In a ball screw feed system of high-speed/high-acceleration machine tools, large frictional and inertial forces may change the real contact state of the kinematic joints, resulting in changes in the contact and transmission stiffnesses and, hence, changes in the dynamic characteristics of the system. In this study, a variable−coefficient dynamic modeling method for a ball screw feed system is proposed, considering the influence of changes in the no-extra-load running states, such as position, speed, and acceleration. Based on Timoshenko beam elements with two nodes and four DOFs, an equivalent dynamic model of a ball screw feed system is established using the hybrid element method. The expression for the equivalent axial stiffness of individual kinematic joints is derived, considering the influence of the feed speed/acceleration under the no-extra-load running state of the system. In addition, the stiffness and mass of the screw shafts on both sides of the screw nut are calculated, con... [more]

This article summarizes the arguments surrounding the scientific discussion of the cement production process at a selected company in Slovakia. (1) The main goal of this article is to evaluate the quality of the cement production process with the intention of increasing the performance and quality of the process and the quality of the cement in various assortments. The object of this research was a selected company in Slovakia which focuses on cement production. (2) The methods of research were focused on using statistical, economic, and financial analyses and instruments of quality management, such as the Ishikawa diagram, regression diagram, correlation, and box plot diagram. The relevance of the decision of this scientific research relating to the innovation of the cement production process focused on Industry 4.0 requirements. (3) This paper presents the results of the clinker CaOF content and LS and their quality. These components are used for cement products and are responsible f... [more]

Agro-industrial discharge contains acetimidothioic acid, which is commercially named “Lanox 90” and is a widely applied insecticide in greenhouses, and the result is wastewater loaded with this insecticide. Treating such wastewater is a must to reduce the environmental impact as well as to facilitate the opportunity for water recycling. Thus, the present work introduced Montmorillonite (MMT) clay as a novel Fenton reaction source to treat wastewater loaded with Lanox 90 insecticide as a benign sustainable strategy. Scanning electron microscopy (SEM) supported with energy-dispersive X-ray spectroscopy (EDX) and Fourier-transform infrared spectroscopy (FTIR) were used to characterize the MMT sample. Response surface methodology based on Box−Behnken analysis was selected to optimize the parametric circumstances. The optimized parameters of the proposed technique were obtained at a pH of 2.6 with the addition of 0.8 and 854 mg/L of MMT and H2O2, respectively, to attain the highest predicte... [more]

Since the requirement for a material cutting process occurs in a wide variety of applied contemporary manufacturing, the cutting stock problem plays a critical role in optimizing the amount of raw material utilized in everyday production operations. In this paper, we address the two-dimension strip-cutting problem and implement the graph compression technique to improve the performance of the arc-flow formulation. The number of variables of the obtained mathematical model are substantially reduced. A comparative study on a large set of benchmark instances shows that our compressed model yields very good results for the non-unitary item demand case in contrast to the state-of-the-art mathematical models. Moreover, improved bounds are provided for 24 unsolved benchmark instances, among which 8 have been solved to optimality.

Synthetic plant of chemicals (SPC) consumes large amounts of hydrogen and carbon-oxides while refineries require high-purity hydrogen. Coal gasification (CG) and steam methane reforming (SMR) are common industrial hydrogen production technologies. Their gas products are essentially a mixture of H2, CO, and CO2. Therefore, such gas products can provide both syngas for SPC and concentrated hydrogen for refinery through appropriate allocation. Based on the composition complementation of gas products from CG and SMR for their efficient utilization, this paper proposed an integration methodology for refinery and SPC coupling networks to conserve both fossil fuel resources and carbon emissions. A superstructure is established as a problem illustration and a nonlinear programming model (NLP) is formulated as a mathematical solution. A case study is performed, and the results show that the coupling network integration can save 19.1% and 20.2% of coal and natural gas consumption, as well as cor... [more]

Dyes used in textiles, foods, cosmetics, and chemicals have become a major environmental pollution issue around the world. To address this issue, a number of technologies have been created to remove these pollutants from the environment. Due to their superior properties at nanoscale, numerous nanomaterials have been applied to remove dyes from polluted waters. This research presents the findings of the development of bentonite nano zero-valent iron (B-nZVI) for the treatment of synthetic cationic dyes. This study has three objectives: (i) to produce bentonite nano zero-valence iron (B-nZVI), (ii) to characterize its adsorbents (B-nZVI), (iii) to characterize its adsorption capacity. Four main tests were used for this purpose: (i) a physical test (Brunauer−Emmett−Teller (BET) surface area), (ii) a chemical test (cation exchange capacity (CEC) and X-ray fluorescence (XRF)), (iii) morphology (field emission scanning electron microscopy (FESEM) and (iv) mineralogy (Fourier transform infrar... [more]

A mathematical model for the pre-cooling process was established to solve the problems of the long pre-cooling time and uncertain parameters of cryogenic propellant tanks. The pre-cooling parameters of a 300 m3 liquid hydrogen tank at several cooling rates were calculated and analyzed. The results show that the liquid hydrogen flow required to pre-cool the gas in the tank, tank wall, accessories, and interlayer thermal insulation materials increases first and then decreases and that the liquid hydrogen flow needed to offset the heat leakage gradually increases with the temperature reduction. When the average cooling rate rose from 0.1 K/min to 1 K/min, the pre-cooling time was shortened from 2730 min to 273 min, and the consumption of liquid hydrogen decreased from 2115 kg to 2091 kg. Among the various heat loads, the inner tank wall and accessories consumed the most significant proportion of liquid hydrogen, accounting for 87.84% to 88.61%. The cooling capacity was derived from the li... [more]

Acoustic emission (AE) technology has the advantage of online localization to study the change laws of AE in the process of coal spontaneous combustion and to reveal the generation mechanisms of AE signal during the process of heating and rupture of coal body from a microscopic perspective. This paper first constructs a large-scale coal spontaneous combustion AE test system and conducts experimental tests on the AE signal in the process of coal spontaneous combustion. The results show that with the increase of temperature in the process of coal spontaneous combustion, the AE signal shows a trend of increasing fluctuations. Low-temperature nitrogen adsorption experiments studied the pore structure of coal spontaneous combustion, and the results showed a correspondence between the development of pores and the temperature of coal spontaneous combustion. Further, through the analysis of the evolution of the pore structure of coal through Fourier transform and fractal theory, it is found th... [more]

Starting from bioethanol it is possible, by using an appropriate catalyst, to produce ethyl acetate in a single reaction step and pure hydrogen as a by-product. Two molecules of hydrogen can be obtained for each molecule of ethyl acetate produced. The mentioned reaction is reversible, therefore, it is possible to hydrogenate ethyl acetate to reobtain ethanol, so closing the chemical cycle of a Liquid Organic Hydrogen Carrier (LOHC) process. In other words, bioethanol can be conveniently used as a hydrogen carrier. Many papers have been published in the literature dealing with both the ethanol dehydrogenation and the ethyl acetate hydrogenation to ethanol so demonstrating the feasibility of this process. In this review all the aspects of the entire LOHC cycle are considered and discussed. We examined in particular: the most convenient catalysts for the two main reactions, the best operative conditions, the kinetics of all the reactions involved in the process, the scaling up of both eth... [more]

Submerged arc welding is a complex metallurgical system involving various phases with a temperature higher than 2000 °C. Since the hot weld pool is shielded beneath the flux, thermodynamic investigation on the O content variation during the welding process remains nebulous. Within this framework, a thermodynamic approach has been proposed to estimate the variation tendency of O content in metal during the overall submerged arc welding process. The modeling is based on the assumptions of Oxygen Layer Theory, Local Attained Equilibrium, and Scheil Solidification. The simulated and measured data show that this approach is capable of predicting the variation of the O content roadmap when typical CaO−Al2O3 based fluxes are employed. Then, factors pertinent to the level of O content are evaluated from thermodynamic perspectives. Additionally, it is revealed that the decomposition mechanisms of the oxides in welding can be constrained via the incumbent approach.

The very useful organic solvent 2-octanol is widely employed in the industry, and the direct hydration of olefins is an important method for its production. However, a slow transfer rate during a reaction due to the poor mutual solubility of the reactants is a problem; a cosolvent can be used to solve it. In this study, the feasibility of using the direct hydration of 1-octene via a catalytic distillation process using 1,4-dioxane as a cosolvent was investigated. First, the COSMOtherm program was used to identify and screen many typical cosolvents. Subsequently, the kinetics of the direct hydration reaction of 1-octene using 1,4-dioxane as a cosolvent and an HZSM-5 molecular sieve as the catalyst were determined experimentally. Finally, kinetic and thermodynamic models were utilized to create non-reactive and reactive residual curve maps to assess the feasibility of proceeding with the reaction. Applying a suitable Damköhler number (Da) value and the residual curve changes demonstrated... [more]

Slags from the ferrous and nonferrous metallurgical industries have been used to treat toxic contaminants in water and wastewater. Using slag as a recycling or renewable resource rather than a waste product has environmental and economic benefits. Recycled smelter slags can be used in both in situ and ex situ treatment. However, their application has some limitations. One of the challenges is how to handle spent slag adsorbents, as they contain the accumulation of solid waste loaded with high concentrations of toxic contaminants. These challenges can be overcome by regeneration, recycling, reuse, and immobilization treatment of spent slag adsorbents. The present paper explored the scientific and technical information about the composition, reaction mechanisms, adsorption capacity, and opportunities of recycled slags while adsorbing toxic compounds from contaminated water. It comprehensively reviewed the current state of the art for using smelting slags as sustainable adsorbents for wat... [more]

Plastic collapse and buckling are the key structural failure criteria in 3D concrete printing (3DCP). This study aims to analyze the effect of different geometrical designs and printing factors on the buildability performance of 3DCP structures. Due to the high number of variables involved, the Design of Experiment (DOE) has been used to reduce the number of simulations. In geometrical design parameters, the structure’s design is more sensitive, followed by the width and length of the printed design. The buildability increases when we move from sharp corners to more stable structures like fillets and circular geometry. For geometrical design parameters, a maximum buildability of 74% of the designed height is achieved for circular design with the highest width and lowest diameter. For printing parameters, the highest buildability of 486 mm (81%) is achieved for the lower values of printing speed and layer height. The study analyzed failure phenomena of buckling and yield strength for th... [more]

Probiotic strains such as Lactobacillus spp. are already known for their beneficial effect on human health and new research supports their role in colon cancer prevention and treatment. The current study reports the effect of different concentrations of Lacticaseibacillus rhamnosus (LGG, 106−109 CFU/mL), alone or in association with 5-fluorouracil (5-FU, 10 μM), tested against normal HaCaT cells, HT-29 colorectal adenocarcinoma and HCT-116 colorectal carcinoma cell lines. The underlying cytotoxic effect was further investigated. LGG treatment of HT-29 and HCT-116 cells caused a variety of apoptotic-related nuclear morphological changes, as revealed by DAPI staining. ELISA studies showed that LGG treatment increased caspase-3 activity and pro-apoptotic BAX protein levels while decreasing anti-apoptotic Bcl-2 protein levels and the proto-oncogene Cyclin D1. A more detailed examination of the mitochondrial function revealed that high concentrations of LGG can impair mitochondrial function... [more]

Geological carbon sequestration is a proven method of safely storing carbon dioxide in formations, thereby reducing atmospheric carbon imprint and mitigating global warming. The relative permeability to carbon dioxide versus brine/water in geological formations determines flow characteristics of one fluid in the presence of another. The objective of this research is to evaluate the relative permeability to carbon dioxide in both the gas phase and the supercritical state in the presence of water in a Vedder sandstone core sample. The sandstone sample used is medium- to fine-grain arkosic artenite containing primarily quartz, potassium feldspar, plagioclase, and biotite. The effect of the viscosity ratio between the non-wetting phase and the wetting phase, on the relative permeability to the non-wetting phase, is studied. Computational fluid dynamics (CFD) is used for this study. Results show that with the same amount of irreducible water fraction, the endpoint relative permeability to t... [more]

There are many criticisms for the association between the Six Sigma concept and the two statistical metrics associated to 6σ processes: 1.5σ shift for maximum deviation and 3.4 PPM non-conformities for the long-term performance. As a result, the paper aims to carry out an analysis of this problem, and the first result obtained is that a stable process can reach a maximum drift, but its value depends on the volume of the sample. It is also highlighted that, using only the criterion “values outside the control limits” for monitoring stability through the Xbar chart, a minimum value can be calculated for the long-term performance of a process depending on the sample size. The main conclusion resulting from the calculations is that, in the case of a 6σ process, the long-term performance is much better than the established value of 3400 PPB: For small volume samples of two pieces it is below 700 PPB, for three pieces it is below 200 PPB, and for samples with a volume greater than or equal t... [more]

Experiments have proven that traditional prediction research methods have limitations in practice. Proposing countermeasures for environmental changes is the key to optimal control of the cold chain environment and reducing the lag of control effects. In this paper, a cold chain transportation environment prediction method, combining k-means++ and a long short-term memory (LSTM) neural network, is proposed according to the characteristics of the cold chain transportation environment of agricultural products. The proposed prediction model can predict the trend of cold chain environment changes in the next ten minutes, which allows cold chain vehicle managers to issue control instructions to the environmental control equipment in advance. The fusion process for temperature and humidity data measured by multiple data sensors is performed with the k-means++ algorithm, and then the fused data are fed into an LSTM neural network for prediction based on time series. The prediction error of th... [more]

Printed circuit boards (PCBs) are primarily used to connect electronic components to each other. It is one of the most important stages in the manufacturing of electronic products. A small defect in the PCB can make the final product inoperable. Therefore, careful and meticulous defect detection steps are necessary and indispensable in the PCB manufacturing process. The detection methods can generally be divided into manual inspection and automatic optical inspection (AOI). The main disadvantage of manual detection is that the detection speed is too slow, resulting in a waste of human resources and costs. Thus, in order to speed up the production speed, AOI techniques have been adopted by many PCB manufacturers. Most current AOI mechanisms use traditional optical algorithms. These algorithms can easily lead to misjudgments due to different light and shadow changes caused by slight differences in PCB placement or solder amount so that qualified PCBs are judged as defective products, whi... [more]

We investigated the effect of electro-induced multi-gas modification (EIMGM) duration on the adhesion and wear resistance of PET and LDPE polymer substrates used in the printing industry. It was found that EIMGM increases the polar component and the complete free surface energy from 26 to 57 mJ/m2 for LDPE and from 37 to 67 mJ/m2 for PET (due to the formation of oxygen-containing groups on the surface of the materials). Although the degree of textural and morphological heterogeneity of the modified LDPE increased more than twice compared to the initial state, it is not still suitable for application as a substrate in extrusion 3D printing. However, for PET, the plasma-chemical modification contributed to a significant increase (~5 times) in filament adhesion to its surface (due to chemical and morphological transformations of the surface layers) which allows for using the FFF technology for additive prototyping on the modified PET-substrates.

We report on a light-triggered process at which repulsive interactions between microparticles with a polyelectrolyte (PE) brush coating can be remotely controlled. The spherical polyelectrolyte brushes are loaded with photosensitive azobenzene containing surfactant which can undergo reversible photo-isomerization from trans to cis state. The surfactant hydrophilicity is altered by illumination with light of an appropriate wavelength, at which a dynamic exchange of the more surface-active trans isomer in comparison to the more water soluble cis isomer with the PE brush generates a concentration gradient of the cis isomers near a solid surface where the particle is sedimented. In this way, each spherical brush produces its local lateral diffusioosmotic flow pointing outside in a radial direction resulting in mutual long-range repulsive interactions. We demonstrate that a PE layer has a higher tendency to absorb surfactant in comparison to plain silica particles, yielding a larger flow st... [more]

Impact energy, the main performance subject of hydraulic breakers, is required to evaluate value from consumers. This study proposes a neural network algorithm-based model to predict the impact energy of a hydraulic breaker without measuring it. The proposed model was developed using 1451 data points for various parameters as an input to predict the impact energy of hydraulic breakers in a small class to a large class. Different machine learning methods have been studied, including correlation analysis, linear regression, and neural networks. The results revealed that the working pressure, working flow rate, chisel diameter, nitrogen gas pressure, operating frequency, and power significantly influenced impact energy formation. The results obtained provide a reliable model for predicting the impact energy of hydraulic circuit breakers of various sizes.

The results of the second trial production of the gas hydrate reservoir in the Shenhu area of the South China Sea show that the production of a gas hydrate reservoir by horizontal wells can greatly increase the daily gas production, but the current trial production is still far below the minimum production required for commercial development. Compared with a single horizontal well, a fishbone well has a larger reservoir contact area and is expected to achieve higher productivity in the depressurization development of gas hydrate reservoirs. However, there is still a lack of systematic research on the application of fishbone wells in Class I gas hydrate reservoirs. In this paper, a grid system for gas hydrate reservoirs containing fishbone wells is first established using the PEBI unstructured grid, and fine-grained simulation of reservoirs near the bottom of the wells is achieved by adaptive grid encryption while ensuring computational efficiency. On this basis, Tough + Hydrate softwar... [more]

PBL stiffeners, made of thin-walled steel plates with circular openings and welded to the steel tube of a square concrete-filled steel tubular (CFST) column, can improve the combined effect effectively by co-carrying axial compressive forces and confining the concrete core. A numerical simulation study based on the previous test was conducted to study the ultimate strength of the CFST stub column with PBL stiffeners. Finite element models of CFST with different stiffeners were made and verified by the test results of typical failure modes and load−strain curves of specimens. The parameter study was conducted, including PBL stiffener detailing (i.e., material strength, stiffener thickness, opening diameter, and opening spacing). Finally, based on the study and analysis results, an ultimate bearing capacity prediction formula was proposed, which can reasonably predict the bearing capacity of a square CFST column with longitudinal or diagonal stiffeners, while the methods in ACI, BS5400,... [more]

In this study, we carried out a para-xylene crystallization experiment at constant temperature and concentration levels. Throughout the process, the kinetics of nucleation, growth, breakage, and aggregation of para-xylene particles were measured and built using a morphological approach. An additional a three-stage continuous suspension crystallization separation experiment was carried out, the process for which was simulated using the population balance model based on correlated kinetic equations. The population balance equation was solved using an extended moment of classes algorithm, and the solving process was implemented in MATLAB. In this case, the predicted particle size distribution of the products matched well with the experiment. In order to provide references for the optimization of the industrial para-xylene crystallization process, a three-stage suspension crystallization separation experiment was designed and conducted, in which each crystallizer had a distinct operating t... [more]

In recent years, China has entered a period of rapid urban development, but most of the cities with rapid development still have ground hardening, which makes it difficult for rainwater to penetrate and discharge. In order to achieve the rapid drainage of accumulated water in the city, nanotechnology was introduced, and permeable concrete based on NC and NS nanomaterials was proposed. Combined with finite element analysis, the permeable properties and mechanical properties of permeable concrete mixed with nanomaterials were analyzed. A comprehensive performance analysis of pervious concrete shows that the viscosity of permeable concrete mixed with nanomaterials is significantly higher than that of non-mixed pervious concrete, and the permeability coefficient of permeable concrete mixed with nanomaterials can reach 0.43 cm/s. A finite element analysis shows that the incorporation of nanomaterials can improve the compressive strength of permeable concrete. At the same time, under a rainw... [more]