This article presents the synthesis and sorption characteristics of novel microspheres based on 4-vinylbenzene chloride (VBCl) with divinylbenzene (DVB) or ethylene glycol dimethylacrylate (EGDMA). To confirm the chemical structure of the homo- and co-polymers attenuated total reflectance, Fourier transform infrared spectroscopy (ATR-FTIR) was used. The presence of characteristic functional groups (−OH, −CH, −CH2, C−O, C=O and C−O−C) in obtained microspheres was confirmed. Differential scanning calorimetry (DSC) analysis confirms the good thermal resistance of the polymers. The decomposition of microspheres is closely related to the chemical structure of the monomers used. DVB-derived materials decompose in one step, whereas the decomposition of EGDMA derivatives is multi-stage. Obtained polymeric microspheres were applied for auramine O (AO) basic dye removal form aqueous solutions. Equilibrium studies confirmed that the Freundlich model described the system better than Langmuir or Te... [more]

High efficiency removal of methyl orange (MO) and bromothymol blue (BT) dyes from contaminated water has been reported using magnetic mesoporous nanoparticles modified with cationic polymer brush (poly(2-methacryloyloxy)ethyl] trimethylammonium chloride solution) (Fe3O4-MSNs-PMETAC). Atom transfer radical polymerization (ATRP) was utilized to grow the polymer chains on the magnetic mesoporous silica nanoparticles. The chemical surface modifications were confirmed using IR, TGA, SEM and TEM. The results show that the obtained Fe3O4-MSNs-PMETAC materials were nearly spherical in shape with approximately 30 nm magnetic core, and silica shell thicknesses ranged from 135 to 250 nm. The adsorption performance of the material was found to be unaffected by the pH (3-9) of the media, with a removal efficiency of 100% for both dyes. The adsorption of BT and MO on the surface of Fe3O4-MSNs-PMETAC was found to follow Freundlich and Langmuir models, respectively. Since the synthesized nanocomposite... [more]

Nowadays, upcycling coal gangue into aggregates has become a popular method; nevertheless, the utilization of coal gangue fines (CGFs), a secondary waste generated during the production of coal gangue aggregates, is rarely concerned. This paper attempted to upcycle calcined CGFs at 800 °C as the partial substitution of slag to prepare alkali-activated cement (AAC). The variation in macroscopic compressive strength of AAC was studied, and the hydration mechanism of AAC was explored in depth by microstructure. AAC with CGFs shows tremendous advantages in compressive strength and hydration products. In the 10% calcined CGF content, the 3 d, 7 d, and 28 d compressive strengths of AAC displayed pronounced increases of 8%, 25%, and 13%, respectively. The study results showed that CGFs could replace the small amount of slag in AAC while providing a new theoretical guide and technical support for upcycling CGF into helpful material.

ZnAlCO3 hydrotalcite materials modified by Cu2+ ions were synthesized by the co-precipitation method according to the molar ratios of (Cu2+ + Zn2+):Al3+ as 7:3. Thus, the modified materials contain various molar ratios of Cu2+ from 0−3.5 in the samples. The synthesized materials were characterized by X-ray diffraction pattern (XRD), FT−IR, EDS, SEM, the N2 adsorption/desorption isotherm (BET), and UV−Vis DRS spectrum. The synthesized materials were characterized by a layered double hydroxide structure—such as hydrotalcite. The specific surface area BET increases slightly, corresponding to the increasing Cu2+ molar ratios, and the bandgap energy Eg decreases accordingly. Especially, these material samples have a high phenol red (PR) adsorption capacity at a concentration of 100 ppm and PR was degraded under a 30 W LED light with over 90% of conversion efficiency in the presence of 1.2 mL of 30% H2O2 solution. In addition, the CuH−3.5 material sample maintained stability after four times... [more]

A low material removal rate and a high tool wear rate are two major concerns among the research and development community of electric-discharge machining. From the literature, it is evident that several researchers have attempted to improve the material removal rate and minimize the tool wear rate by different means, such as parametric optimizations, powder mixing in the dielectric, induced vibrations in the electrode and/or workpiece, etc. Herein, an attempt is made to make use of a non-conventional electrode with a relief angle along with the taper angle of the machined feature and perform electric-discharge machining on D2-steel using copper as an electrode material. Preliminary level mathematical models were developed and validated for sparking the area of each non-conventional electrode’s design type. Three-stage experimentation was performed to identify the most appropriate electrode design. An approximately 70% improvement in the material removal rate, an around 45−50% reduction... [more]

The water channeling of fractured carbonate rock seriously affects oil recovery, and this problem is especially serious in the Kazakh North Troyes oilfield. A conventional powder polymer plugging system needs to be hydrated ahead of time, which increases the cost and difficulty of field operation and it cannot realize large-scale plugging operations. The new emulsion polymer crosslinked system can realize rapid hydration and real-time mixing, having low base liquid viscosity and good fluidity and injectability. The results of the laboratory study show that the gelling time of HR9806 emulsion polymer and organic chromium crosslinker was 6~8 h. 0.5 wt % HR9806, which is recommended for field use with P/C ranging from 2.5 to 5.0. The emulsion polymer crosslinking system was found to be highly adaptable in reservoirs and had salinity resistance. Mineral salt and reservoir core were able to enhance the gel strength of the system but shortened the gelling time of the system by about 2 h. The... [more]

Polycrystalline cubic boron nitride (PCBN) tools are widely used for hard machining of various ferrous materials. The edge structure of the PCBN cutting tool greatly affects the machining performance. In this paper, dry turning experiments were conducted on gray cast iron with a PCBN chamfered tool. Both the cutting temperature and the cutting force were measured, and then the surface quality and tool wear mechanisms were analyzed in detail. It was found that the cutting temperature and cutting force increased with the increase in feed rate, depth of cut, and cutting speed. The surface roughness firstly decreased, and then increased with an increase in feed rate. The minimum surface roughness was obtained with a feed rate of 0.15 mm/r which exceeded the tool chamfer width. The PCBN tool wear mode was mainly micro notches on the rake face and micro chipping on the tool chamfer, while the adhesion wear mechanism was the main tool wear mechanism.

The self-built fine water mist fire extinguishing platform studied the fire extinguishing effect of ultra-fine water mist in cold storage fires. The combustible material selected for our experiments is the cold storage insulation material—polystyrene insulation foam board. The combustion characteristics of the insulation board were studied by pyrolysis analysis. We analyzed the temperature, smoke, and other characteristics of the fire scene when a fire occurs in the cold storage and then manipulated the water mist to carry out the fire extinguishing experiment. Experiments aim to change the particle size and pressure of water mist and study the fire extinguishing efficiency of water mist under different conditions. A thorough analysis was used to determine the particle size range of fine water mist most suited for extinguishing fires in cold storage to offer a theoretical foundation for fire protection design.

For the purpose of the intensification of an industrial-scale gas-liquid process, the implementation in an alternative reactor concept is investigated at Hamburg University of Technology (TUHH) in cooperation with Ehrfeld Mikrotechnik GmbH. Existing process operation data from a bubble column hint at a mass transfer limitation of the gas-liquid reaction. In the project, a jet loop reactor (JLR) is chosen to increase the specific interfacial area between gas and liquid, and thus increase mass transfer, while keeping the reactor system mechanically simple and low-maintenance. For the investigation, a laboratory scale reactor has been designed on the basis of an existing industrial scale process and scaled according to a pilot scale reactor available at TUHH. For scaling, geometric similarity is desired, while specific energy dissipation rate and volumetric gas input are kept constant for the chosen scale-up strategy. Between the two different scales, the reactors are successfully charact... [more]

To improve water vapor adsorption, this study employed oxalic acid−ethyl acetate acidic hydrolysis to modify honeycomb activated carbon and introduce hydrophilic functional groups. Scanning electron microscopy (SEM), Boehm titration, Fourier transform infrared spectroscopy (FT-IR), and an automatic surface area analyzer (BET) were used to characterize the microscopic morphology, surface functional groups, specific surface area, and pore size changes. The results showed that, when the concentration of oxalic acid is 0.0006 mol/cm3, the specific surface area is 179.06 m2/g. After hydrolysis with ethyl acetate, the original functional groups became more abundant, while the number of total acidic functional groups on the surface grew from 0.497 mmol/g to 1.437 mmol/g. The static water vapor adsorption experiments were conducted on modified activated carbon under constant temperature and humidity conditions. Compared with unmodified activated carbon, the activated carbon modified with 0.000... [more]

Bionanotechnology is the combination of biotechnology and nanotechnology for the development of biosynthetic and environmentally friendly nanomaterial synthesis technology. The presented research work adopted a reliable and environmentally sustainable approach to manufacturing silver nanoparticles from Brachychiton populneus (BP-AgNPs) leaf extract in aqueous medium. The Brachychiton populneus-derived silver nanoparticles were characterized by UV−Vis spectroscopy, Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and energy dispersive X-ray analysis (EDX). In addition, the antioxidant, anti-inflammatory, antidiabetic, and cytotoxic activities of AgNPs were brought to light. The synthesis of BP-AgNPs was verified at 453 nm wavelength by UV−Vis spectrum. FTIR analysis revealed that synthesis, stability, and capping of AgNPs depend on functional groups such as alkane, alkene, nitro, flouro, phenol, alcoholic, and flavones, present in plant extract. The SE... [more]

The present study reports the results obtained after the analysis of the thermal stability and decomposition kinetics of widely used synthetic derivative of estradiol, ethinylestradiol (EE), as a pure active pharmaceutical ingredient. As investigational tools, Fourier transformed infrared spectroscopy (FTIR), thermal analysis, and decomposition kinetics modeling of EE were employed. The kinetic study was realized using three kinetic methods, namely Kissinger, Friedman, and Flynn-Wall-Ozawa. The results of the kinetic study are in good agreement, suggesting that the main decomposition process of EE that takes place in the 175−375 °C temperature range is a single-step process, invariable during the modification of heating rate of the sample.

Polymers are a vast class of materials that are highly tailorable to a wide variety of applications and can be modified in numerous ways [...]

Cu-Al-Nishape memory alloys (SMAs) are widely known for their better properties in comparison to other SMAs (lower production costs, increased ductility, enhanced machinability, reduced liquidus temperature, and decreased hysteresis), but there is still controversy in terms of the biological properties of these materials. The aim of this study was to evaluate biofunctional performances of Cu-Al-Ni alloy produced by continuous casting. The micro-chemical analysis was investigated by SEM/EDX. Immersion tests performed for seven days were used to estimate the quantity of Cu, Al, and Ni ions released in neutral pH and slightly acidic artificial saliva. To assess the biocompatibility of the Cu-Al-Ni alloy samples, MTT assay on fibroblasts and dental pulp cells was performed in indirect and direct contact with samples after 1,3, and 7 days.The study revealed that continuous casting enables the primary fabrication of Cu-Al-Ni rods with a shape memory effect. Samples immersed in artificial sal... [more]

Currently, the resources of fossil fuels, such as crude oil, natural gas, and coal, are depleting day by day due to increasing energy demands. Nowadays, plastic items have witnessed a substantial surge in manufacturing due to their wide range of applications and low cost. Therefore, the amount of plastic waste is increasing rapidly. Hence, the proper management of plastic wastes for sustainable technologies is the need of the hour. Chemical recycling technologies based on pyrolysis are emerging as the best waste management approaches due to their robustness and better economics. However, research on converting plastic waste into fuels and other value-added goods has yet to be undertaken, and more R&D is required to make waste-plastic-based fuels economically viable. In this review article, the current status of the plastic waste pyrolysis process is discussed in detail. Process-controlling parameters such as temperature, pressure, residence time, reactor type, and catalyst dose are als... [more]

Medical materials are the most important, fundamental resources necessary for emergency relief of major infectious disease disasters. The scientific and optimal allocation of emergency medical materials is the key to reducing casualties and losses in epidemic regions, and to improving the effectiveness and efficiency of rescue operations. In response to the cross-border characteristics of major infectious diseases, the imbalance of material storage, and the differences of supply across regions, a multi-objective optimization model for a multi-regional collaborative allocation of emergency medical materials was developed. Then, an improved adaptive genetic algorithm (IAGA) was designed and applied to solve the proposed model. Finally, a case study of the collaborative response to the COVID-19 epidemic in the Yangtze River Delta of China was conducted for model verification. The results show that collaborative allocation can improve the material satisfaction rate at demand points, especi... [more]

As the development of unconventional oil and gas resources goes deeper, the stimulation of reservoirs goes deeper year by year. Flow in longer wellbores poses a challenge to the stability of drag-reduction performance of fracturing fluid. However, at present we have limited understanding of the mechanism of drag-reduction damage caused by shear flow, especially the microscopic mechanism. Therefore, in this work, the variation pattern of drag reducer solution performance with shear rate has been analyzed by using a high precision loop flow drag test system. The test results show that there is a critical shear rate for the performance damage of the drag reducer solution, and high strength shear flow and cumulative shear flow time are the main factors leading to the performance degeneration of the drag reducer. Based on the nanometer granularity distributions, rheological properties and microscopic structures observed with a transmission electron microscope of drag reducer solutions subje... [more]

Perovskite solar cells (PeSCs) prepared with single crystals (SCs) ideally exhibit higher power conversion efficiencies (PCEs) because they possess a lower density of structural imperfection and superior charge transport. However, the density of the surface defects on the SCs is still very high, thereby inevitably affecting the device performance. Herein, perovskite single-crystal micro-plates were grown on a hole-transporting material, poly[bis(4-phenyl)(2,4,6-trimethylphenyl) amine], through a space-limited inverse temperature crystallization method. The surfaces of the as-prepared SCs were passivated using trioctylphosphine oxide (TOPO) during the device fabrication to alleviate the impact of surface defects. The PCE values are averagely improved from 11.90 ± 0.30% to 14.76 ± 0.65% after the surface passivation; the champion device even exhibits a PCE of 15.65%. The results from photoluminescence and hole-only devices reveal that TOPO treatments effectively reduce the number of surf... [more]

Rupture discs, manufactured using a hydraulic or pneumatic bulge process, are widely used to protect vessels from over-pressuring. The stress−strain relationship of the material in the bulge process plays a major role in understanding the performance of rupture discs. Moreover, both the theoretical analyses and numerical simulations of rupture discs demand a reliable stress−strain relationship of the material in a real bulge process. In this paper, an approach for determining the plastic stress−strain relationship of a rupture disc material in the bulge process is proposed based on plastic membrane theory and force equilibrium equations. Pressures of compressed air and methane/air mixture explosions were used for the bulge pressure to accomplish the quasi-static and dynamic bulge processes of tested discs. Experimental apparatus for the quasi-static bulge test and the dynamic bulge test were built. The stress−strain relations of 316L material during bulge tests were obtained, compared,... [more]

The surface areas of the materials are generally the most vulnerable parts since they are directly exposed to different stresses such as wear, fatigue, and corrosion. On the other hand, the successive impact of the droplets finds numerous applications in additive manufacturing technologies such as 3D printing and liquid metal projection. The lamella state formed by the impact and spreading of the first particle represents the target for the second; however, its molten state or fragmented state, bouncing or a slide, interacts thermally and dynamically to allow or not allow stacking. The deposition, deformation, and solidification of the droplets are the constituent steps of the process which determine the final result, as the topography of the substrate not only conditions the mechanical adhesion of the drop to the substrate but also affects the wettability of the surfaces. The objective of this work was to model by numerical simulation the impact of successive and simultaneous droplets... [more]

Bioremediation of farm soil is a technique that merits in-depth research. There are few studies related to the use of bioremediation to reduce cadmium (Cd) availability in soils used for cacao production. This study investigates (1) field bioprospection and strain characterization using techniques including isothermal microcalorimetry to select a group of cadmium-tolerant bacteria (CdtB) for potential use as bioremediators of cacao soils and (2) the application of bacterial inoculum to compare the immobilization of Cd under field conditions. Bioprospection was carried out in four cacao farms from the Antioquia district in Colombia. Culturable CdtB strains were isolated using CdCl2 as a Cd source and identified using molecular techniques. The metabolic characterization of Cd immobilization was carried out using isothermal microcalorimetry with CdCl2 amendments. Five cadmium-tolerant bacteria were isolated and characterized as Bacillus spp. The strain CdtB14 showed better growth and Cd i... [more]

Aiming at NO (NO 90%, NO2 10%) and SO2 in simulated vessel emissions, denitration and desulfurization were studied through ozone oxidation combined with seawater as absorbent. Specifically, the different influencing factors of denitration and desulfurization were analyzed. The results indicated that the oxidation efficiency of NO can reach over 90% when the molar ratio of O3/NO is 1.2. Ozone oxidation and seawater washing in the same unit can decrease the temperature of ozone oxidation of NO, avoid high temperature ozone decomposition, and enhance the oxidation efficiency of NO. When NO inlet initial concentration is lower than 800 ppm, the NO removal efficiency can be improved by increasing NO inlet concentration, and when NO inlet initial concentration is greater than 800 ppm, increasing the concentration of NO would decrease the NO removal efficiency. Increasing the inlet concentration of SO2 has minor effect on desulfurization, but slightly reduces the absorption efficiency of NO d... [more]

During the construction of tunnels in saturated water-bearing sand stratum, water and mud inrush disasters often occur. Grouting is the most convenient and effective method to improve the mechanical properties of the soil and prevent groundwater seepage. The reasonableness of the Discrete Element Method (DEM) contact parameters is verified by comparing the repose angle test with that obtained by simulations. The grouting model of saturated water-bearing sand stratum was established based on the Volume of Fluid-Discrete Element Method (VOF-DEM). Then, the effects of sand stratum porosity and grouting pressure on grouting were discussed. The results show that (1) in dense sands, the permeation diffusion of the slurry dominates, whereas in loose sands, the compaction zone is well developed. (2) Loose sand has a wider propagation of stress and dense sand has a larger increase in the stress state. (3) In loose sand the slurry diffusion is significantly affected by gravity, whereas in dense... [more]

Species of the genus Artemisia mainly biosynthesize sesquiterpene lactones. Achillin is a guaianolide-type sesquiterpene lactone isolated from Artemisia ludoviciana; it has shown antibacterial and anti-inflammatory activities. In addition, achillin exhibits a significant chemosensitizing effect on hepatocellular carcinoma cells resistant to paclitaxel (PTX). The objective of this study was to establish a callus culture from different explants under conditions of light and total darkness to produce achillin. To obtain in vitro cultures, explants of leaves, nodes, internodes, and roots were used, and they were cultured in MS medium with 0.1 mg/L of kinetin (KIN) or benzyl amino purine (BAP) and/or naphthaleneacetic acid (NAA), 2,4-dichlorophenoxyacetic acid (2,4-D), indole-3-acetic acid (IAA) and 4-amino-3,5,6-trichloro-2-pyridine carboxylic acid (PIC) at 0.1 and 1.0 mg/L. Of all treatments, internodes with BAP (0.1 mg/L) and PIC (1.0 mg/L) grown under photoperiod showed the best friable... [more]

In this study, the laser cutting characteristics were analyzed according to the shape of the back side of the specimen, and the laser cutting characteristics were compared according to the thickness of the edge (10 mm, 20 mm, and 30 mm). A Yb-YAG laser was used in this study, and the cutting target was STS304 with a thickness of 50 mm, and the cutting process was analyzed using a high-speed camera. In the experiment, it was found through image analysis that the cutting performance was excellent at 30 mm thickness of the edge. In order to analyze this reason, a thermal conduction analysis (numerical simulation) was performed, and it was confirmed that the thicker thickness of the edge caused a preheating effect during laser cutting due to a large amount of heat accumulation. This effect can be used as a reference for the initial processing state while cutting thick metals as it is a characteristic that has not been revealed before.