This work investigated hydrogen production from biomass feedstocks (i.e., glucose, starch, lignin and cellulose) using a 100 mL h-type proton exchange membrane electrolysis cell. Biomass electrolysis is a promising process for hydrogen production, although low in technology readiness level, but with a series of recognised advantages: (i) lower-temperature conditions (compared to thermochemical processes), (ii) minimal energy consumption and low-cost post-production, (iii) potential to synthesise high-volume H2 and (iv) smaller carbon footprint compared to thermochemical processes. A Lewis acid (FeCl3) was employed as a charge carrier and redox medium to aid in the depolymerisation/oxidation of biomass components. A comprehensive analysis was conducted, measuring the H2 and CO2 emission volume and performing electrochemical analysis (i.e., linear sweep voltammetry and chronoamperometry) to better understand the process. For the first time, the influence of temperature on current density... [more]

This paper presents an approach for optimizing the oil recovery factor by determining initial oil production rates. The proposed method utilizes the Q-learning method and the reservoir simulator (Eclipse 100) to achieve the desired objective. The system identifies the most efficient initial oil production rates by conducting a sufficient number of iterations for various initial oil production rates. To validate the effectiveness of the proposed approach, a case study is conducted using a numerical reservoir model (SPE9) with simplified configurations of two producer wells and one injection well. The simulation results highlight the capabilities of the Q-learning method in assisting reservoir engineers by enhancing the recommended initial rates.

The group of nontuberculous mycobacteria (NTM) includes about 200 mycobacteria that are widespread in the natural environment as free-living saprophytic bacteria, commensals or symbionts. NTM, also referred to as atypical mycobacteria, are mostly apathogenic; nowadays, they are increasingly important environmental opportunistic pathogens. This study continues the work of previous studies which investigated the individual and synergistic effect of different essential oils (EOs) on NTM. The aim was to investigate the effect of the interaction of the common juniper (Juniperus communis) EO and the antimicrobials, amikacin, clarithromycin and rifampicin, against Mycobacterium avium and M. intracellulare using the checkerboard synergy method in an enriched Middlebrook 7H9 broth. Morphological changes of treated NTM cells were observed with a transmission electron microscope. The most synergistic combinations were found at subinhibitory concentrations of the common juniper EO and rifampicin a... [more]

At the level of skin wounds, an electrical potential difference develops between the edges of the wound and the center of the wound, which favors the migration of cells in the process of their healing. Cells migrate in an electric field because they have a certain electrical membrane potential. This potential is due to differences in the transmembrane electrochemical gradient. The transmembrane electrochemical gradient is due to the migration of sodium, potassium, and calcium ions into the corresponding ion channels. If this is the case, the modification of the functionality of these ion channels should influence the membrane potential and, as a consequence, the wound healing process. In this experiment, we set out to investigate whether the chemical manipulation of ion channels by amiodarone influences the wound healing process. Amiodarone blocks several types of ion channels, but at different concentrations: at low concentrations, it blocks only potassium channels; at medium concentr... [more]

This review focuses on the energy structure of iron and steel production and a feasible development path for carbon reduction. The process path and feasible development direction of carbon emission reduction in the iron and steel industry have been analyzed from the perspective of the carbon−electricity−hydrogen ternary relationship. Frontier technologies such as “hydrogen replacing carbon” are being developed worldwide. Combining the high efficiency of microwave electric-thermal conversion with the high efficiency and pollution-free advantages of hydrogen-reducing agents may drive future developments. In this review, a process path for “microwave + hydrogen” synergistic metallurgy is proposed. The reduction of magnetite powder by H2 (CO) in a microwave field versus in a conventional field is compared. The driving effect of the microwave field is found to be significant, and the synergistic reduction effect of microwaves with H2 is far greater than that of CO.

The aim of this work is to present in a systematic way a novel general methodology to develop the design equations (heat and mass balances) for networks of ideal reactors, that is, Plug-Flow Reactors (PFRs) and Continuous Stirred Tank Reactors (CSTRs). In particular, after introducing the general definition of conversion to be used for reactor networks, several case studies of interest in chemical engineering are presented as topic-examples of application: (i) adiabatic-stage reactors with recycle, (ii) adiabatic-stage reactors with split, (iii) adiabatic-stage reactors intercooled by reactants and (iv) adiabatic-stage reactors with interstage distributed feed. More generally, the presented methodology can also be applied to develop the design equations for complex networks of interconnected reactors, not restricted to those considered in the present work. The motivation behind the present study lies in the fact that, to the best of our knowledge, a systematic development of the design... [more]

A floatation nozzle can effectively transfer heat and dry without touching the substrate, and serves as a vital component for heat transfer to the substrate. Enhancing the heat transfer performance, and reducing its heat transfer unevenness to the substrate play an important role in improving product quality and reducing thermal stress. In this work, the effects of key structural parameters of the floatation nozzle on the heat transfer mechanism are systematically investigated by means of a numerical simulation of computational fluid dynamics. The findings demonstrate that the secondary vortex structure induced by the floatation nozzle with effusion holes increases heat transfer performance by 254.3% compared with the nozzle without effusion holes. The turbulent kinetic energy and temperature distribution between the jet and the target surface are affected by the jet angle and slit width respectively, which change the heat transfer performance of the float nozzle in different degrees.... [more]

This study aims to elucidate the mechanism by which the ultrasonic loading of metal affects the extraction of small molecular phase substances (low molecular compounds) in tar-rich coal. Tar-rich coal samples were collected from the Huangling mining area in the southeastern Ordos Basin, China. The coal, the leaching solution of the coal, the extraction products, and the extraction residual coal samples with different metal ions loaded by ultrasound were analyzed using field emission scanning electron microscopy, pH detection, gas chromatography−mass spectrometry, a Fourier transform infrared spectrometer, and an X-ray diffractometer. The obtained results indicated that the ultrasonic loading of coal samples with different metal ions (Mn2+, Co2+, Cu2+, Fe2+, and Ni2+) promoted the extraction of small molecular phase substances in coal and increased the proportion of extracted aliphatic hydrocarbons, alkylbenzene, naphthalene, phenanthrene, and other compounds. The extraction rate of Mn2... [more]

This paper investigates the decentralized fuzzy control problems for nonlinear-state-unmeasured interconnected descriptor systems (IDSs) that utilize the observer-based-feedback approach and the proportional−derivative feedback control (PDFC) method. First of all, the IDS is represented as interconnected Takagi−Sugeno (T−S) fuzzy subsystems. These subsystems can effectively capture the dynamic behavior of the system through fuzzy rules. For the stability analysis of the system, this paper uses the free-weighing Lyapunov function (FWLF), which allows the designer to set the weight matrix, to achieve the desired control performance and design the controller more easily. Furthermore, the control problem can be transformed into a set of linear matrix inequalities (LMIs) through the Schur complement, which can be solved using convex optimization methods. Simulation results confirm the effectiveness of the proposed method in achieving the desired control objectives and ensuring system stabil... [more]

This paper proposes a high-efficiency and compact fuel cell−battery hybrid power system without DC/DC converters. Generally, fuel cells supply power to charge lithium batteries or loads using DC/DC converters. The disadvantages of a DC/DC converter are its complex design, poor efficiency, and large volume. Therefore, improvements in the volume, weight, and efficiency are the main objectives of the proposed topology, which is suitable for stable operation in power equipment. This paper proposes a novel topology without DC/DC converters for a fuel cell−battery hybrid forklift system and analyzes, discusses, and verifies it with experimental measurements. Additionally, the proposed topology uses an average charging method to charge the Li-ion battery. The dynamic response of fuel cells is slower than that of Li-ion batteries. By properly configuring the voltages of a fuel cell and a lithium battery, we propose a hybrid system that can maintain a stable output and high efficiency in differ... [more]

Titanium carbide has attracted widespread attention due to its excellent properties. This study investigates the process of carbon thermally reducing TiO2 to prepare TiC through a combination of thermodynamic analysis and experiments. The effects of temperature, TiO2/C molar ratio, and time on the phase transformation and morphology evolution of the products are investigated. The synthesis of titanium carbide involves the main reduction path of TiO2−Magnéli−Ti3O5−Ti2O3−TiCxO1−x. With the increase in reaction temperature and TiC content, the microstructure transitions from a smooth disc-like structure to a loose and porous layered structure, while the particle size decreases significantly. The carburisation rate of the reduced product is more affected by temperature, according to chemical analysis. The carburisation rate increased from 18.37% to 36.09% for 2 h−10 h of holding time at 1400 °C, and from 51.43% to 77.57% for 2 h−10 h of holding time at 1500 °C. The quantification of the ca... [more]

Electrostatic precipitators (ESP) are especially known for the efficient separation of micron and submicron particles from aerosols. Wet electrostatic precipitators are particularly suitable for highly resistive materials. Using these, particles can be directly transferred into a liquid for further processing or safer handling, which is advantageous for either hazardous or valuable materials. In this work, a wet ESP, which enables the separation of highly resistive particles into a heated liquid, was designed and investigated. To do this, spray-dried drug particles were embedded in a molten sugar alcohol to enhance the drug dissolution rate. After cooling, the solidified product showed advantageous properties such as a high drug dissolution rate and easy handling for further processing. For the design of the wet ESP, different discharge electrode configurations were tested. A wall film served as the collection electrode, which was generated by a specially designed distributer die. A la... [more]

The research program “Engineered Artificial Minerals (EnAM)” addresses the challenge of recycling valuable elements from battery waste streams. These elements, such as lithium (Li), often migrate in the slag phase, in some cases as crystals. EnAM crystals represent concentrated reservoirs of these elements, which can only be effectively recycled if they are extracted from the slag matrix and then separated. Selective wet agglomeration is a separation process based on a three-phase system and is often used in coal and ore processing. The produced agglomerates in this process can be easily separated from the remaining suspension. The precise quantification of the wetting properties and adhesion strength between suspended particles and binding liquid droplets is a scientific challenge. An accurate technique suitable for adhesion force measurements in three-phase systems with micrometer-scale particles is Fluidic Force Microscopy (FluidFM®). An experimental setup with optical control is be... [more]

In this study, the effects of ultrasonic power, drying temperature, and slice thickness on the drying rate, chromatism, water migration law, gingerol content, flavor, and antioxidant activity of ginger were investigated by using a direct-contact ultrasound and far infrared combined drying technology. The results showed that compared with single far infrared drying, direct-contact ultrasound and far infrared combined drying accelerated the free water migration rate of ginger (7.1~38.1%), shortened the drying time (from 280 min to 160 min), reduced the loss of volatile components in ginger, and significantly increased the antioxidant activity of ginger (p < 0.05). Furthermore, after ultrasound intervention, the gingerol content decreased in slices of 4 mm thickness (0.1226 ± 0.0189 mg/g to 0.1177 ± 0.0837 mg/g) but increased in slices of 6 mm thickness (0.1104 ± 0.0162 mg/g to 0.1268 ± 0.0112 mg/g). This drying technology has a certain reference significance for the drying process of... [more]

A pumping-while-tripping method is proposed to mitigate pressure swabs during tripping out in wells with a narrow mud density window and extended reach. In the proposed tripping-out process, the fluid circulation is started by using a special pump from a customized circulation line before tripping is initiated. During the tripping out, drilling fluid is circulated in the wellbore simultaneously while the drilling string is moving. A model to simulate the dynamic pressure changes in this process is developed based on the Navier−Stokes (N-S) equations and a damped free vibration system. The model was initially developed for Herschel−Bulkley (H-B) fluid; however, it can be applied to other fluid models by eliminating the non-existing terms. An analysis was conducted to investigate the effect of tripping velocity and circulation pumping rate on the pressure changes. The results show that pumping-while-tripping is effective in mitigating the pressure swab during tripping out, which is espec... [more]

Organobentonites have been applied for the removal of two common non-steroidal anti-inflammatory drugs, ibuprofen (IBU) and diclofenac sodium (DS), from aqueous solutions. Two surfactants, one with and the other without benzyl group (octadecyldimethylbenzylammonium chloride, ODMBA, and hexadecyltrimethylammonium bromide, HDTMA), in amounts equivalent to 50, 75, and 100% of the cation exchange capacity of bentonite were used for the preparation of organobentonites. Successful modification of bentonite was confirmed by several methods: X-ray powder diffraction (XRPD), point of the zero charge (pHPZC), determination of exchanged inorganic cations in bentonite, determination of textural properties, and scanning electron microscopy (SEM). Kinetic and thermodynamic data on the adsorption of IBU and DS showed that drug adsorption was controlled by the type and the amount of surfactant incorporated into the bentonite and by their arrangement in the interlayer space and at the surface of organo... [more]

Well deviation is a prevalent problem in deep oil and gas exploration, leading to a significant increase in drilling costs. The conventional bottom-hole assembly (BHA) anti-deviation design method does not consider the impact of the BHA structure on lateral vibration. This paper proposes an integrated BHA design method that takes into account both anti-deviation and vibration reduction. This method evaluates the BHA’s anti-deviation ability using the drilling trend angle. A negative value of the drilling trend angle indicates that the BHA can correct well deviation. A finite element linearized dynamics method is used to evaluate the lateral vibration intensity of the BHA. This method involves calculating the bending displacement caused by mass imbalance and then determining the magnitude of the bending strain energy based on this displacement. The structural factors affecting the anti-deviation ability and potential lateral vibration intensity of pendulum BHAs and bent-housing mud moto... [more]

Due to improved mechanical properties, nano-alumina (NA) addition has been considered as an interesting method to promote the performance of cement composites. To investigate the enhancing effect of NA on the fire resistance of cement-based composites, the physical and mechanical properties of NA-modified cement composites (NAMCCs) were experimentally measured after exposure to high temperatures (up to 800 °C). The variation mechanism of the physical properties of NAMCCs with increasing temperature was explored using X-ray diffraction (XRD) and scanning electron microscopy (SEM) methods. Increasing temperature leads to a gradual decrease in density and ultrasonic wave velocity but an overall increase in mass loss. The addition of NA particles effectively improved the mechanical properties of hardened cement pastes after heat treatment at all the temperatures studied. The compressive strength, elastic modulus and flexural strength all gradually decrease with increasing temperature. Comb... [more]

Backstepping-based fixed-time tracking control is proposed for a robotic arm system to solve the problem of trajectory tracking control under system uncertainties, which ensures the robotic arm system can realize stable tracking control within a fixed time independent of the initial state of the system. In addition, to address the uncertainties in the robotic arm system, a control strategy based on disturbance observer compensation is designed, which provides feed-forward compensation through the accurate estimation of the system uncertainties and enhances the system’s robustness. Finally, a two-link robotic arm model is used for simulation experiments, and the comparison results show that the control scheme designed in this article can effectively improve the robotic arm’s tracking accuracy and convergence speed.

A series of theoretical and experimental studies was carried out with the aim of a direct comparison of the thermal and microwave destruction of peat during pyrolysis. Different heating mechanisms in these processes were investigated in the framework of simulations conducted using a commercial 3D software package, CST Studio Suite, to define their specific features. Based on these simulations, identical reactors were constructed exploiting an electric element and a microwave complex as a heat source, and an experimental technique was developed that allows these processes to be correctly compared under similar conditions. Using these reactors based on different heat sources, comparative experiments on peat pyrolysis were performed, and the results of the theoretical analysis were confirmed. As a result, the advantages of microwave exposure were demonstrated to achieve a more uniform and deep fragmentation of peat, increase the reaction rate and reduce the processing time, with high ener... [more]

Due to the growth in the consumption of avocado in recent years, the amount of waste caused by avocado peel and seed has increased. Avocado waste can be transformed into valuable products such as energy, biofuels, and biological products using integrated processes in a biorefinery. This paper considers the detailed modeling, simulation, and optimization of a biorefinery for the production of phenolic compounds, bioethanol, biological xylitol, syngas, and electrical power from avocado seed and peel, using Aspen Plus in equation-oriented mode as a process simulation tool. For a biorefinery in nominal conditions, it is possible to achieve a gross profit of approximately 30×106 USD/year for capital costs of USD 31.4×106, while the combined effect of process optimization and heat integration allows reaching a gross profit of 37×106 USD/year for capital costs of USD 30.7×106. These results of the optimized plant show its potential to take advantage of avocado seed and peel in a profitable an... [more]

Reducing carbon emissions and increasing the integration of new energy sources are key steps towards achieving sustainable development. Virtual power plants (VPPs) play a significant role in enhancing grid security and promoting the transition to clean, low-carbon energy. The core equipment of the VPP, the CHP unit, utilizes a thermal engine or power station to generate electricity and useful heat simultaneously. However, the intermittent and volatile nature of renewable energy sources, as well as the “heat-driven power generation” mode of combined heat and power (CHP) units, presents contradictions that severely affect their peak-shifting capability and lead to high carbon emissions. To address these issues, a novel VPP is established by integrating traditional power plants with carbon capture and hydrogen energy storage. This approach utilizes a “hydrogen energy storage−electric boiler” decoupling method to address the operational mode of CHP, strengthens the coupling relationship be... [more]

Solar photovoltaic (PV) generation will play a crucial role in the global clean energy transition toward carbon neutrality. While the development of solar PV generation has been explored in depth, the development of high-proportion solar PV generation has yet to be discussed. Considering the back force of the constraint of achieving carbon neutrality within the specified timeframe, this paper establishes a unified, multi-dimensional, and achievable framework through which to perform a system analysis for exploring the potential risks and challenges involved in the development process of high-proportion solar PV generation and investigating possible pathways to fostering the development of high-proportion solar PV generation. The results show that the critical risks and challenges include a low conversion efficiency, poorer resource endowment, more limited land resources, a low use of rooftop resources, an increasing complexity of power system scheduling, and low public awareness. These... [more]

Three-compartment septic tanks are a prominently advocated environmentally sustainable sanitation facility in rural China. However, the comprehensive elimination efficacy and underlying mechanisms of pathogenic bacteria within septic tanks remain incompletely understood. In particular, the operational performance in low-temperature conditions has received limited attention in the existing literature. In this work, a simulation of the three-compartment septic tank treatment system was conducted under low-temperature conditions (15 °C). The operational results exemplify the synergistic interplay of volatile fatty acids (VFAs), NH3-N, and bacterial communities, culminating in a partial reduction in Enterococcus faecalis, Escherichia coli, Staphylococcus aureus, and Salmonella enteritidis, within the three-compartment septic tank. Their respective population abundances were decreased by magnitudes of 2.2, 1.3, 0.03, and 1.46 logarithmic units (copies/mL), respectively. Through the utilizat... [more]

A prevalent metal surface defect is hot-rolled iron oxide; thus, it is critical to regulate the production and growth of oxidized iron during the hot-rolling process. To analyze the influence of Si content on the growth laws of the oxidized layer in carbon steel during heating, three types of carbon steel with significant differences in Si content were selected for research on the growth laws of the oxidized layer at different heating temperatures. The production law and micromorphology of the oxidized layer were analyzed using methods such as scanning electron microscopy and thermodynamic phase diagram calculation, and an oxidation dynamic model was obtained. The predicted control values of the model are highly consistent with the measured values. This study reveals that the heating temperature significantly impacts the thickness of the oxidized layer of carbon steel. At temperatures below 500 °C, the oxidation is not evident, and the layer is thin. Between 500 °C and 900 °C, the stee... [more]