Plastics are used for various applications, including in the food and beverage industry, for the manufacturing of plastic utensils and straws. The higher utilization of plastic straws has indirectly resulted in the significant disposal of plastic waste, which has become a serious environmental issue. Alternatively, bio-plastic and paper straws have been introduced to reduce plastic waste. However, limited studies are available on the environmental assessment of drinking straws. Life cycle assessment (LCA) studies for bio-plastic and paper straws have not been comprehensively performed previously. Therefore, the impact of both bio-plastic and paper straws on the environment are quantified and compared in this study. Parameters, such as the global warming potential (GWP), acidification potential (AP) and eutrophication potential (EP), were evaluated. The input−output data of the bio-plastic and paper straws processes from a gate-to-grave analysis were obtained from the literature and gen... [more]

The chemical activation of a carbon precursor with KOH generally results in an activated carbon (AC) with a high specific surface area. However, this process generates a large volume of wastewater that includes dissolved alkali metals, existing mainly as K2CO3. Thus, wastewaters with a high concentration of dissolved K2CO3 can potentially be used in place of KOH as a chemical agent. In the present study, to reduce the thermal stability of K2CO3, which decomposes at temperatures greater than 891 °C, K2CO3 was chemically impregnated into carbon precursors prior to activation of the precursors. The thermochemical properties and activation efficiency of the carbon precursors treated with K2CO3 were compared with those of carbon precursors treated with KOH. Analysis by XPS indicated that C−O−K complexes formed on the surface of the carbon precursors; in addition, their peak intensities were approximately the same irrespective of the chemical agent used. However, the specific surface area of... [more]

Currently, the use of fossil fuels is very high and existing nature reserves are rapidly depleted. Therefore, researchers are turning their attention to find renewable fuels that have a low impact on the environment, to replace these fossil fuels. Biogas is a low-cost alternative, sustainable, renewable fuel existing worldwide. It can be produced by decomposition of vegetation or waste products of human and animal biological activity. This process is performed by microorganisms (such as methanogens and sulfate-reducing bacteria) by anaerobic digestion. Biogas can serve as a basis for heat and electricity production used for domestic heating and cooking. It can be also used to feed internal combustion engines, gas turbines, fuel cells, or cogeneration systems. In this paper, a comprehensive literature study regarding the laminar burning velocity of biogas-containing mixtures is presented. This study aims to characterize the use of biogas as IC (internal combustion) engine fuel, and to d... [more]

The flammable propane−air mixtures raise specific safety and environmental issues in the industry, storage, handling and transportation; therefore dilution of such mixtures has gained significant importance from the viewpoint of fire safety, but also due to nitrogen oxide’s emission control through flameless/mild combustion. In this paper, the propagation of the flame in C3H8-air-diluent stoichiometric gaseous mixtures using Ar, N2 and CO2 as diluents was investigated. Data were collected from dynamic pressure-time records in spherical propagating explosions, centrally ignited. The experiments were done on stoichiometric C3H8-air + 10% diluent mixtures, at initial pressures within 0.5−2.0 bar and initial temperatures within 300−423 K. The flame velocity was determined from laminar burning velocities obtained using the pressure increase in the incipient stage of flame propagation (when the pressure increase is lower than the initial pressure). The experimental propagation velocities wer... [more]

With the increase of public environmental awareness and the growth of e-commerce, sustainable development promotes the manufacturer to increasingly participate in green innovation and make full use of the online sales channel to enhance competitiveness. Despite decentralized encroachment being widely adopted in business reality, the current literature has commonly paid more attention to centralized encroachment. To complement related research, a dual-channel green supply chain composed of a manufacturer (its retail subsidiary) and a retailer is investigated. We focus on what encroachment strategy (centralization vs. decentralization) drives the green innovation and analyze the impact of consumer green awareness and product substitutability on the manufacturer’s encroachment strategy, green innovation efforts and supply chain performance. Under each encroachment strategy, we build a Stackelberg game model and derive the equilibrium outcome. Then, we theoretically analyze the effects of... [more]

The mining industry plays a significant role in economic growth and development. Coal is a viable renewable energy source with 185.175 billion deposits in Thar, which has not been deeply explored. Although coal is an energy source and contributes to economic development, it puts pressure on environmental sustainability. The current study investigates Sindh Engro coal mining’s impact on environmental sustainability and human needs and interest. The Folchi and Phillips Environmental Sustainability Mathematics models are employed to measure environmental sustainability. The research findings demonstrated that Sindh Engro coal mining is potentially unsustainable for the environment. The toxic gases (methane, carbon dioxide, sulfur, etc.) are released during operational activities. The four significant environment spheres (atmosphere, hydrosphere, biosphere, and lithosphere) are negatively influenced by Thar coal mining. The second part of the analysis results shows that human needs and int... [more]

Environmental pollution caused by excessive Sb(III) in the water environment is a global issue. We investigated the effect of processing parameters, their interaction and mechanistic details for the removal of Sb(III) using an iron salt-modified biosorbent (Fe(III)-modified Proteus cibarius (FMPAs)). Our study evaluated the optimisation of the adsorption time, adsorbent dose, pH, temperature and the initial concentration of Sb(III). We use response surface methodology to optimize this process, determining optimal processing conditions and the adsorption mechanism evaluated based on isotherm model and adsorption kinetics. The results showed that—(1) the optimal conditions for the adsorption of Sb(III) by FMPAs were an adsorption time of 2.2 h, adsorbent dose of 3430 mg/L, at pH 6.0 and temperature 44.0 °C. For the optimum initial concentration of Sb(III) 27.70 mg/L, the removal efficiency of Sb(III) reached 97.60%. (2) The adsorption process for Sb(III) removal by FMPAs conforms to the... [more]

There is an increasing demand for automatic, reliable and sensitive analytical methods for determining trace levels of phthalic acid esters (PAEs) in environmental samples. While on line coupled liquid chromatography-gas chromatography (LC-GC) has been proof to be a powerful tool for trace-level analyses in complex matrices, the present work presents a new totally automated on line LC-GC method, using the Through Oven Transfer Adsorption Desorption (TOTAD) interface, for the analysis of four of the main phthalates, dibuthyl phthalate (DBP), diethyl phthalate (DEP), dimethyl phthalate (DMP) and diethylhexyl phthalate (DEHP), in a matrix as complex as leachate. The sample is directly injected into the LC injector valve with no sample pretreatment other than simple filtration. The LC step separates the target analytes from matrix interference. Two different LC fractions are collected in a purposely designed fraction collector and then transferred to the TOTAD interface, which concentrates... [more]

Line structured light systems have been widely applied in the measurement of various fields. Calibration has been a hot research topic as a vitally important process of the line structured light system. The accurate calibration directly affects the measurement result of the line structured light system. However, the external environment factors, such as uneven illumination and uncertain light stripe width, can easily lead to an inaccurate extraction of light stripe center, which will affect the accuracy of the calibration. An image analysis-based framework in the calibration process was proposed for the line structure light system in this paper. A three-dimensional (3D) vision model of line structure light system was constructed. An image filtering model was established to equalize the uneven illumination of light stripe image. After segmenting the stripe image, an adaptive window was developed, and the width of the light stripe was estimated by sliding the window over the light stripe... [more]

Sources of contamination in a subsurface environment are petrol, diesel fuel, gasoline at oil refineries, underground storage tanks, transmission pipelines, and different industries. The permeable reactive barrier (PRB) is a promising technology to remediate groundwater in-situ. In this study, synthetic groundwater samples containing toluene are treated in three reactor columns by biological processes. PRB-1 consisted of sand and gravel as reactor media, microbial inoculum (bioaugmentation—BA), and nutrients (biostimulation—BS); PRB-2 consisted of sand and gravel as reactor media, microbial inoculum, nutrients, and 12 layers of nonwoven geotextile fabrics; and PRB-3 consisted of only sand and gravel as reactor media (natural attenuation—NA). This study was conducted to assess the impact of geotextile fabric filter, bioaugmentation, and biostimulation on toluene degradation efficiency. After 167 days of treatment, toluene biodegradation efficiencies varied between 88.2% and 93.8% for PR... [more]

Efficient conversion of renewable biomass into value-added chemicals and biofuels is regarded as an alternative route to reduce our high dependence on fossil resources and the associated environmental issues. In this context, biomass-based furfural and levulinic acid (LA) platform chemicals are frequently utilized to synthesize various valuable chemicals and biofuels. In this review, the reaction mechanism and catalytic system developed for the generation of furfural and levulinic acid are summarized and compared. Special efforts are focused on the different catalytic systems for the synthesis of furfural and levulinic acid. The corresponding challenges and outlooks are also observed.

Biomass is recognised as one of the most attractive feedstocks among the alternative resources, having a high potential for the sustainable production of valuable chemicals and biofuels. Due to its abundance, convenience, carbon neutrality and eco-friendliness, biomass is believed to positively impact the current environmental crisis caused by the extensive use of petroleum resources. For this reason, the search for processes that can convert this feedstock, resolving some inherent drawbacks, is needed. Biomass liquefaction using ionic liquids (ILs) as catalysts has received appreciable attention in renewable fuels and chemicals production. With the potential for a substantial number of anion and cation pairings, ILs can be an attractive medium towards reusability and sustainability for these processes due to the unique and tunable combinations of their functional groups-and, therefore, their properties. In this review, several studies using ILs in biomass liquefaction are compared and... [more]

A novel manganese-rich pokeweed biochar was prepared at different temperatures from manganese-rich pokeweed plants collected at manganese tailings, resulting in materials identified as BC300, BC400, and BC500. The synthetized biochar materials were investigated as regards their potential for removing Cu2+, Pb2+, and Cd2+, specifically in terms of adsorption performances, adsorption kinetics, adsorption isotherms, and potential environmental pollution risk. The results showed that the sorption process fitted well to the pseudo-second-order kinetic and Langmuir models, and the maximum adsorption capacities of BC500 were 246, 326, and 310 mg·g−1 for Cu2+, Pb2+, and Cd2+ respectively. The physicochemical characteristics of the biochars, and the adsorption mechanisms, were revealed by using scanning electron microscopy-energy spectrometer, elemental analysis, Brunauer−Emmett−Teller techniques, X-ray diffraction, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy.... [more]

Recirculating aquaculture systems (RAS) are good candidates for the sustainable development of the aquaculture sector. A current limitation of RAS is the production and accumulation of nitrogenous waste, which could affect fish health. We investigated the potential of the anaerobic ammonia oxidation (anammox) process to treat marine wastewater from a cold-water RAS. We show that the marine anammox bacteria Candidatus Scalindua is a promising candidate. However, its activity was affected by unknown compounds in the RAS wastewater and/or the sub-optimum content of essential trace elements (TEs). Anammox activity dropped to 2% and 13% in NH4+ and NO2− removal, respectively, when NO3-rich RAS wastewater was used as a medium in the absence of TE supplementation. A TE supplementation was added to the RAS wastewater in a subsequent phase, and a recovery in anammox activity was shown (25% and 24% in NH4+ and NO2− removal, respectively). Future studies need to identify the unknown factor and de... [more]

In this study, a combined technique of bibliometric and social network analysis was applied on research articles, related to the application of nano-adsorbents for cobalt removal from wastewater, published in Scopus database up to 2020. The results revealed that the first relative research article appeared in the Scopus database in the year 2002. The total output of research articles reached 214 in the year 2020. Published research articles of the years 2014−2020, added up to 83.6% of total articles. King Saud University of Saudi Arabia, Chinese Academy of Science, and LUT University of Finland were found to serve as the gatekeepers who control information flows in the network of the most prolific institutions, while cooperation between China, Saudi Arabia, and United States was also identified. On average, the most prolific authors cooperated with five others, while the top 10 cited publications appeared to represent a sparse and weakly interconnected network of co-authors. Graphene o... [more]

Soot particles in diesel engine exhaust is one of the main reasons for hazy weather and elimination of them is urgent for environmental protection. At present, it is still a challenge to develop new catalysts with high efficiency and low cost. In this paper, a kind of K modified three-dimensionally ordered macroporous (3DOM) MnCeOx/Ti0.7Si0.3O2 catalysts are designed and synthesized by a sample method. Due to the macroporous structure and synergistic effect of K, Mn, and Ce, the KnMnCeOx/Ti0.7Si0.3O2 (KnMnCeOx/M-TSO) catalysts exhibit good catalytic performance for soot combustion. The catalytic activity of K0.5MnCeOx/M-TSO was the best, and the T10, T50, and T90 are 287, 336, and 367 °C, respectively. After the prepared catalyst was doped with K, the physicochemical properties and catalytic performance changed significantly. In addition, the K0.5MnCeOx/M-TSO catalyst also somewhat exhibits sulfur tolerance owing to it containing Ti. Because of its simple synthesis, high activity, and... [more]

Bacterial cell immobilization offers considerable advantages over traditional biotreatment methods using free bacteria. Bacillus velezensis was underwented isolation and genetic identification as COD-degrading bacteria in slaughter wastewaterand immobilized on the surface of polyvinyl alcohol (PVA) microsphere with the adhesion to bio-carrier through direct physical adsorption. The removal CODMn rates of microsphere (PVA) immobilized cells were 16.99%, increased 9.38% from a 50% concentration of slaughter wastewater within 24 h at 37 °C, pH 7.0, and 120 rpm, which was about 2.2 times that of the free bacteria. A significant difference was found in two groups (p < 0.01 p value less than 0.01 means statistical significance), and the COD degradation rate of the microsphere immobilized Bacillus velezensis strain was higher than the control group (PVA: control vs 20.08: 10.81), with the processing time reaching 36 h (p < 0.05). Additionally, similar results were obtained from a 20% co... [more]

Serious traffic-related pollution and high population density during the spring festival (Chinese new year) travel rush (SFTR) increases the travelers’ exposure risk to pollutants and biohazards. This study investigates personal exposure to particulate matter (PM) mass concentration when commuting in five transportation modes during and after the 2020 SFTR: China railway high-speed train (CRH train), subway, bus, car, and walking. The routes are selected between Nanjing and Xuzhou, two major transportation hubs in the Yangtze Delta. The results indicate that personal exposure levels to PM on the CRH train are the lowest and relatively stable, and so it is recommended to take the CRH train back home during the SFTR to reduce the personal PM exposure. The exposure level to PM2.5 during SFTR is twice as high as the average level of Asia, and it is higher than the WHO air quality guideline (AQG).

It is with great pleasure that we present to you the output of the Special Issue Study of Biodegradation and Bioremediation [...]

One of the greatest challenges of the 21st century is to fulfill the growing energy needs sustainably and cost-effectively. Among the different sources of energy, biodiesel is one of the alternative energy sources that has tremendous potential to become a major mainstream renewable energy mix. Jatropha is an important raw input for biodiesel that provides an ecological and sustainable solution for emerging greenhouse gas emissions over the other biomass feedstock. This paper critically evaluates different factors and presents a SWOT analysis (strengths, weaknesses, opportunities, and threats) and barriers to the adoption of Jatropha biodiesel. In Pakistan, the estimated production of Jatropha biodiesel is expected to be 2.93 million tons, that are calculated from available barren land and possible shortlisted suitable areas for Jatropha plantation. It is ~25% of the total import (11.84 million tons) of petroleum products, which can save ~$2 billion USD reserves of Pakistan. The cultiva... [more]

This study verified the environmental effectiveness of potentially less aggressive routes for the synthesis of poly(propylene/ethylene oxide) glycol (PPG). The analysis was developed in two stages. Firstly, the environmental performance of the conventional PPG processing route was compared to alternative variants—vegetal PPG and CO2-based PPG—applying the life cycle assessment technique to measure the primary energy demand, global warming potential, acidification, photochemical oxidation, and freshwater ecotoxicity impact categories. The synthesis of vegetable polyols from bio-based assets, such as vegetable oils, and the application of CO2 conversion routes as an alternative to technologies supported by petroleum and natural gas were studied. The use of CO2 recovered through carbon capture and usage practices resulted in environmental gains for PPG production. The processing routes within vegetal assets were not an environmentally attractive option as the performance was worse than th... [more]

The environmental issue has become a global problem that needs to be examined frequently, motivating researchers to investigate it. Thus, the present study has investigated the asymmetric impact of globalization, economic growth and natural resources on the ecological footprint in the presence of environmental Kuznets curve (EKC) in Thailand. The study has used annual time series data from 1970 to 2018. The study applied a novel method of nonlinear autoregressive distributive lag (ARDL). In particular, the current study has investigated the effect of positive and negative shocks on the independent variable on the dependent variable. The findings have confirmed that the effect of globalization and natural resources are significant and nonlinear. However, the effect of negative shocks of globalization and natural resources is more dominant on the ecological footprint in Thailand than the positive shocks of both variables. Moreover, the present study has also tested the presence of EKC in... [more]

High concentrations of particulate COD (pCOD) in the influent of aerobic granular sludge (AGS) systems are often associated to small granule diameter and a large fraction of flocculent sludge. At high particulate concentrations even granule stability and process performance might be compromised. However, pilot- or full-scale studies focusing on the effect of real wastewater particulates on AGS are scarce. This study describes a 3-month period of increased particulate loading at a municipal AGS wastewater treatment plant. The pCOD concentration of the influent increased from 0.5 g COD/L to 1.3 g COD/L, by adding an untreated slaughterhouse wastewater source to the influent. Sludge concentration, waste sludge production and COD and nutrient removal performance were monitored. Furthermore, to investigate how the sludge acclimatises to a higher influent particulate content, lipase and protease hydrolytic activities were studied, as well as the microbial community composition of the sludge.... [more]

Currently, people worldwide, in the period from September to April, observe with their own eyes and feel the pollution of the air, called smog, in their own breath. The biggest cause of smog and the source of air pollution is burning rubbish in stoves. Other causes include exhaust fumes from large factories, burning coal in furnaces, and car exhaust fumes. Smog is an unnatural phenomenon, directly related to human activity. The weather is becoming worse. On no-wind, foggy days, the smog phenomenon is the most troublesome for city dwellers. Smog persists in European countries from November to April, during the heating season. The harmful effect of smog affects almost the entire human body. Every year, air pollution causes the death of approximately 26,000−48,000 people. At the same time, poor air quality reduces life expectancy by up to a year. The purpose of this article is to present buildings and finishing elements that can help in the fight against air pollution.

Soil aggregates are among crucial factors for determining both the quality and erosion resistance of soils. Biochar is a soil amendment that has seen increasing use to improve specific soil properties, mainly the physical structure and the preserving capacity of water and nutrients, as well as sequestration of soil organic carbon. In this study, we applied the rice husk biochar (RHB) and cattle manure compost (COM) in a sandy loam rural soil, which is widely distributed in southern Taiwan, to investigate the combined effects of the biochar and compost on soil aggregation and dynamic change of organic carbon fractions. Through our incubation experiment, both biochar and compost could promote the soil aggregation after eight weeks incubation. The total amounts of macroaggregates (MaAs, >2.0 mm) and mesoaggregates (MeAs, 0.25−2.0 mm) increased by 1.3−9%. During aggregation processes, a considerably greater amount of the soil organic carbon was found to enrich mainly in MaAs and MeAs in al... [more]