The hydrocarbon compositions of shale oils, generated from two different lithological−facial Domanic deposits of the Tatarstan Republic (Russia), were studied under hydrothermal impact with 30% of water addition in a 350 °С and CO2 environment. The samples were extracted from carbonate−siliceous rocks of the Semiluky−Mendym deposits of the Berezovskaya area, and carbonate deposits of the Dankovo−Lebedyan horizon of the Zelenogorskaya area of the Romashkino oil field. The distinctive features of rocks are in the composition and content of organic matter (OM), its thermal stability, as well as the structural-group composition of the shale oil products. The hydrothermal treatment of the rock samples increased the content of saturates and decreased the content of aromatics, resins and asphaltenes in the composition of crude oil. The decomposition of the polymer-like kerogen structure and destruction processes of high-molecular compounds, such as resins and asphaltenes, are accompanied with... [more]

Papaya (Carica papaya) waste cause significant commercial and environmental damage, mainly due to the economic losses and foul odours they emit when decomposing. Therefore, this work provides an innovative way to generate electricity for the benefit of society and companies dedicated to the import and export of this fruit. Microbial fuel cells are a technology that allows electricity generation. These cells were produced with low-cost materials using zinc and copper electrodes; while a 150 mL polymethylmethacrylate tube was used as a substrate collection chamber (papaya waste). Maximum values of 0.736 ± 0.204 V and 5.57 ± 0.45 mA were generated, while pH values increased from 3.848 to 8.227 ± 0.35 and Brix decreased slowly from the first day. The maximum power density value was 878.38 mW/cm2 at a current density of 7.245 A/cm2 at a maximum voltage of 1072.77 mV. The bacteria were identified with an identity percentage of 99.32% for Achromobacter xylosoxidans species, 99.93% for Acineto... [more]

Industrial green technology progress is an effective way to realize high-quality economic development in China. The different competitive incentives of local governments make a difference in the intensity of environmental regulation between regions. The intensity of environmental regulation is different in different areas of the same industry, leading to the inter-regional transfer of pollution enterprises. The regional distribution of industries is different, which determines the different industries’ needs to coordinate different regions. Only when various industries realize the coordination of regional governance can they jointly promote the progress of industrial green technology. Based on data from 33 industrial sectors in China from 2001 to 2015 and considering the institutional evolution of governance synergy, this study comprehensively investigated the influence mechanism of local government environmental regulation on the industrial green technology progress using the mediatin... [more]

Fe3O4 nanoparticles with cluster structure are superparamagnetic particles with applicability in various high-tech fields. In this study, the influence of surface modification with polyacrylic acid (PAA), a polymeric precursor, on the characteristics of Fe3O4 nanoparticles was investigated. The particles were synthesized by the polyol method and surface modified with various amounts of PAA. The surficial, structural, optical, and magnetic properties of the PAA-modified Fe3O4 nanoparticles were analyzed, confirming that negatively charged carboxyl groups were formed on the particle surface, and the particle dispersibility was enhanced by surface modification. This arises from an increase in the electrostatic repulsive force due to the surface functional groups. Functionalization promoted dissociation of the cluster particles, which became more pronounced as the PAA content increased. The optical parameters changed with the PAA content. Analysis of the magnetic properties showed that the... [more]

Magnetic gel abrasive finishing is a high-precision polishing method that uses magnetic forces to attract and restrain a gel abrasive, composed of aqueous slime gel, steel grits, and silicon carbon (SiC), for polishing workpieces. However, the magnetic adsorption performance of the gel abrasive will drop quickly when polishing non-ferromagnetic material such as stainless-steel or brass. Moreover, centrifugal force will push out the gel abrasive from the machining surface reducing the stability of polishing. Therefore, this paper developed a rotating cylinder-based magnetic finishing setup to allow the gel abrasive and workpieces to tumble and rotate together during the polishing process. To make the gel abrasive produce irregular and complicated movement paths for improving the polishing performance, this study first analyzed and compared the average surface roughness and removed material weight of workpieces using three kinds of motor operating modes; a unidirectional trapezoidal wave... [more]

Studying the characteristics of wind speed is essential in wind speed prediction. Based on long-term observed wind speed data, fractal dimension analysis of wind speed was first conducted at different scales, and persistence in wind speed was evaluated based on fractal dimensions in this paper. To propose a more accurate model for wind speed prediction, the wavelet decomposition method was applied to separate the high-frequency dynamics of wind speed data from the low-frequency dynamics. Chaotic behaviors were studied for each decomposed component using the largest Lyapunov exponents method. A proposed hybrid prediction method combining wavelet decomposition, a chaotic prediction method and a Kalman filter method was investigated for short-term wind speed prediction. Simulation results showed that the proposed method can significantly improve prediction accuracy.

The complex ventilation system development process is associated with the stages of modelling, design, execution, and testing. Each of these steps requires the use of measuring equipment that is capable of determining the basic parameters of the flow. In the process of calibrating instruments for measuring flow velocity, one of the limitations is the size of the calibrated devices positioned in the test section of the wind tunnel. This is related to the change in the flow condition within the vicinity of the calibrated anemometers, which is caused by the blockage effect. Instruments with significant dimensions in relation to the cross-sectional area of the wind tunnel test section may have an impact on the reference velocity as indicated by the standard. In such cases, the calibration results may be affected by additional systematic error. This article presents a study of this effect using a real case of a calibration laboratory and commonly used sensors. The influence of different typ... [more]

Development of gas sensors displaying improved sensing characteristics including sensitivity, selectivity, and stability is now possible owing to tunable surface chemistry of the sensitive layers as well as favorable transport properties. Herein, zinc ferrite (ZnFe2O4) nanoparticles (NPs) were produced using a microwave-assisted hydrothermal method. ZnFe2O4 NP sensing layer films with different thicknesses deposited on interdigitated alumina substrates were fabricated at volumes of 1.0, 1.5, 2.0, and 2.5 µL using a simple and inexpensive drop-casting technique. Successful deposition of ZnFe2O4 NP-based active sensing layer films onto alumina substrates was confirmed by X-ray diffraction and atomic force microscope analysis. Top view and cross-section observations from the scanning electron microscope revealed inter-agglomerate pores within the sensing layers. The ZnFe2O4 NP sensing layer produced at a volume of 2 μL exhibited a high response of 33 towards 40 ppm of propanol, as well as... [more]

In this paper, the dynamic evolution of nanoparticles in a turbulent Taylor−Couette flow was studied by means of a numerical simulation. The initial particle size was 200 nm, and the volume concentration was 1 × 10−5. The Reynolds-averaged N−S equation for Taylor−Couette flow was solved numerically using the realizable k-ε model combined with the standard wall function. The numerical result of the velocity distribution is in good agreement with the experimental results. Additionally, the dynamic equation for the particle number distribution function was solved numerically using the Taylor series expansion moment method (TEMOM). The variation characteristics of particle number density, diameter and polydispersity in the flow were analyzed. The results show that particle breakage is obvious in the region with strong vorticity due to the large shear strength, which leads to a significant change in the particle number density, diameter and polydispersity. Furthermore, the effects of the ga... [more]

Drug delivery systems (DDS) are artificial devices employed to enhance drug bioavailability during administration to a human body. Among DDS, liposomes are spherical vesicles made of an aqueous core surrounded by phospholipids. Conventional production methods are characterized by several drawbacks; therefore, Supercritical assisted Liposome formation (SuperLip) has been developed to overcome these problems. Considering that the use of high pressures involves high energy cost, in this paper, sustainability indicators were calculated to quantitatively evaluate the emissions related to the attainment of liposomes containing daunorubicin (a model antibiotic drug) using the SuperLip process. The indicators were depicted using a spider diagram to raise the actual weaknesses of this technique; some variations were proposed in the process layout to solve the critical issues. According to the literature, many studies related to the pharmaceutical industry are expressed in terms of solid, liquid... [more]

Direct methanol fuel cells (DMFCs) offer high energy density, simple liquid fuel storage, and the ability to operate at ambient temperature. They may be used in a variety of portable mobile power supplies, small civilian power supplies, and automotive power supplies. However, in the process of electrochemical reaction inside a DMFC, because the reactants and products are distributed unevenly, the in-plane concentration of reactants and reaction rate are different; thus, the current density generated in the active area shows a high degree of non-uniformity. The high local current density can easily lead to the acceleration of DMFC aging. As a result, the operating cost of the DMFC is increased and the service life is shortened, which limits the commercial application of DMFCs. In this work, we develop an in-plane gradient loading catalyst. The loading on both the anode and cathode catalysts was lower near the inlet and higher close to the outlet. The experimental results of the single-c... [more]

In the Intelligent Transportation System (ITS) realm, queue length estimation is one of an essential yet a challenging task. Queue lengths are important for determining traffic density in traffic lanes so that possible congestion in any lane can be minimized. Smart roadside sensors such as loop detectors, radars and pneumatic road tubes etc. are promising for such tasks though they have a very high installation and maintenance cost. Large scale deployment of surveillance cameras have shown a great potential in the collection of vehicular data in a flexible way and are also cost effective. Similarly, vision-based sensors can be used independently or if required can also augment the functionality of other roadside sensors to effectively process queue length at prescribed traffic lanes. In this research, a CNN-based approach for estimation of vehicle queue length in an urban traffic scenario using low-resolution traffic videos is proposed. The queue length is estimated based on count of t... [more]

A rotary desiccant-based air-conditioning system is a heat-driven hybrid system which combines different technologies such as desiccant dehumidification, evaporative cooling, refrigeration, and regeneration. This system has an opportunity to utilize low-grade thermal energy obtained from the sun or other sources. In this paper, the basic principles and recent research developments related to rotary desiccant-based cooling systems are recalled and their applications and importance are summarized. It is shown that with novel system configurations and new desiccant materials, there is great potential for improving the performance and consistency of rotary desiccant systems; at the same time, the use of solar energy for regeneration purposes can minimize the operating cost to a great extent. Some examples are presented to demonstrate how rotary desiccant air conditioning can be a promising solution for replacing traditional vapor-compression air-conditioning systems. Recent advances and on... [more]

A nonlinear offset-free model predictive control based on a dynamic partial least square (PLS) framework is proposed in this paper. A multi-output multi-input system is projected into latent variable space by a PLS outer model. For each latent variable model, the T−S fuzzy model is used to describe the nonlinear characteristics of the system; while the state-space model is used in T−S fuzzy model consequent parameters to describe the dynamic characteristics. A disturbance model is introduced in the state-space model. For model state variables, a state observer is used to compensate for the mismatch of the model. The case study results for the pH neutralization process show that the MPC controller based on this method can guarantee the tracking performance of the nonlinear system without static error.

Industry-sponsored research has intensified to find suitable substitutes for synthetic polymers. For this purpose, biopolymers are promising materials that are extracted from renewable resources. However, there are areas of concern (biopolymers are mostly brittle in the dry state) that require further research before they are used in advanced applications. To overcome this, plasticizers are often added to biopolymers to enhance their physicochemical properties. In this study, chitosan (CH)-glycerol (GL)-based polymeric films were prepared by a simple drop-casting technique, and the influence of a plasticizer (GL) on the properties of chitosan films was analyzed. Additionally, the as-prepared samples were irradiated with γ-rays (60Co γ rays with a dose of 102 kGy) to study the effect of γ-irradiation on the properties of polymeric composites. To achieve this, different samples were prepared by varying the amount of GL. FT-IR analysis revealed the interruption of hydrogen bonding in chit... [more]

The objective of this study was to examine the physicochemical composition, thermal properties, quality, and sensorial characteristics of bread with substitution of wheat flour with ayocote bean (Phaseolus coccineus) or black bean (Phaseolus vulgaris) flours at 10, 20, and 30%. Ayocote and black bean contain 21.06 and 23.94% of protein, 3.06 and 5.21% of crude fiber, and 3.1 and 5.21% of ash, respectively, directly influencing bread composition. Bread with ayocote and black bean presented higher values in those components in contrast with control bread. The protein content increased in a range of 14−34%; ash increased by 10% to double, and crude fiber also increased. In vitro protein digestibility was similar for bread with 10% of substitution and control, and it decreased in samples with 30% of wheat substitution. Thermal analysis by DSC denoted that the addition of those legumes reduces retrogradation, as seen in 45.33−65.65 °C endotherm, producing higher endotherms of amylose-lipid... [more]

To reach Carbon Peak in 2030 and Carbon Neutrality in 2060, China is developing renewable energy at a fast pace. Renewable energy enterprises will participate in the power market in an all-round way as China gradually improves its electricity market. Signing the Power Purchase Agreement (PPA) helps renewable energy companies to avoid market risk and achieve sustainable development. Therefore, a novel PPA pricing model is proposed in our research. Based on the theory of the Levelized Cost of Energy (LCOE), our model considers system operating costs in China’s dual-track electric power sector, which is both government-guided and market-oriented. First of all, key influencing factors of the PPA agreement are analyzed in view of the developments of the renewable energy and electricity markets in China. Next, the design of pricing strategies for renewable energy power plants to cope with market challenges is presented through a photovoltaic project case study. The results show that when the... [more]

In the past few decades, the role of nanotechnology has expanded into environmental remediation applications. In this regard, nanofibers have been reported for various applications in water treatment and air filtration. Nanofibers are fibers of polymeric origin with diameters in the nanometer to submicron range. Electrospinning has been the most widely used method to synthesize nanofibers with tunable properties such as high specific surface area, uniform pore size, and controlled hydrophobicity. These properties of nanofibers make them highly sought after as adsorbents, photocatalysts, electrode materials, and membranes. In this review article, a basic description of the electrospinning process is presented. Subsequently, the role of different operating parameters in the electrospinning process and precursor polymeric solution is reviewed with respect to their influence on nanofiber properties. Three key areas of nanofiber application for water treatment (desalination, heavy-metal rem... [more]

The topology algorithm (TA) can effectively find an optimal solution by changing the material and shape of the design target without the limitation of design variables. In this paper, a genetic topology algorithm (GTA) is proposed for the design optimization of a synchronous reluctance motor (SynRM). By applying the stochastic algorithm (genetic algorithm (GA)) and the deterministic algorithm (ON-OFF method) to the design, the optimal shape can be found quickly and effectively. The GTA, which improves manufacturability by removing the aliasing that occurs in TA, was applied to the design of SynRM to search for the optimal model. After dividing the rotor into a reverse mesh grid, the optimal topology was searched for by GA and ON-OFF methods. Then, mechanical stability was verified through stress analysis, and additional performance improvement was obtained through the skew technique. The final design, which satisfies the minimum efficiency, required torque, and torque ripple was derive... [more]

Products from castor seeds have been widely used in various fields. In order to study the breaking behavior and rupture mechanism of castor seed episperm during coat shelling process, the force-structure property of coating castor seed was investigated by a self-developed texture analyzer with in situ optical microscopic observation. Influences of compression distance, velocity and working temperature were studied. The results showed that castor seed episperm rupture commonly happened from the tail end to the first end. Compression distance effect can change the episperm cracking degree. Under pressing distance 2−3 mm, the episperm easily cracked into two flaps, and the breaking force stabilized at 77 N. Pressing velocity has no significant effect on episperm breaking. Temperature changes the physical property. With an increase in temperature, breaking force presents a “slope” decline; under a temperature of 120 ℃, temperature effect on the breaking force decreased significantly and th... [more]

The development of small semiconductor molecules such as the maleiperinone, have gained importance due to their applications in optoelectronics. In this work semiconductor films composed by a polymer matrix of PEDOT:PSS (poly(3,4-ethylenedioxythiophene) polystyrene sulfonate) and maleiperinone were manufactured. The films used in the studies were deposited by vacuum evaporation and spin-coating techniques. Atomic force microscopy (AFM), scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and Infrared spectroscopy were used for the analysis of morphological and structural films. The fundamental and the onset of the direct and indirect band gaps were also obtained by UV-vis spectroscopy. The band-model theory and the Density-functional theory (DFT) calculations were applied to determine the optical parameters. The dipole moment is 3.33 Db, and the high polarity gives a signal of the heterogeneous charge distribution along the structure of maleiperinone. Simple devices we... [more]

Rupture discs, also called bursting discs, are widely used in pressure vessels, pressure equipment, and pressure piping in process industries, such as nuclear power, fire protection, and petrochemical industries. To explore the relationship between the burst pressure of reverse-acting rupture discs and their production, two common manufacturing methods, air pressure moulding and hydraulic moulding, were compared in this study. Reverse-acting rupture discs that complied with the form recommended by API 520-2014 were prepared with four release diameters, and burst pressure tests were carried out. These results showed an obvious negative correlation between the forming pressure of rupture discs and their actual burst pressure for all experimental samples. Further study showed that the main reason for this correlation was a reduction in thickness at the top of the rupture disc caused by large plastic deformation during compression moulding. To explore the relationship between the thickness... [more]

In this paper, a new hybrid algorithm based on two meta-heuristic algorithms is presented to improve the optimization capability of original algorithms. This hybrid algorithm is realized by the deep ensemble of two new proposed meta-heuristic methods, i.e., slime mold algorithm (SMA) and arithmetic optimization algorithm (AOA), called DESMAOA. To be specific, a preliminary hybrid method was applied to obtain the improved SMA, called SMAOA. Then, two strategies that were extracted from the SMA and AOA, respectively, were embedded into SMAOA to boost the optimizing speed and accuracy of the solution. The optimization performance of the proposed DESMAOA was analyzed by using 23 classical benchmark functions. Firstly, the impacts of different components are discussed. Then, the exploitation and exploration capabilities, convergence behaviors, and performances are evaluated in detail. Cases at different dimensions also were investigated. Compared with the SMA, AOA, and another five well-kno... [more]

A combined circulation system of spray evaporative cooling and air cooling (CCSSECAC) is a way to enhance the cooling performance of an air-cooled electric machine while maintaining its existing structure. Based on a traditional air-cooled machine, when the discrete evaporative cooling medium particles are scattered into the airflow, they will reach the heat source with the air circulation. The cooling capacity of the cooling system is enhanced simultaneously through the phase transition and convection heat transfer. Ultrasonic atomization is a simple way to produce tiny droplets and a good way to improve the performance of CCSSECAC. To verify the effectiveness of such a system, a principle test model was built and a multi-operational condition experiment was carried out as an exploratory study. The experimental results showed that the new cooling system was feasible for horizontal machines, and the stator coil temperature was significantly reduced compared with the air-cooled mode.

Whey is a primary by-product of dairy plants, and one that is often difficult to manage. As whey processing units are costly and complicated, only 15−20% of whey is recycled for use in the food industry. The difficulties in managing waste whey are particularly pronounced for small, local dairy plants. One possible solution to this problem is to use advanced and efficient digesters. The aim of this study was to present an innovative multi-section hybrid anaerobic bioreactor (M-SHAR) design and to identify how microwave radiation heating (MRH) affects methane fermentation of liquid dairy waste (LDW) primarily composed of acid whey. The MRH reactor was found to perform better in terms of COD removal and biogas production compared with the convection-heated reactor. The heating method had a significant differentiating effect at higher organic load rates (OLRs). With OLRs ranging from 15 to 25 kgCOD∙m−3∙d−1, the M-SHAR with MRH ensured a 5% higher COD removal efficiency and 12−20% higher bi... [more]