Fuel resource diversification is a global effort to deviate from non-renewable fossil fuels. Biomass has been identified as an alternative solid biofuel source due to its desirable properties and carbon neutrality. As reported in the literature, biomass can positively contribute towards combating climate change while providing alleviation for energy security issue. As part of efforts to diversify biomass resources, this work intends to explore the potential of Napier grass, one type of energy crop, for the production of renewable syngas via gasification. This energy crop is originally from Africa, which is highly productive with low cost (40 tonnes per year per hectare). Limited studies were conducted to analyze the potential of such an energy crop as a fuel source, which is the subject of this work. In order to analyze the full potential of such energy crop, the physical and chemical characteristics of this biomass was first analyzed. To determine the productivity of syngas from this... [more]

Nowadays, to ensure sustainability of smart materials, it is imperative to eliminate or reduce carbon footprint related to nano material production. The concept of design of experiment to provide an optimal synthesis process, with a desired yield, is indispensable. It is the researcher’s goal to get optimum value for experiments that requires multiple runs and multiple inputs. Herein, is a reliable approach of utilizing design of experiment (DOE) for response surface methodology (RSM). Thus, to optimize a facile and effective synthesis process for fluorescent carbon dots (CDs) derived from tapioca that is in line with green chemistry principles for sustainable synthesis. The predictions for fluorescent CDs synthesis from RSM were in excellent agreement with the artificial neural network (ANN) model prediction by the Levenberg−Marquardt back propagation (LMBP) algorithm. Considering R2, root mean square error (RMSE) and mean absolute error (MAE) have all revealed a positive hidden layer... [more]

The high capacity and voltage properties demonstrated by lithium-ion batteries render them as the preferred energy carrier in portable electronic devices. The application of the lithium-ion batteries which previously circulating and contained around small-scale electronics is now expanding into large scale emerging markets such as electromobility and stationary energy storage. Therefore, the understanding of the risk involved is imperative. Thermal runaway is the most common failure mode of lithium-ion battery which may lead to safety incidents. Transport process of immense amounts of heat released during thermal runaway of lithium-ion battery to neighboring batteries in a module can lead to cascade failure of the whole energy storage system. In this work, a model is developed to predict the propagation of lithium-ion battery in a module for large scale applications. For this purpose, kinetic of material thermal decomposition is combined with heat transfer modelling. The simulation is... [more]

This paper deals with a sustainable personnel scheduling problem of personnel working in a large-scale natural gas combined-cycle power plant in Turkey. The proposed model focuses on employee complaints due to unfair work schedules and the results of balanced assignments based on power plant interruptions. Eighty personnel work in three shifts at this natural gas combined-cycle power plant. The model is solved with respect to some of the workers’ skills, and there are 20 criteria regarding skills. The analytic network process method is used to get the weights of workers’ skills, which are calculated and included in the model. Goal programming is used in this paper. Our proposed model gives cost minimization and fair work schedules for the power plant. Compared with the literature, the number and set of criteria are unique in terms of personnel competency in the energy sector. Minimizing cost and imbalanced assignments was achieved by the proposed model for the first time without consid... [more]

The self-priming pump as an essential energy conversion equipment is widely used in hydropower and thermal power plants. The energy losses in the internal flow passage of the pump directly affect its work efficiency. Therefore, it is important to improve the internal flow characteristic of the pump. In the present work, a novel self-priming pump which starts without water is proposed; this pump can reduce the energy consumption as well as the time needed to start its operation. The spatial structure of the vortices in the pump is investigated by employing the Q criterion with the numerical solution of the vorticity transport equation. Based on the morphology, the vortices can be separated into three categories: Trailing Edge Vortex (TEV), Leading Edge Vortex (LEV) and Gap Leakage Vortex (GLV). Generally, the morphology of the TEV is more disorderly than that of LEV and GLV, and the intensity of TEV is significantly higher than that of the other two vortices. To determine the magnitude... [more]

Anaerobic digestion (AD) is an established process for integrating waste management with renewable energy and nutrient recovery. Much of the research in this field focuses on the utilisation of new substrates, yet their effects on operational aspects such as fluid behaviour and power requirement for mixing are commonly overlooked, despite their importance for process optimisation. This study analysed rheological characteristics of samples from 21 laboratory-scale continuous stirred-tank biogas reactors (CSTBRs) digesting a range of substrates, in order to evaluate substrate effect on mixing efficiency and power demand through computational fluid dynamics (CFD). The results show that substrate and process parameters, such as solids content and organic loading, all have a significant effect on CSTBR fluid rheology. The correlation levels between rheological and process parameters were different across substrates, while no specific fluid behaviour patterns could be associated with substra... [more]

Density functional theory calculations and molecular dynamics simulations were performed to investigate the hydrogen storage capacity in the sII hydrate. Calculation results show that the optimum hydrogen storage capacity is ~5.6 wt%, with the double occupancy in the small cage and quintuple occupancy in the large cage. Molecular dynamics simulations indicate that these multiple occupied hydrogen hydrates can occur at mild conditions, and their stability will be further enhanced by increasing the pressure or decreasing the temperature. Our work highlights that the hydrate is a promising material for storing hydrogen.

An environment-friendly insulating gas, perfluoroisobutyronitrile (C4F7N), has been developed recent years. Due to its relatively high liquefaction temperature (around −4.7 °C), buffer gases, such as CO2 and N2, are usually mixed with C4F7N to increase the pressure of the filled insulating medium. During these processes, the insulating gases may be contaminated with micro-water, and the mixture of H2O with C4F7N could produce HF under breakdown voltage condition, which is harmful to the gas insulated electricity transfer equipment. Therefore, removal of H2O and HF in situ from the gas insulated electricity transfer equipment is significant to its operation security. The adsorbents with the ability to remove H2O but without obvious C4F7N/CO2 adsorption capacity are essential to be used in this system. In this work, a series of industrial adsorbents and desiccants were tested for their compatibility with C4F7N/CO2. Pulse adsorption tests were conducted to evaluate the adsorption performa... [more]

An air distributor is a major component of industrial fluidized beds and its design significantly affects the quality of fluidization. In this study, a hybrid design of an annular distributor was tested for swirling fluidized beds (SFBs). Using this distributor design, a bed was operated in its uniform swirling regime of operation. A high-speed imaging method was used to capture images of the fluidized bed of particles. These images were processed using a binary cross-correlation technique and analyzed through particle image velocimetry (PIV) software. The velocity vector fields and corresponding velocity magnitudes at different locations in the bed were obtained for different bed weights, blade inclination angles, and superficial air velocities (SAVs). The Response Surface Analysis program was used to predict the bed velocity statistically. The statistical confidence interval for the bed velocity ranged from 0.49485 to 0.49998. The statistical fit and experimental values of the bed ve... [more]

Based on the study of the relationship between micro and macro parameters in the actual microstructure of the electrodes, a new multi-scale multi-field coupling model of battery monomer is established and the heat generation rate of the battery is obtained by detailed numerical simulation. According to the parameters of a certain electric vehicle and battery selected, the structure of the power battery pack and heat pipe cooling system is designed. Through multi-field coupling computational fluid dynamics simulation, the temperature difference of the battery pack is gained. By changing the fin spacing, the cooling scheme of the heat pipe is optimized, which ensures that the temperature difference is less than 5 K and the maximum temperature of the battery system is 306.26 K. It is found that increasing the discharge rate, the temperature difference increases rapidly. Increasing the air inlet velocity can improve the thermal uniformity of the battery pack, but changing the air inlet tem... [more]

Center spring wear faults in hydraulic pumps can cause fluid pressure fluctuations at the outlet, and the fault feature information on fluctuations is often contaminated by different types of fluid flow interferences. Aiming to resolve the above problems, a fluid pressure signal method for hydraulic pumps based on Autogram was applied to extract the fault feature information. Firstly, maximal overlap discrete wavelet packet transform (MODWPT) was adopted to decompose the contaminated fault pressure signal of center spring wear. Secondly, based on the squared envelope of each node, three kinds of kurtosis of unbiased autocorrelation (AC) were computed in order to describe the fault feature information comprehensively. These are known as standard Autogram, upper Autogram and lower Autogram. Then a node corresponding to the biggest kurtosis value was selected as a data source for further spectrum analysis. Lastly, the data source was processed by threshold values, and then the fault could... [more]

Stirred bioreactors are commonly used unit operations in the pharmaceutical industry. In this study, computational fluid dynamics (CFD) was used in order to analyze the influence of the impeller configuration (Segment−Segment and Segment−Rushton impeller configurations) and the impeller rotational speed (an operational parameter) on the hydrodynamic behaviour and mixing performance of a bioreactor equipped with a double impeller. A relatively close agreement between the power values obtained from the CFD model and those measured experimentally was observed. Various parameters such as velocity profiles, stress generated by impellers due to the turbulence and velocity gradient, flow number, and mixing time were used to compare the CFD simulations. It was observed that the impeller’s RPM could change the intensity of the interaction between the impellers when a Segment−Rushton impeller was used. In general, increasing the RPM led to an increase in total power and the stress acting on the... [more]

This contribution discusses the main challenges related to successful application of automatic control systems used to control specific growth rate in industrial biotechnological processes. It is emphasized that, after the implementation of basic automatic control systems, primary attention shall be paid to the specific growth rate control systems because this process variable critically affects the physiological state of microbial cultures and the formation of the desired product. Therefore, control of the specific growth rate enables improvement of the quality and reproducibility of the biotechnological processes. The main requirements have been formulated that shall be met to successfully implement the specific growth rate control systems in industrial bioreactors. The relatively easy-to-implement schemes of specific growth rate control systems have been reviewed and discussed. The recommendations for selection of particular control systems for specific biotechnological processes ha... [more]

In order to improve the general problem of irregular coating morphology and low mechanical strength of the coating layer in existing coating desensitization technology, nano-cyclotrimethylene trinitramine/melamine-urea-formaldehyde (RDX/MUF) composite energetic microspheres were prepared by an improved emulsion polymerization, taking the MUF as the binder and RDX as the main explosive. In order to judge whether RDX/MUF possessed good stability, the combination of differential scanning calorimetry (DSC) and molecular dynamics (MD) simulation was used to determine the level of binding binding energy between urea-formaldehyde resin binder (UF) and RDX. In addition, to investigate the optimal reaction temperature for the preparation of MUF/RDX, the binding energy between UF and RDX at different temperatures was simulated. And then the morphology and thermal properties of the as-prepared composite energetic microspheres were analyzed by scanning electron microscopy (SEM) and DSC, the impact... [more]

The unsteady flow characteristics of a forward multi-wing centrifugal fan under a low flow rate are studied using the computational fluid dynamics (CFD) method. This paper emphasizes the eddy current distribution in terms of the Q criterion method, as well as pressure fluctuation, frequency spectrum, and kinetic energy spectrum analysis of internal monitoring points in a forward multi-wing centrifugal fan. The numerical results show that abnormal eddies mainly appear at the volute outlet and near the volute tongue, boundary layer separation occurs near the suction surface of the blade, and shedding eddies appear at the trailing edge of the blade with the time evolution. The unsteady flow characteristics of a forward multi-wing centrifugal fan at a small flow rate provide significant physical insight into understanding the internal flow law.

The waterjet propulsion system has been widely used in the military and civil fields because of its advantages of in terms of high efficiency and energy savings. In order to study the three-dimensional cavitation flow in the waterjet propulsion pump, the cavitation process of the waterjet propulsion pump was simulated numerically using the Zwart−Gerber−Belamri cavitation model and the RNG (Renormalization Group) k-ε model. The simulation results of cavitation on the waterjet propulsion pump and pump system show that, in the initial stage of cavitation, vapors first collect on the leading edge of the suction surface of the blade near the rim of the impeller. As the total pressure at the impeller inlet decreases, the cavitation region expands toward the trailing edge and the vapor fraction volume gradually increases. In order to simulate the cavitation state of the waterjet propulsion pump under the actual working conditions, a numerical simulation of the entire waterjet propulsion pump... [more]

Double-volute is an effective technique to reduce radial hydraulic force on the centrifugal pump and thereby mitigate the pump-casing vibration induced by unsteady flow characteristics. The mechanism of the double-volute structure balancing radial force on the impeller and volute was investigated on the basis of volute cross-sections by using Computational Fluid Dynamics (CFD) method. The tested performances and simulated inner-flow characteristics of two pumps with single-volute and double-volute were compared in this paper. The performance-test results verify the veracity of CFD method and illustrate that double-volute pump has some losses in terms of pump head and operation efficiency. The numerical simulations reveal that double-volute pump has smaller radial-force magnitude than single-volute pump on the abnormal conditions. Steady pressure field and transient pressure variations of pumps were explored to account for radial-force characteristics of double-volute pump. Compared wit... [more]

A coal-based coproduction process of liquefied natural gas (LNG) and methanol (CTLNG-M) is developed and key units are simulated in this paper. The goal is to find improvements of the low-earning coal to synthesis natural gas (CTSNG) process using the same raw material but producing a low-margin, single synthesis natural gas (SNG) product. In the CTLNG-M process, there are two innovative aspects. Firstly, the process can co-generate high value-added products of LNG and methanol, in which CH4 is separated from the syngas to obtain liquefied natural gas (LNG) through a cryogenic separation unit, while the remaining lean-methane syngas is then used for methanol synthesis. Secondly, CO2 separated from the acid gas removal unit is partially reused for methanol synthesis reaction, which consequently increases the carbon element utilization efficiency and reduces the CO2 emission. In this paper, the process is designed with the output products of 642,000 tons/a LNG and 1,367,800 tons/a methan... [more]

A mathematical model comprising Darcy Forchheimer effects on the 3D nanofluid flow with engine oil as a base fluid containing suspended carbon nanotubes (CNTs) is envisioned. The CNTs are of both types i.e., multi-wall carbon nanotubes (MWCNTs) and single-walled carbon nanotubes (SWCNTs). The flow is initiated by an exponentially stretched surface. The impacts of Cattaneo−Christov heat flux along with velocity and thermal slip conditions are key factors in the novelty of the defined model. The boundary layer notion is designed to convert the compact form of equations into the component shape. Appropriate transformations lead to differential equations with high nonlinearity. The final non-dimensional system is solved numerically by a “MATLAB” function known as bvp4c. For both CNTs, different graphical sketches are drawn to present the influence of arising parameters versus related profiles. The outcomes show that higher slip parameter boosts the axial velocity, whereas fluid temperature... [more]

Water inrush of tunnel face is one of the most common geological disasters during tunnel construction in China. Aiming at the rock mass with multi fractures in water-resistant strata ahead of karst tunnel, the compressive-shear cracking property is analyzed by fracture mechanics theory and the change law of rock bridge shear strength with branch crack propagated length under karst water pressure and geo-stress is studied according to Mohr-Coulomb strength criterion. Moreover, the critical water pressure of water-resistant strata with multi fractures under tension-shear failure is deduced. The safe thickness of water-resistant strata with multi fractures ahead of karst tunnel is established based on two band theory and critical water pressure, and the influence of karst water pressure, initial crack length, crack spacing, array pitch of cracks, lateral pressure coefficient and the angle between the crack and the maximum principal stress on the minimum safe thickness of water-resistant s... [more]

This paper focuses on total quality management (TQM) processes and their applications to increase the management performance of enterprises in the renewable energy sector (RES). TQM is a modern tool used by enterprises to increase their management performance. We start with a description of Edwards Deming’s conceptualized model, highlighting different phases of its development as described in the literature. The TQM process is then used for an application to the RES in Romania. The quantitative model analyzes the influence of TQM process implementation in achieving competitive advantage and the management performance of the undertakings in the RES. Data was collected through a survey based on a questionnaire addressed to employees and managers in the RES. Structural equation modeling (SEM) was used and the research hypotheses were tested with the partial least squares path method (PLS). Data analysis was performed with the statistical software SmartPLS 3.2.8. The main contribution of t... [more]

In this research, a state-of-the-art experimental core flooding setup is used to assess the efficiency of surfactant flooding as an enhanced oil recovery (EOR) technique in tight carbonate rocks. Specifically, we investigate the role of apparent wettability in governing the effectiveness of surfactant flooding. A series of flooding experiments with well-defined boundary conditions were performed on the low permeability core plug samples of Indiana Limestone (calcite-cemented carbonate grainstones). Experiments were conducted on three samples exhibiting differing apparent wetting characteristics: strongly oil-wet, moderately oil-wet and weakly oil-wet. Initially, the oil-saturated core samples were flooded with brine until the residual oil saturation was achieved, with surfactant flooding performed as a tertiary recovery technique. Interestingly, our experimental results reveal that the efficiency of surfactant flooding increases with the degree of oil-wetness of the tight carbonate roc... [more]

Chromatography is widely used in biotherapeutics manufacturing, and the corresponding underlying mechanisms are well understood. To enable process control and automation, spectroscopic techniques are very convenient as on-line sensors, but their application is often limited by their sensitivity. In this work, we investigate the implementation of Raman spectroscopy to monitor monoclonal antibody (mAb) breakthrough (BT) curves in chromatographic operations with a low titer harvest. A state estimation procedure is developed by combining information coming from a lumped kinetic model (LKM) and a Raman analyzer in the frame of an extended Kalman filter approach (EKF). A comparison with suitable experimental data shows that this approach allows for the obtainment of reliable estimates of antibody concentrations with reduced noise and increased robustness.

In this paper, we consider the problem of economic model predictive control of wastewater treatment plants based on model reduction. We apply two model approximation methods to a wastewater treatment plant (WWTP) described by a modified Benchmark Simulation Model No.1 to overcome the intensive computation associated with economic model predictive control (MPC). Two computationally efficient models are obtained based on trajectory piecewise linearization (TPWL) and reduced order TPWL. To obtain the reduced order TPWL model, a proper orthogonal decomposition (POD)-based method is utilized. Further, the reduced order model is linearized to obtain a TPWL-POD model. The objective is to design controllers which minimize the overall economic cost. Accordingly, we design economic MPC (EMPC) controllers based on each of the models. The economic control cost can be described as a weighted summation of effluent quality and overall operating cost. We compare the accuracy of the two proposed approx... [more]

The ethnobotanical survey of Euclea divinorum Hiern (Ebenaceae) was conducted on Soqotra Island, Yemen. The root bark is used to treat mouth, dental, dermal and blood diseases in the traditional medicine of the island. The study is the first report about the effect of the plant root barks against six human pathogenic fungi. The non-polar dichloromethane extract of Euclea divinorum root bark showed stronger antifungal activities compared to polar direct and sequential methanolic extracts. These extracts showed significant broad antifungal activity against Absidia corymbifera, Aspergillus fumigatus, Candida krusei, Microsporum gypseum, Mucor sp. and Trichophyton mentagrophytes compared to the standard antibiotic drug nystatin. Thin-layer chromatography (TLC) revealed the presence of the naphthoquinones in the extracts. The results showed an extraction process to separate most antifungal naphthoquinones from the root bark by using non-polar solvent dichloromethane, while flavonoids remain... [more]