol, hydrogenolysis, nickel catalysts
The wide availability of crude glycerol and its low market price make this by-product of the biodiesel industry a promising raw material for obtaining high-value-added products through catalytic conversion processes. This work studied the effect of the composition of different industrial crude glycerol samples on the catalytic hydrogenolysis to 1,2-propylene glycol. A nickel catalyst supported on a silica−carbon composite was employed with this purpose. This catalyst proved to be active, selective to 1,2-propylene glycol and stable in the glycerol hydrogenolysis reaction in the liquid phase when analytical glycerol (99% purity) was employed. In order to determine the effect of crude glycerol composition on the activity, selectivity and stability of this catalyst, industrial crude glycerol samples were characterized by identifying and quantifying the impurities present in them (methanol, NaOH, NaCl and NaCOOH). Reaction tests were carried out with aqueous solutions of analytical glycero... [more]
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