This study was based on a numerical effort to use the motor support (prop) as a guide vane when the motor of a wall-mounted axial fan was located at the fan outlet while maintaining the structural and spatial advantage. The design for the guide vane followed two- and three-dimensional methods. The inlet vane angle, meridional length (total), and meridional length with a vane angle of zero (0) degrees (linear) were considered as design variables. At the design and some low flow rate points, the 2D design offered the most favorable performance when the meridional length with a vane angle of zero (0) degrees (linear) was 30% based on total length, and was the worst for 70%. The 3D design method applied in this study did not outperform the 2D design. In the 2D design concept, averaging the flow angle for the entire span at the design flow rate could ensure a better pressure rise over a more comprehensive flow rate range than weighting the flow angle for a specific span. In addition, the nu... [more]

The isolation of nanocellulose from different agricultural residues is becoming an important research field due to its versatile applications. This work collects different production processes, including conditioning steps, pretreatments, bleaching processes and finally purification for the production of nanocellulose in its main types of morphologies: cellulose nanofiber (CNF) and cellulose nanocrystal (CNC). This review highlights the importance of agricultural wastes in the production of nanocellulose in order to reduce environmental impact, use of fossil resources, guarantee sustainable economic growth and close the circle of resource use. Finally, the possible applications of the nanocellulose obtained as a new source of raw material in various industrial fields are discussed.

The development of information and communication technology in terms of sensor technologies cause the Internet of Things (IoT) step toward smart homes for prevalent sensing and management of resources. The gateway connections contain various IoT devices in smart homes representing the security based on the centralized structure. To address the security purposes in this system, the blockchain framework is considered a smart home gateway to overcome the possible attacks and apply Deep Reinforcement Learning (DRL). The proposed blockchain-based smart home approach carefully evaluated the reliability and security in terms of accessibility, privacy, and integrity. To overcome traditional centralized architecture, blockchain is employed in the data store and exchange blocks. The data integrity inside and outside of the smart home cause the ability of network members to authenticate. The presented network implemented in the Ethereum blockchain, and the measurements are in terms of security, r... [more]

The use of metal oxides as supports for palladium and copper (Pd−Cu) nanoalloys constitutes a new horizon for improving new active catalysts in very important reactions. From the literatures, Pd-based bimetallic nanostructures have great properties and active catalytic performance. In this work, nanostructures of titanium dioxide (TiO2) were used as supports for Pd−Cu nanoparticles catalysts. Palladium and copper were deposited on these supports using the sol-immobilisation method. The composite nanoalloys were characterized using transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The catalyst was evaluated for the oxidation of benzyl alcohol. The effect of the Cu−Pd ratio using sol-immobilization methods supported on TiO2 was investigated. The results show that monometallic Cu/TiO2 was observed to have a low activity. However, as soon as the catalyst contained any palladium, the activity increased with a significant increase in the selectivity towards i... [more]

Due to CO2 mass transfer limitation as well as the competition of hydrogen evolution reaction in electroreduction of CO2 in the aqueous electrolyte, Zn-based electrodes normally exhibit unsatisfying selectivity for CO production, especially at high potentials. In this work, we introduced a zinc myristate (Zn [CH3(CH2)12COO]2) hydrophobic layer on the surface of zinc foam electrode by an electrodeposition method. The obtained hydrophobic zinc foam electrode showed a high Faradaic efficiency (FE) of 91.8% for CO at −1.9 V (vs. saturated calomel electrode, SCE), which was a remarkable improvement over zinc foam (FECO = 81.87%) at the same potentials. The high roughness of the hydrophobic layer has greatly increased the active surface area and CO2 mass transfer performance by providing abundant gas-liquid-solid contacting area. This work shows adding a hydrophobic layer on the surface of the catalyst is an effective way to improve the electrochemical CO2 reduction performance.

Biochar can be derived from a wide variety of organic materials including agricultural wastes and residues, animal wastes, municipal solid wastes, pulp and paper mill wastes, and sewage sludge. Its productivity relies on feedstock type and thermochemical conditions of production. Biochar has many application advantages in several fields and has been widely studied in recent years. However, most of these studies are mainly on the powder form of biochar, while its pelleted form is sparsely reported. Even with the reported studies on biochar pellets, there is still lack of knowledge and awareness of the effects of different feedstock on the densification behavior of biochar. The mechanisms of biochar densification, which appear to be sensitive to the conditions predominating during its thermochemical production, are affected by the material from which the biochar is derived. This partly accounts for why biochar pellets have not been widely adopted in various application fields. Therefore,... [more]

In its prominent experimental studies salvianolic acid B (Sal B) is novel because of its well-defined, common physiological effects, which include anti-inflammatory, anti-depressant, cardioprotective, DNA protective, neuroprotective and hepatoprotective activity in experimental animals. Initially, Sal B was studied for its anti-inflammatory properties, used as a remedy for a wide range of disease conditions, but its specific efficacy on inflammatory bowel disease is still unclear. The aim of this current study was to understand the therapeutic potential of Sal B in an acetic acid (AA)—triggered experimental mouse colitis model. Colitis was triggered by intrarectal injection of 5% AA, and then laboratory animals were given Sal B (10, 20 and 40 μg/kg) for seven days. The ulcerated colonic mucosa was assessed by clinical experiment, macroscopical, biological and histopathological analysis. The results showed depleted SOD, CAT, GSH levels and consequential elevated MPO and MDA levels and a... [more]

This paper would like to compare two extraction procedures for analyzing phthalates (PAEs) in hot drinks collected at vending machines, usually coffee and tea. The two analytical procedures are based on Solid Phase Extraction (SPE) using C18 cartridge and on dispersive liquid-liquid microextraction (DLLME) assisted by ultrasound and vortex for improving the dispersion mechanically, with each followed by a routinary analytical method such as GC-FID. Seven phthalates (DMP, DEP, DiBP, DBP, DEHP, DOP, DDP) have been analyzed and determined. All the analytical parameters (i.e., recovery, limit of detection, limit of quantification, enrichment factors, repeatability, reproducibility) have been investigated and discussed, as has the matrix effect. The entire procedure has been applied to hot drink matrices, e.g., coffee, decaffeinated coffee, barley coffee, ginseng coffee and tea.

In the study of block copolymers, many parameters need to be adjusted to obtain good phase separation results. Based on block copolymer polystyrene-b-polycarbonate and homopolymer polystyrene, the effects of the annealing atmosphere, blending ratio, and molecular weight on phase separation were studied. The results show that annealing in air can inhibit the occurrence of phase separation. In addition, snowflake patterns are formed during phase separation. The blending ratio affects the quality of the pattern. The molecular weight affects the size of the pattern, and the size increases as the molecular weight increases. In this article, the influence of process conditions and materials on phase separation was discussed, which has laid a solid foundation for the development of block copolymer self-assembly in the future.

Vapor pressure deficit (VPD) can be used as an indicator to schedule greenhouse irrigation. VPD can be estimated as a function of relative humidity (RH) and temperature (T). The objective of this work was to analyze spatial variation in VPD as an indicator of water stress influenced by concentration of water vapor and intensity of near infrared (NIR). The study was carried out in an empty three-span sawtooth greenhouse with natural ventilation under the local climate in Montecillo, Mexico; these findings established a base value to analyze greenhouse field conditions prior to the influence from a crop. The experimental phase consisted of recording data (3 February 2019−24 February 2019) on temperature, humidity, solar radiation, and wind speed, which were used for developing a model in computational fluid dynamics (CFD). Then, this model was used to estimate VPD, considering changes in mass fraction of water vapor and the intensity of NIR. Scenarios with 50, 70, and 90% external RH wer... [more]

The processing of large quantities of water in biorefining processes can lead to immense costs for heating, evaporation, and wastewater disposal. These costs may prohibit the exploitation of alternative products, e.g., xylooligosaccharides from straw, which are regarded as too costly. A new counter-current extractions method is proposed that aims at low solvent (water) consumption, as well as high yields and extract concentrations. This process was evaluated with suspension extraction experiments with steam pretreated wheat straw and the process window analysis based on a mass balance for a washing and a leaching scenario. The latter was conducted with two other suspension extraction processes as a comparison. The equilibration time was found to be well below 10 min. While the suspension extraction with and without recycling need to be designed to achieve a high yield or a high concentration and low solvent consumption, the proposed extraction method can reach all three simultaneously.... [more]

To mitigate the current global energy and the environmental crisis, biofuels such as bioethanol have progressively gained attention from both scientific and industrial perspectives. However, at present, commercialized bioethanol is mainly derived from edible crops, thus raising serious concerns given its competition with feed production. For this reason, lignocellulosic biomasses (LCBs) have been recognized as important alternatives for bioethanol production. Because LCBs supply is sustainable, abundant, widespread, and cheap, LCBs-derived bioethanol currently represents one of the most viable solutions to meet the global demand for liquid fuel. However, the cost-effective conversion of LCBs into ethanol remains a challenge and its implementation has been hampered by several bottlenecks that must still be tackled. Among other factors related to the challenging and variable nature of LCBs, we highlight: (i) energy-demanding pretreatments, (ii) expensive hydrolytic enzyme blends, and (ii... [more]

The biopreservation of meat products is of great interest due to the demand for products with low or minimal chemical additives. Lactic acid bacteria (LAB) have been used as protective cultures for many centuries. The objective of this work was to characterize 10 native LAB isolated from meat masses with biopreservative potential for meat products. The isolates were subjected to viability tests with different concentrations of NaCl, nitrite, and nitrate salts, pHs, and temperature conditions. Antibiotic resistance and type of lactic acid isomer were tested. In addition, the isolates were tested against seven pathogens, and inhibitory substances were identified by diffusion in agar wells. Finally, two isolates, Lb. plantarum (SB17) and Lb. sakei (SB3) were tested as protective cultures of chorizo in a model. As a result, the viability at different concentrations of NaCl and nitrate and nitrate salts were obtained. pH and temperature exerted a negative effect on the growth of some of the... [more]

The formation control for the effective operation of multiple vessels is discussed. First, a virtual matrix approach is proposed to improve the formation robustness and transform performance during swarm operations, which is created based on the virtual leader vessel location, and agents composing the formation follow cells in the matrix to maintain formation. This approach is affected by the virtual leader vessel location. The virtual leader vessel location is defined by two cases: matrix center and geometric center; furthermore, robustness and efficiency comparison simulations are performed. The simulation results show that in most formations, the geometric center is better in terms of efficiency and robustness. Second, the isosceles triangle guidance algorithm is proposed to improve the “go-back behavior” of certain agents during excessive maneuvering. Through a waypoint-following simulation, the algorithm is confirmed to be superior to the line-of-sight guidance algorithm. The swar... [more]

A new design of gas absorption that winds the permeable membrane onto an inner concentric tube to conduct a concentric circular gas−liquid membrane module has been studied theoretically in the fully developed region. An analytical formulation, referred to as conjugated Graetz problems, is developed to predict the concentration distribution and Sherwood numbers for the absorbent fluid flowing in the shell side and CO2/N2 gas mixture flowing in the tube side under various designs and operating parameters. The analytical solutions to the CO2 absorption efficiency were developed by using a two-dimensional mathematical modeling, and the resultant conjugated partial differential equations were solved analytically using the method of separation variables and eigen-function expansion in terms of power series. The predictions of CO2 absorption rate by using Monoethanolamide (MEA) solution in concentric circular membrane contactors under both concurrent- and countercurrent-flow operations are de... [more]

Olive Sound is the acronym of a Horizon 2020 European Project aimed at the development of a high-flow oil extraction plant, the Sono-Heat-Exchanger, which combines ultrasound and heat exchange in order to break, through a radical innovation model in the oil mill, the historical paradigm that sees as inversely correlated the oil yield and the content of bio-phenols. These compounds are biologically active molecules that transform the product, extra virgin olive oil, from a mere condiment into a functional food. The primary objective of the project, financially supported by the European Union through the “Fast Track to Innovation” program, is the development of a product “ready for the market” (TRL 9) capable of making the involved companies more competitive while increasing the competitiveness of European extra virgin olive oil in the international context.

In today’s rapidly changing and highly competitive industrial environment, a new and emerging business model—fast fashion—has started a revolution in the apparel industry. Due to the lack of historical data, constantly changing fashion trends, and product demand uncertainty, accurate demand forecasting is an important and challenging task in the fashion industry. This study integrates k-means clustering (KM), extreme learning machines (ELMs), and support vector regression (SVR) to construct cluster-based KM-ELM and KM-SVR models for demand forecasting in the fashion industry using empirical demand data of physical and virtual channels of a case company to examine the applicability of proposed forecasting models. The research results showed that both the KM-ELM and KM-SVR models are superior to the simple ELM and SVR models. They have higher prediction accuracy, indicating that the integration of clustering analysis can help improve predictions. In addition, the KM-ELM model produces sa... [more]

Metabolic flux analysis is often (not to say almost always) faced with system underdeterminacy. Indeed, the linear algebraic system formed by the steady-state mass balance equations around the intracellular metabolites and the equality constraints related to the measurements of extracellular fluxes do not define a unique solution for the distribution of intracellular fluxes, but instead a set of solutions belonging to a convex polytope. Various methods have been proposed to tackle this underdeterminacy, including flux pathway analysis, flux balance analysis, flux variability analysis and sampling. These approaches are reviewed in this article and a toy example supports the discussion with illustrative numerical results.

Nonlinear drag force has been a research frontier in complex gas-solid systems. The literature has reported that the commonly-used drag correlations often overestimate drag force and, thus, cause unrealistic homogeneous flow structures in gas-solid fluidized beds of fine particles. For solving this problem, the structure-dependent drag model, derived from energy-minimization multi-scale approach, is used in discrete simulations of fluid catalytic cracking particles in a small riser. The gas phase is dealt with by computational fluid dynamics. Particles are considered as a discrete phase and described by Newton’s second law of motion. Gas-particle phases are coupled according to Newton’s third law of motion. Simulations show that use of structure-dependent drag model results in drag reduction, the effect of which is not so apparent as that in simulations of the two fluid model. The particle clustering tendency, however, is more distinct and leads to more heterogeneous flow structures in... [more]

For a high-speed centrifugal pump, cavitation occurs easily. To equip a high-performance splitter-bladed inducer upstream of the pump is an effective method to suppress cavitation. In this paper, an external characteristics experiment of the high-speed centrifugal pump with a splitter-bladed inducer is carried out, and the corresponding numerical calculations are completed. The research shows that the results of the numerical calculation are credible. Numerical cavitation calculations under eight different tip clearance conditions are carried out. First, it is found that the tip clearance (TC) has a certain impact on the head of the centrifugal pump. When TC is in a small range, the clearance leakage is small, and the impact on the head of the pump is not so obvious, which can give the pump a higher performance. Second, it is found that TC has a certain influence on the static pressure distribution in the cascade passage of the splitter-bladed inducer. When TC is in a certain range, th... [more]

The chemical structures of pyrolytic chars prepared from 32 kinds of Chinese coals were investigated with micro-Raman spectroscopy in this study. Both first-order and second-order Raman spectra of the chars were curve-fitted and analyzed. The effects of the parent coal properties, including coal rank, volatile, fixed carbon, and ash content, on the pyrolytic char structures were detailed discussed and the correlations between these coal properties and pyrolytic char chemical structures were set up. Multiple-factor analysis was done to propose a comprehensive coal property index that relates well to the pyrolytic char chemical structure. The results indicate that the aromatization degree is the key distinguishable structure of pyrolytic chars prepared from coals with various rank, and the alkyl C−H and aryl C−H structures have no significant difference. The aromatization degree of pyrolytic char decreases with the increase of coal rank, while it increases with the increase of the fixed... [more]

The paper discusses issues related to the sectors of biofuels for transport. Development directions of those sectors and factors limiting the growth rate thereof are analysed. At present, researchers’ attention is increasingly focused on development of the alternative fuels sector. Moreover, issues related to waste used in the sector of alternative fuels are now among the leading undertakings of environmental engineering. The authors have analysed the potential of biofuels sectors in Poland taking into account the EU’s legislative requirements. The paper contains a discussion of the sector of esters, liquid biofuels, sector of lignocellulose, sector of liquid bio-hydrocarbons and, additionally, pays attention to the sector of electromobility as one of the most attractive and prospective sectors in terms of emission reduction.

The Shunbei crude oil pipeline is prepared to use the unheated transportation process to transport waxy crudes. However, the wax formation in the pipeline is unknown. In order to predict the wax deposition of the pipeline, the physical property experiment of Shunbei crude oil was carried out through field sampling. The density, freezing point, hydrocarbon composition, and viscosity−temperature characteristics of crude oil are obtained. The cloud point and wax precipitation characteristics of the crude oil were obtained using the differential scanning calorimetry (DSC) thermal analysis method. Then, the wax deposition rate of the pipeline was predicted by two methods: OLGA software and wax deposition kinetic model. Finally, the optimal pigging cycle of the pipeline was calculated on this basis. The results show that: Shunbei crude oil is a light crude oil with low wax content, a low freezing point, and a high cloud point. Comparing the OLGA simulation results with the calculation result... [more]

Compounds 2,4,6-trichloroanisole (TCA), 2,3,4,6-tetrachloroanisole (TeCA), 2,4,6-tribromoanisole (TBA) and pentachloroanisole (PCA), 2-methylisoborneol (2MIB) and geosmin (GSM) have been reported as being responsible for cork and wine taint. A sustainable method based on thermal desorption-gas chromatography−mass spectrometry (TD-GC/MS) has been developed and optimized, taking into account desorption parameters and chromatographic and mass spectrometric conditions. The combination of parameters that jointly maximized the compound detection was as follows: desorption temperature at 300 °C, desorption time at 30 min, cryo-temperature at 20 °C and trap high temperature at 305 °C. The proposed methodology showed a good linearity (R ≤ 0.994) within the tested range (from 0.1 to 2 ng) for all target compounds. The precision expressed as repeatability and reproducibility was RSD < 10% in both. The limits of quantification ranged from 0.05 to 0.1 ng. The developed methodology and the sampli... [more]

Friction materials, mainly made of reinforced composites, should possess excellent physical and tribological properties, such as a higher coefficient of friction, minimum wear, adequate surface hardness, and higher porosity for various automotive brake applications. Attainment of those properties greatly depends on the settings of different input parameters, such as molding pressure, temperature and time, temperature and time of heat treatment/sintering, etc., during the processing of friction materials. In this article, four multi-criteria decision-making (MCDM) tools, i.e., technique for order of preference by similarity to ideal solution (TOPSIS), evaluation based on distance from average solution (EDAS), VlseKriterijumska Optimizacija I Kompromisno Resenje (VIKOR), and multi-objective optimization on the basis of ratio analysis (MOORA) are applied to identify the optimal parametric combinations for two different friction materials. A comparative analysis of the derived results sugg... [more]