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Records with Type: Published Article
23917. LAPSE:2023.15217
Experimental Study on Manned/Unmanned Thermal Environment in Radar Electronic Shelter Based on Different Air Supply Conditions
March 2, 2023 (v1)
Subject: Environment
Keywords: air distribution, electronic radar shelter, manned and unmanned, temperature and wind speed, thermal environment
Studies on the thermal environment of the electronic radar shelter have been mainly focused on the simulation of the unmanned thermal environment, and there have been few studies on experiments in the thermal environment. Additionally, a comparative study of the experimental results from manned and unmanned shelters has been missing. In this paper, we experimented in thermal environments of manned/unmanned shelter under different air supply conditions. The experiment was divided into cooled, ventilated, and heated trials analyzing three aspects: (1) The average temperature distributions of walls, air inlet points, air outlet points, and surfaces were measured over time under different conditions in an unmanned shelter. The temperature distribution curve was fitted into the function. (2) Based on different working conditions, the temperature distribution experiments were carried out in three different areas for subjects wearing short or long clothing respectively. (3) The wind speed was... [more]
23918. LAPSE:2023.15216
Alternative Solutions for Small Hydropower Plants
March 2, 2023 (v1)
Subject: Energy Systems
Keywords: permanent magnet generator, semi-Kaplan turbine, small hydropower plants, variable speed generation
Obtaining energy from renewable resources is a worldwide trend in the age of increasing energy demand. Hydropower has some potential in this field, especially for low-power locations. However, construction of such facilities requires high expenses, which is why some attempts at lowering the costs have been made, i.e., by proposing alternative solutions to the classic ones. This paper proposes a selection of options for small hydropower plants (SHP) that lower the investment costs while keeping up profitable operations. The proposed solutions concern simplifying the turbine’s and generator’s integration by installing them in dedicated prefabricated concrete modules. A rare but simple and cheap semi-Kaplan type of turbine with a non-classical spiral inflow is proposed. The turbine operates a permanent magnet (PM)-excited generator, converting the energy at a variable rotational speed. Thanks to this approach, it is possible to simplify the regulation system and eliminate expensive mechan... [more]
23919. LAPSE:2023.15215
Properties of Animal-Origin Ash—A Valuable Material for Circular Economy
March 2, 2023 (v1)
Subject: Materials
Keywords: animal-origin biomass, ash characterization, Biomass, biomass ash, chicken litter, chlorine corrosion, cow manure, SEM, slagging
In the presented paper, two types of animal-origin biomass, cow dung and chicken litter, are characterized in terms of combustion-related problems and ash properties. It was found that these parameters strongly depend on the farming style. Whether it is cow dung or chicken litter, free-range raw materials are characterized by higher ash contents than industrial farming ones. Free-range samples contain chlorine at lower levels, while industrial farming samples are chlorine rich. Free-range samples are characterized by the predominant content of silica in the ash: 75.60% in cow dung and 57.11% in chicken litter, while industrial farming samples contain more calcium. Samples were classified by 11 “slagging indices” based on the ash and fuel composition to evaluate their tendencies for slagging, fouling, ash deposition and bed agglomeration. Furthermore, an assessment was made against the current EU law regulations, whether the ashes can be component materials for fertilizers. The phosphor... [more]
23920. LAPSE:2023.15214
Microwave-Assisted Pyrolysis of Leather Waste
March 2, 2023 (v1)
Subject: Materials
Keywords: bioproduct, chromium salt tannin, compound distribution, fraction composition, leather waste, microwave-assisted pyrolysis, physical recovery, vegetable tannins
The processing of leather into leather is one of the oldest known manufacturing practices. The subsequent refinement of this technique over recent centuries has led to an increase in production, which in turn has led to an increase in waste production. Today, many of the by-products and waste streams from the leather industry have applications in industries such as petfood and in the production of collagen and derivatives, while others, such as waste from trimming and scraping the material, are disposed of in landfills, causing a detrimental environmental impact. For this reason, new alternatives for the treatment of these wastes, such as pyrolysis, are being investigated. The aim of this work is to assess the feasibility of recovering non-recyclable waste from the leather industry by pyrolysis. Waste from the tanning of cowhides with vegetable tannins and tanning with chrome salts, without pre-treatment, were used as raw materials. The operating conditions of the microwave-assisted py... [more]
23921. LAPSE:2023.15213
HPC Geophysical Electromagnetics: A Synthetic VTI Model with Complex Bathymetry
March 2, 2023 (v1)
Subject: Modelling and Simulations
Keywords: electromagnetic geophysical, high-order methods, HPC, numerical simulations, tailored meshes
We introduce a new synthetic marine model for 3D controlled-source electromagnetic method (CSEM) surveys. The proposed model includes relevant features for the electromagnetic geophysical community such as large conductivity contrast with vertical transverse isotropy and a complex bathymetry profile. In this paper, we present the experimental setup and several 3D CSEM simulations in the presence of a resistivity unit denoting a hydrocarbon reservoir. We employ a parallel and high-order vector finite element routine to perform the CSEM simulations. By using tailored meshes, several scenarios are simulated to assess the influence of the reservoir unit presence on the electromagnetic responses. Our numerical assessment confirms that resistivity unit strongly influences the amplitude and phase of the electromagnetic measurements. We investigate the code performance for the solution of fundamental frequencies on high-performance computing architectures. Here, excellent performance ratios ar... [more]
23922. LAPSE:2023.15212
A Comprehensive Assessment of Fundamental Overcurrent Relay Operation Optimization Function and Its Constraints
March 2, 2023 (v1)
Subject: Optimization
Keywords: coordination time interval, overcurrent relays, plug settings, protection optimization, time multiplier settings
The optimization of overcurrent relays’ operation is a topic associated with protection coordination of distribution networks. Usually, this refers to medium-voltage networks, since they are protected by numerical relay devices, as opposed to low-voltage networks, where utility operators allocate fuses. Correct setting of relays and optimal coordination is becoming a serious challenge to Distribution Network Operators around the world, since their networks’ passive operation has been greatly altered in the past two decades. Distributed generation units, a growing liberalized electricity market and more stringent legislation for distribution network planning and operation by state regulatory bodies have all indirectly affected the evolving of protection philosophy for distribution networks. In this paper the traditional optimization problem of overcurrent relay operation will be addressed and critically examined from both a theoretical and practical point of view. Optimization function,... [more]
23923. LAPSE:2023.15211
Energy Production from Biodegradable Waste as an Example of the Circular Economy
March 2, 2023 (v1)
Subject: Environment
Keywords: biogas plants, circular economy, renewable energy sources, waste management
A growing population, technological progress and economic development result in a constant increase in energy demand. Energy is mostly obtained from fossil energy resources such as coal, natural gas, and crude oil. Burning them leads to air pollution with greenhouse gases (CO2, CH4, NH3 and N2O) and dust (PM2.5 and PM10). They are recognized as the cause of global warming and air pollution. Wind, water, solar and biomass energy are used to eliminate harmful emissions. The latter may come from special plant crops or from biodegradable waste from farming, animal husbandry, the agrifood industry and households. These wastes are transformed into biogas in biogas plants, the basic ingredient of which is methane. Most often, biogas is burned in a cogeneration process, providing electricity and heat. After purification of admixtures, it can be injected into the high-methane gas network or converted into hydrogen in the steam reforming process. In this way, environmentally harmful waste become... [more]
23924. LAPSE:2023.15210
Benchmarking Approaches for Assessing the Performance of Building Control Strategies: A Review
March 2, 2023 (v1)
Subject: Process Control
Keywords: building controls, building simulation, control benchmarking, control test bench, HVAC control
In the last few decades, researchers have shown that advanced building controllers can reduce energy consumption without negatively impacting occupants’ wellbeing and help to manage building systems, which are becoming increasingly complex. Nevertheless, the lack of benefit awareness and demonstration projects undermines stakeholders’ trust, justifying the reluctance to approve new controls in the industry. Therefore, it is necessary to support the development of controls through solid arguments testifying to the performance gain that can be achieved. However, the absence of standardized and systematic testing methods limits the generalization of results and the ability to make fair cross-study comparisons. This study presents an overview of the different benchmarking approaches used to assess control performance. Our goal is to highlight trends, limitations, and controversies through analytics to support the definition of best practices, which remains a widely discussed topic in this... [more]
23925. LAPSE:2023.15209
Distribution Law of In Situ Stress and Its Engineering Application in Rock Burst Control in Juye Mining Area
March 2, 2023 (v1)
Subject: Energy Systems
Keywords: anti-impact support, coal mining, coal resources, coal roadway support, high static stress, in-situ stress, Juye mining area, mining layout, rock burst
This paper presents an integrated approach for mathematical statistics, theoretical analysis, and a field test to investigate the distribution law of in-situ stress and its engineering practice of rock burst control. The test site is located in the Juye mining area, Shandong Province, China. The main conclusions included: (1) There are two types of in-situ stress states in the Juye mining area, σH > σV > σh (42.42%) and σH > σh > σV (57.57%), which are mainly caused by the tectonic stress of the Heze and Fushan faults (The σH, σV, and σh is the maximum principal stress, vertical principal stress or intermediate principal stress and minimum principal stress respectively). (2) The lateral pressure coefficients KH, Kh, and Kav show a non-linear distribution with increased depth, approaching 1.32, 0.96, and 1.41, respectively. The variation range of the horizontal difference stress μd is 0.09−0.58. (3) The average value of the stress gradient is 3.05 MPa/100 m, and the main directions of t... [more]
23926. LAPSE:2023.15208
Relationship Analysis and Optimisation of Space Layout to Improve the Energy Performance of Office Buildings
March 2, 2023 (v1)
Subject: Process Design
Keywords: correlation analysis, design of experiments, energy performance, optimisation, space layout
Architectural space layout has proven to be influential on building energy performance. However, the relationship between different space layouts and their consequent energy demands has not yet been systematically studied. This study thoroughly investigates such a relationship. In order to do so, a computational method was developed, which includes a method to generate space layouts featuring energy-related variables and an assessment method for energy demand. Additionally, a design of experiments was performed, and its results were used to analyse the relationship between space layouts and energy demands. In order to identify their relationship, four types of design indicators of space layout were proposed, both for the overall layout and for each function. Finally, several optimisations were performed to minimise heating, cooling and lighting demands. The optimisation results showed that the maximum reduction between different layouts was up to 54% for lighting demand, 51% for heatin... [more]
23927. LAPSE:2023.15207
Effects of Air Supply Terminal Devices on the Performance of Variable Refrigerant Flow Integrated Stratum Ventilation System: An Experimental Study
March 2, 2023 (v1)
Subject: Environment
Keywords: air diffusion performance index (ADPI), air supply terminal device (ASTD), airflow pattern, thermal comfort, VRF-SV hybrid system
A variable refrigerant flow integrated stratum ventilation (VRF-SV) system was proposed as an energy efficient substitute for conventional central cooling systems for buildings. The novel system provided conditioned air to enclosed spaces with high indoor air quality and thermal comfort. This study investigated the effects of different types of ASTDs on the performance of the VRF-SV hybrid system. The performance was experimentally evaluated with five air terminal types, including bar grille, double deflection grille, jet slot, perforated and drum louver diffusers. The evaluation was carried out using standard indices: temperature and velocity distribution, airflow pattern, effective draft temperature (EDT), air distribution performance index (ADPI), thermal sensation vote and comfort feedback survey. The results indicated that the ASTD type had a significant impact on airflow pattern. Furthermore, the bar grille diffuser provided the occupants with greater thermal comfort and acceptab... [more]
23928. LAPSE:2023.15206
Application of Machine Learning Models for Fast and Accurate Predictions of Building Energy Need
March 2, 2023 (v1)
Subject: Modelling and Simulations
Keywords: building energy saving solutions, building energy simulation, Machine Learning, optimisation algorithms
Accurate prediction of building energy need plays a fundamental role in building design, despite the high computational cost to search for optimal energy saving solutions. An important advancement in the reduction of computational time could come from the application of machine learning models to circumvent energy simulations. With the goal of drastically limiting the number of simulations, in this paper we investigate the regression performance of different machine learning models, i.e., Support Vector Machine, Random Forest, and Extreme Gradient Boosting, trained on a small data-set of energy simulations performed on a case study building. Among the XX algorithms, the tree-based Extreme Gradient Boosting showed the best performance. Overall, we find that machine learning methods offer efficient and interpretable solutions, that could help academics and professionals in shaping better design strategies, informed by feature importance.
23929. LAPSE:2023.15205
Energy-Based Approaches in Estimating Actual Evapotranspiration Focusing on Land Surface Temperature: A Review of Methods, Concepts, and Challenges
March 2, 2023 (v1)
Subject: Energy Systems
Keywords: evapotranspiration, land surface models, land surface temperature, surface energy balance algorithms
The surface energy balance (SEB) model is a physically based approach in which aerodynamic principles and bulk transfer theory are used to estimate actual evapotranspiration. A wide range of different methods have been developed to parameterize the SEB equation; however, few studies addressed solutions to the SEB considering the land surface temperature (LST). Therefore, in the current review, a clear and comprehensive classification is provided for energy-based approaches considering the key role of LST in solving the energy budget. In this regard, three general approaches are presented using LSTs derived by climate and land surface models (LSMs), satellite-based data, and energy balance closure. In addition, this review surveys the concepts, required inputs, and assumptions of energy-based LSMs and SEB algorithms in detail. The limitations and challenges of aforementioned approaches including land surface temperature, surface energy imbalance, and calculation of surface and aerodynam... [more]
23930. LAPSE:2023.15204
Effectiveness of Electricity-Saving Communication Campaigns: Neurophysiological Approach
March 2, 2023 (v1)
Subject: Process Design
Keywords: cognitive neuroscience, EEG, electricity saving, media message effectiveness, public communication campaign
Public communication campaigns are among the tools for promoting electricity saving. A crucial task in the process of creating a campaign is to design a simple message to effectively reach the average consumer. It is a beneficial practice to create alternative messages and pretest them to find the most effective. The research methodology during pretesting includes both quantitative and qualitative methods. However, it is believed that the outcomes obtained with the use of conventional techniques are not fully reliable. Therefore, the following question arises: What additional research methods should be applied at the stage of testing the message of a communication campaign so that its effectiveness can be assessed more reliably and/or improved even before its broadcast? In this study, we aim to present the possibility of applying cognitive neuroscience methods in conjunction with a questionnaire to experimentally check the effectiveness of the message using the example of selected elec... [more]
23931. LAPSE:2023.15203
Extended Residential Power Management Interface for Flexibility Communication and Uncertainty Reduction for Flexibility System Operators
March 2, 2023 (v1)
Subject: Energy Systems
Keywords: electric vehicle, flexibility calculation, flexibility manager, power management system, smart energy system, smart grid
The high importance of demand-side management for the stability of future smart grids came into focus years ago and is today undisputed among a wide spectrum of energy market participants, and within the research community. The increasing development of communication infrastructure, in tandem with the rising transparency of power grids, supports the efforts for deploying demand-side management applications. While it is then accepted that demand-side management will yield positive contributions, it remains challenging to identify, communicate, and access available flexibility to the flexibility managers. The knowledge about the system potential is essential to determine impacts of control and adjustment signals, and employ temporarily required demand-side flexibility to ensure power grid stability. The aim of this article is to introduce a methodology to determine and communicate local flexibility potential of end-user energy systems to flexibility managers for short-term access. The pr... [more]
23932. LAPSE:2023.15202
Recovery of Trains’ Braking Energy in a Railway Micro-Grid Devoted to Train plus Electric Vehicle Integrated Mobility
March 2, 2023 (v1)
Subject: Energy Systems
Keywords: dual active bridge (DAB) converter, electric vehicles charging station, energy and power measurement, energy recovery, energy storage system, high frequency transformer, railway micro-grid, railway system, regenerative braking, wayside energy recovery system
This paper deals with the energy recovery resulting from the braking transient of trains arriving in a railway station, to feed a railway micro-grid that would be purposely connected to the railway traction circuit to feed the electrical infrastructure required for charging a fleet of electrical vehicles that are parked nearby the station and offered for providing train plus electric vehicle integrated mobility. Based on results of an experimental campaign intended to recording the mechanical quantities related to the braking transient of regional trains arriving in a medium-size station of the Italian railways network, this paper describes a suitable quasi-stationary model that allows the evaluation of the amount of energy that is recoverable over each single day of operation, as well as the micro-grid dynamic electric behaviour due to the sudden energy recovery transient in the railway catenary. The proposed railway micro-grid is discussed, particularly concerning the configuration o... [more]
23933. LAPSE:2023.15201
Efficiency Enhancement of Tilted Bifacial Photovoltaic Modules with Horizontal Single-Axis Tracker—The Bifacial Companion Method
March 2, 2023 (v1)
Subject: Energy Systems
Keywords: bifacial companion, bifacial photovoltaic module, fixed/tracking solar reflector, light supplementation and efficiency enhancement, photovoltaic support system, tilted horizontal single-axis tracker
Bifacial photovoltaic modules combined with horizontal single-axis tracker are widely used to achieve the lowest levelized cost of energy (LCOE). In this study, to further increase the power production of photovoltaic systems, the bifacial companion method is proposed for light supplementation and the efficiency enhancement of tilted bifacial modules with a horizontal single-axis tracker. Specifically, a solar reflector is added to the rear end of the tilted bifacial photovoltaic module to guide the sunlight and promote power generation on the rear end. The technical feasibility of the proposed method is verified through optimal calculation and prototype experimental test. The theoretical calculation results suggest that the bifacial companion system is particularly suitable for mid-to-high latitude areas. The higher the latitude, the higher the gain ratio of generated power in the system; there is an optimal module tilt angle that maximizes the efficiency at different latitudes. The c... [more]
23934. LAPSE:2023.15200
Appropriate Technology-Based AMI Deployment in Multi-Dwelling Units
March 2, 2023 (v1)
Subject: Environment
Keywords: advanced metering infrastructure, automated meter reading, energy-as-a-service, measurement, remote metering, smart meter
Digital technologies, especially information and communication technologies, paved the way for social welfare by providing efficient and effective means for services. In the energy sector, advanced metering infrastructures (AMIs) are essential for providing various services through information measurement. In this article, we focus on the deployment of an AMI in multi-dwelling units where automated meter reading (AMR) infrastructures are installed. In particular, we explore whether the AMR should substitute the AMI with few alterations, while ensuring desirable accuracy. To determine the adequacy of technology, information measurement performance, service performance, and implementation cost are used as the indicators. Through a case study using real data recorded in Korea, we quantitatively estimate that AMR-based information measurement can exhibit adequate performance and performance degradation of less than 1% in a service environment utilizing AMI with a low-cost investment. We al... [more]
23935. LAPSE:2023.15199
The Influence of New and Old Energy Labels on Consumer Judgements and Decisions about Household Appliances
March 2, 2023 (v1)
Subject: Energy Systems
Keywords: energy efficiency classes, energy labeling system, household appliances, perception of energy labels
Energy efficiency is an increasingly important dimension of household appliances, which is why they are labeled to indicate their energy consumption. In 2020, the European Union countries changed the labeling system from the previous system: ranging from A+++ to D, to the new system: ranging from A to G, assuming it would be more transparent for the consumer. The aim of the study was to find out the extent to which consumers are aware of the new labeling system, and the impact that the new labels have (compared to the previous ones) on the perception of household appliances and consumer decision-making. For this purpose, the survey was conducted on a nationwide representative Polish sample (n = 1054). The research was partly experimental, where the same appliances were presented with new and previous energy labels. The results showed that currently most people do not identify the new energy classes. Furthermore, products with the new labels are perceived as being less energy efficient... [more]
23936. LAPSE:2023.15198
Assessment on the Cost Synergies and Impacts among Measures on Energy Conservation, Decarbonization, and Air Pollutant Reductions Using an MCEE Model: A Case of Guangzhou, China
March 2, 2023 (v1)
Subject: Environment
Keywords: air pollutants reduction, cost synergies, decarbonization, energy saving, urban sustainability
Many challenges are faced in the process of urban sustainable development, including the continuous growth in energy demand and rapid increase in CO2 and air pollutant emissions. This study focuses on the costs of measures to address these issues and establishes a multi-objective comprehensive assessment model for energy saving, CO2, and pollutant emission (MCEE). Taking Guangzhou as an example, the sustainable development measures are divided into three categories, energy-saving, demand-optimization, and environmental-protection. Five scenarios are set to quantitatively evaluate the costs when these measures are implemented alone or coordinately for the period 2015−2035. Conclusions are as follows: (1) Measures of energy-saving and demand-optimization have the best synergistic effect on energy saving and emission reduction. The synergistic benefits include an 80% and 84% increase in energy savings and CO2 reductions, respectively, and more than 50% increase in pollutant reductions. (2... [more]
23937. LAPSE:2023.15197
An Online Data-Driven LPV Modeling Method for Turbo-Shaft Engines
March 2, 2023 (v1)
Subject: Energy Systems
Keywords: data-driven method, linear parameter-varying model, online sequential extreme learning machine (OS-ELM), turbo-shaft engine
The linear parameter-varying (LPV) model is widely used in aero engine control system design. The conventional local modeling method is inaccurate and inefficient in the full flying envelope. Hence, a novel online data-driven LPV modeling method based on the online sequential extreme learning machine (OS-ELM) with an additional multiplying layer (MLOS-ELM) was proposed. An extra multiplying layer was inserted between the hidden layer and the output layer, where the hidden layer outputs were multiplied by the input variables and state variables of the LPV model. Additionally, the input layer was set to the LPV model’s scheduling parameter. With the multiplying layer added, the state space equation matrices of the LPV model could be easily calculated using online gathered data. Simulation results showed that the outputs of the MLOS-ELM matched that of the component level model of a turbo-shaft engine precisely. The maximum approximation error was less than 0.18%. The predictive outputs o... [more]
23938. LAPSE:2023.15196
Mechanism of Magnetic Nanoparticle Enhanced Microwave Pyrolysis for Oily Sludge
March 2, 2023 (v1)
Subject: Materials
Keywords: kinetics simulation, magnetic nanoparticles, microwave pyrolysis, oily sludge, thermogravimetric analysis
In view of the high dielectric constant of magnetic nanoparticles, this paper intends to use it as a new type of microwave absorbing medium to accelerate the microwave pyrolysis process of oily sludge. Microwave thermogravimetric reaction and pyrolysis product staged collection devices were established, respectively. The main stage of pyrolysis process of oily sludge was divided based on the thermogravimetric experiments. Mechanism was studied through the characteristics of pyrolysis products and reaction kinetics simulation. Experimental results showed that the addition of magnetic ZnFe2O4 particle did not change the microwave pyrolysis process of oily sludge and the pyrolysis efficiency could be improved. Pyrolysis process was divided into three stages, rapid heating and water evaporation stage (20~150 °C), light component evaporation stage (150~240 °C) and heavy component cracking stage (240~300 °C). Due to the addition of magnetic ZnFe2O4 particles, the content of C4~C12 increased... [more]
23939. LAPSE:2023.15195
Using Group Predictive Voltage and Frequency Regulators of Distributed Generation Plants in Cyber-Physical Power Supply Systems
March 2, 2023 (v1)
Subject: Process Control
Keywords: automatic speed regulator, automatic voltage regulator, cyber-physical power supply systems, distributed generation plant, group regulation, Modelling, predictive control algorithms, synchronous generator
The widespread use of distributed generation (DG) plants in cyber-physical power supply systems (CPPSS) requires solving the complex problem of setting their regulators. The presented study aimed to determine the performance of the group predictive voltage and frequency regulators of DG plants in CPPSS. These studies were conducted in the MatLab environment on the CPPSS models with gas turbine units and with a small-scale hydroelectric power plant. The proposed method for tuning group predictive regulators makes it possible to improve the quality control indices. The research has established that with an additional load connected, the maximum voltage dip is reduced by a factor of 3.5 compared to conventional control regulators. In addition, the time of a transient process for the generator rotor speed is decreased by a factor of 3. In the case of a short-term short circuit, predictive regulators can reduce the time of the transient process by a factor of 1.5 and the overshoot by more t... [more]
23940. LAPSE:2023.15194
Advanced Ensemble Methods Using Machine Learning and Deep Learning for One-Day-Ahead Forecasts of Electric Energy Production in Wind Farms
March 2, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: deep neural network, electric energy production, ensemble methods, Machine Learning, short-term forecasting, swarm intelligence, wind energy, wind farm
The ability to precisely forecast power generation for large wind farms is very important, since such generation is highly unstable and creates problems for Distribution and Transmission System Operators to properly prepare the power system for operation. Forecasts for the next 24 h play an important role in this process. They are also used in energy market transactions. Even a small improvement in the quality of these forecasts translates into more security of the system and savings for the economy. Using two wind farms for statistical analyses and forecasting considerably increases credibility of newly created effective prediction methods and formulated conclusions. In the first part of our study, we have analysed the available data to identify potentially useful explanatory variables for forecasting models with additional development of new input data based on the basic data set. We demonstrate that it is better to use Numerical Weather Prediction (NWP) point forecasts for hourly la... [more]
23941. LAPSE:2023.15193
Enhanced OH− Conductivity for Fuel Cells with Anion Exchange Membranes, Based on Modified Terpolymer Polyketone and Surface Functionalized Silica
March 2, 2023 (v1)
Subject: Energy Systems
Keywords: alkaline stability, anion exchange membrane, chemical modification, Fuel Cells, functionalized silica, polyketone
Several modified terpolymer polyketones (MPK) with N-substituted pyrrole moieties in the main chain and quaternized amine in the side group were synthesized for use as anion exchange membranes for fuel cells. The moieties were carried by SiO2 nanoparticles through surface functionalization (Si−N), which were added to the membranes to enhance their overall properties. On increasing the amount of modified silica from 10% to 60% wt/of MPK, there was an increase in Si−N and a corresponding threefold increase in the hydroxide conductivity of the membrane. The MPK−SiN (60%) exhibited a superior ionic conductivity of 1.05 × 10−1 S.cm−1 at 120 °C, a high mechanical stability, with a tensile strength of 46 MPa at 80 °C. In strongly alkaline conditions (1 M KOH, 216 h at 80 °C), the membranes maintained about 70% of the conductivity measured in a usual environment. Fuel cell performance at 80 °C showed a peak power density of 133 mW·cm−2, indicating that using surface-functionalized SiO2 is a si... [more]
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