This study presents the further development of the TU Wien dual fuel mechanism, which was optimized for simulating ignition and combustion in a rapid compression expansion machine (RCEM) in dual fuel mode using diesel and natural gas at pressures higher than 60 bar at the start of injection. The mechanism is based on the Complete San Diego mechanism with n-heptane extension and was attuned to the RCEM measurements to achieve high agreement between experiments and simulation. This resulted in a specific application area. To obtain a mechanism for a wider parameter range, the Arrhenius parameter changes performed were analyzed and updated. Furthermore, the San Diego nitrogen sub-mechanism was added to consider NOx formation. The ignition delay time-reducing effect of propane addition to methane was closely examined and improved. To investigate the propagation of the flame front, the laminar flame speed of methane−air mixtures was simulated and compared with measured values from literatur... [more]

A simple yet accurate photovoltaic (PV) performance curve as a function of satellite-based solar irradiation is necessary to develop a PV power forecasting model that can cover all of South Korea, where more than 35,000 PV power plants are currently in operation. In order to express the nonlinear power output of the PV module with respect to the hourly global horizontal irradiance derived from satellite images, this study employed the Gompertz model, which is composed of three parameters and the sigmoid equation. The nonphysical behavior of the Gompertz model within the low solar irradiation range was corrected by combining a linear equation with the same gradient at the conjoint point. The overall fitness of Linear-Gompertz regression to the 242 PV power plants representing the country was R2 = 0.85 and nRMSE = 0.09. The Gompertz model coefficients showed normal distributions and equivariance of standard deviations of less than 15% by year and by season. Therefore, it can be conjectur... [more]

Rapid developments in energy storage and conversion technologies have led to the proliferation of low- and medium-power electric vehicles. Their regular operation typically requires an on-board battery charger that features small dimensions, high efficiency and power quality. This paper analyses an interleaved step-down single-ended primary-inductor converter (SEPIC) operating in the discontinuous conduction mode (DCM) for charging of battery-powered light electric vehicles such as an electric wheelchair. The required characteristics are achieved thanks to favourable arrangement of the inductors in the circuit: the input inductor is used for power factor correction (PFC) without additional elements, while the other inductor is used to provide galvanic isolation and required voltage conversion ratio. A modular interleaved structure of the converter helps to implement low-profile converter design with standard components, distribute the power losses and improve the performance. An optima... [more]

A horizontal well with hydraulic fractures is key to forming a fracture network in oil shale for the generated hydrocarbon flows. By considering the influence of anisotropic strength, a prediction model is proposed for fracture initiation by studying different fracture initiation modes (FIMs) in oil shale: failure of the intact rock matrix and of the bedding planes. Through a case study on Nong’an oil shale, the influences of wellbore trajectory and bedding planes on the fracture initiation pressure (FIP), location (FIL), and FIM were analyzed and the induced changes in wellbore trajectory design were concluded. The preferred angle between the wellbore axis and the minimum horizontal principal stress was the same of 90° or 270°, when the lowest required FIP corresponded to the failure of the intact rock matrix. However, when the angle corresponded to the failure of the bedding planes, the preferred direction of the wellbore axis was away from the fixed direction and not corresponding t... [more]

Catalytic hydrotreatment is recognized as an efficient method to improve the properties of pyrolysis liquids (PO) to allow co-feeding with fossil fuels in conventional refinery units. The promising catalyst recipes identified so far are catalysts with high nickel contents (38 to 57 wt.%), promoted by Cu, Pd, Mo and/or a combination, and supported by SiO2, SiO2-ZrO2, SiO2-ZrO2-La2O3 or SiO2-Al2O3. To gain insights into the reactivity of the pyrolytic sugar (PS) and pyrolytic lignin (PL) fraction of PO, hydrotreatment studies (350 °C, 120 bar H2 pressure (RT) for 4 h) were performed in a batch autoclave. Catalyst performance was evaluated by considering the product properties (H/C ratio, the charring tendency (TGA) and molecular weight distribution (GPC)) and the results were compared with a benchmark Ru/C catalyst. All Ni based catalysts gave products oils with a higher H/C compared to Ru/C. The Mo promoted catalyst performed best, giving a product with the highest H/C ratio (1.54) and... [more]

Strong tectonic movement brings great risk to exploration of shale gas in southern China, especially in Lower Cambrian shale with complex tectonic backgrounds, which has good hydrocarbon-generation matter but low or no gas content. In this paper, the Lower Cambrian shale from the southeast Chongqing region, located in the Upper Yangtze Platform, and the Xiuwu Basin, located in the Lower Yangtze Platform, were selected as the research objects. First, the gas components in shale gas samples were measured, then analysis of nitrogen isotopic was used to reveal the nitrogen sources. Using regional geological backgrounds, core description, and seismic interpretation, combined with the perpendicular and parallel permeability test and focused ion beam−helium ion microscopy (FIB−HIM) observation, the reasons for high content of nitrogen in the Lower Cambrian shale from the Xiuwu Basin and the Southeast Chongqing region were clarified. The results indicate that the main sources of nitrogen in th... [more]

The quick U-building (QUB) method is used to measure the overall heat loss coefficient of buildings during one to two nights by applying heating power and by measuring the indoor and the outdoor temperatures. In this paper, the numerical model of a real house, previously validated on experimental data, is used to conduct several numerical QUB experiments. The results show that, to some extent, the accuracy of QUB method depends on the boundary conditions (solar radiation), initial conditions (initial power and temperature distribution in the walls) and on the design of QUB experiment (heating power and duration). QUB method shows robustness to variation in the value of the overall heat loss coefficient for which the experiment was designed and in the variation of optimum power for the QUB experiments. The variations in the QUB method results are smaller on cloudy than on sunny days, the error being reduced from about 10% to about 7%. A correction is proposed for the solar radiation abs... [more]

The paper investigates the dynamics of the thermal field of the ACCC (aluminum conductor composite core) line. The system was heated by solar radiation and current flow. Conductor cooling was modeled using the total heat transfer coefficient as the sum of convective and radiative components. The temperature increase generated by the current is described by a system of parabolic differential equations with an appropriate set of boundary, initial and continuity condition. The mentioned boundary-initial problem was solved by a modified Green’s method, adapted to the layered structure of the system. For this purpose, Green’s functions, as the kernels of integral operators inverse to differential ones, were determined. Aluminum resistivity and heat transfer coefficient change significantly with temperature. For this reason, the solution to the problem is presented in the form of a lower and upper estimation of the heating curve and local time constant. A steady-state current rating was also... [more]

In this study, the vertically-oriented pulsating heat pipe (PHP) heat exchangers charged with either water or HFE-7000 in a filling ratio of 35% or 50% were fabricated to exchange the thermal energy between two air streams in a parallel-flow arrangement. Both the effectiveness of the heat exchangers and the thermal resistance of PHP with a size of 132 × 44 × 200 mm, at a specific evaporator temperature ranging from 55 to 100 °C and a specific airflow velocity ranging from 0.5 to 2.0 m/s were estimated. The results show that the heat pipe charged with HFE-7000 in either filling ratio is likely to function as an interconnected array of thermosiphon under all tested conditions because of the unfavorable tube inner diameter, whereas the water-charged PHP possibly creates the pulsating movement of the liquid and vapor slugs once the evaporator temperature is high enough, especially in a filling ratio of 50%. The degradation in the thermal performance of the HFE-7000-charged PHP heat exchang... [more]

This manuscript presents an advanced exergo-economic analysis of a waste heat recovery system based on the organic Rankine cycle from the exhaust gases of an internal combustion engine. Different operating conditions were established in order to find the exergy destroyed values in the components and the desegregation of them, as well as the rate of fuel exergy, product exergy, and loss exergy. The component with the highest exergy destroyed values was heat exchanger 1, which is a shell and tube equipment with the highest mean temperature difference in the thermal cycle. However, the values of the fuel cost rate (47.85 USD/GJ) and the product cost rate (197.65 USD/GJ) revealed the organic fluid pump (pump 2) as the device with the main thermo-economic opportunity of improvement, with an exergo-economic factor greater than 91%. In addition, the component with the highest investment costs was the heat exchanger 1 with a value of 2.769 USD/h, which means advanced exergo-economic analysis i... [more]

In this study, the cold-start failure processes of a polymer electrolyte fuel cell have been investigated numerically for different initial membrane water content λ 0 and the startup current densities I 0 . The result shows that the failure of the cell cold-start process is mostly attributed to the anode dehydration when the cell operates with relatively large current density. However, the failure is dominated by the cathode pore blockage when the cell starts with relatively high initial membrane water content. Corresponding maps for the classification of startup failure modes are plotted on the λ 0 − I 0 plane with different startup temperatures. Three zones, including the anode dehydration, the cathode pore blockage, and the ambiguous region, can be observed. They can be distinguished with different startup failure mechanisms. The anode dehydration zone is expanded as the cell startup temperature drops due to the weakening of the membrane water back-dif... [more]

The electrolyte is one of the three essential constituents of a Lithium-Ion battery (LiB) in addition to the anode and cathode. During increasingly high power and high current charging and discharging, the requirement for the electrolyte becomes more strict. Solid State Electrolyte (SSE) sees its niche for high power applications due to its ability to suppress concentration polarization and otherwise stable properties also related to safety. During high power and high current cycling, heat management becomes more important and thermal conductivity measurements are needed. In this work, thermal conductivity was measured for three types of solid state electrolytes: Li 7 La 3 Zr 2 O 12 (LLZO), Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 (LAGP), and Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 (LATP) at different compaction pressures. LAGP and LATP were measured after sintering, and LLZO was measured befo... [more]

This study evaluates energy efficiency of pastoral (PDFs) and barn (BDFs) dairy farming systems in New Zealand through application of data envelopment analysis (DEA) approach. Two models constant return to scale (CCR) and variable return to scale (BCC) of DEA were employed for determining the technical (TE), pure technical (PTE) and scale (SE) efficiencies of New Zealand pastoral and barn dairy systems. Further, benchmarking was also performed to separate efficient and inefficient dairy farms and energy saving potential was identified for both dairy systems based upon their optimal energy consumption. For this study, the energy inputs data were taken from 50 dairy farms (including PDFs and BDFs) across Canterbury, New Zealand. The results indicated that the average technical, pure technical and scale efficiencies of pastoral (PDFs) dairy systems were 0.84, 0.90, 0.93 and for barn (BDFs) systems were 0.78, 0.84, 0.92, respectively, showing that energy efficiency is slightly better in PD... [more]

In recent years, the exploitation and utilization of offshore oil and gas resources have attracted more attention. In offshore gas reservoir production, wellbore temperature and pressure change continuously when water-bearing natural gas flows upward. The wellbore temperature is also affected by the low-temperature sea water. The combination of temperatures and pressures controlled by the upward flow, and cooling from the surrounding seawater frequently leads to the conditions of temperature and pressure for hydrate formation. This can lead to pipeline blockage and other safety accidents. In this study, we utilize mathematical models of hydrate phase equilibrium, wellbore temperature, wellbore pressure to study hydrate formation and decomposition in offshore gas reservoir production. Numerical solution algorithms are developed and numerical solutions are validated. The sensitivity influence of different parameters on the regions and regularities of hydrate formation and decomposition i... [more]

Environmentally friendly and pollution-free fuel cell/lithium battery hybrid vehicles have received the attention of the community in recent years. It is imperative for fuel cell/lithium battery hybrid vehicles to use the energy management strategy (EMS) to distribute the output power of each power source to improve fuel economy and system life. In practical application, inconsistency of battery pack will lead to security hazard and capacity degradation. However, few EMS take the inconsistency of battery pack into account. Also, the current battery equalization strategy rarely discusses how to perform the equilibrium process while meeting the power demand of vehicle. To solve these issues, a novel equalization energy management strategy (EEMS) based on the switch network is proposed at first. Then, a switched energy management strategy (SEMS) that switches between the EEMS and the equivalent consumption minimization strategy (ECMS) is proposed and implemented in the fuel cell/lithium b... [more]

A battery/supercapacitor hybrid energy storage system is developed to mitigate the battery degradation for electric vehicles. By coordinating the battery and supercapacitor, the proposed system avoids using the large bidirectional DC/DC. Through the improved topology and two added controlled switches, the battery current can be managed flexibly. Based on the battery and supercapacitor voltage, seven operation modes of battery and capacitor cooperation are designed. The control strategy is redesigned to match the modes, in which the key control parameters are calibrated based on three standard driving cycles. During driving, the proposed system calls the predefined parameter set by the cycle recognition technique. The objective of the cycle-related control is to maximize the harvest of the braking energy and minimize battery degradation in various driving styles. Taking the battery case solely as a benchmark and the infinite supercapacitors case as the largest battery degradation mitiga... [more]

In this work, different methods and electrochemical set-ups were investigated in order to study the corrosion behaviour of bipolar plates (BPP) for high temperature (HT) polymer electrolyte membrane fuel cell application. Using confocal and scanning electron microscopy, it was shown that chemical and electrochemical aging significantly increases surface roughness as well as morphology changes, confirming material degradation. Identical electrochemical corrosion behaviour was observed for both set-ups with typical quinone/hydroquinone peaks in the potential range ~0.6−0.7 V versus reversible hydrogen electrode (RHE). The appearance of the peaks and an increase of double layer capacitance can be related to the oxidation of carbon surface and, consequently, material corrosion. Simultaneously, an optimised corrosion set-up was introduced and verified regarding suitability. Both investigated set-ups and methods are useful to analyse the oxidation behaviour and corrosion resistance.

The engine generator system with a diode rectifier causes harmonic currents in the generator which can affect generator efficiency and may produce torque oscillations. Using an active rectifier instead of a diode rectifier helps us to improve the current waveforms. In this paper, an active rectifier is used for a stand-alone gas engine generation system with a permanent magnet synchronous generator (PMSG). The generator side converter and the load side converter can be controlled separately to achieve high performance and reliability of the system. In the proposed control framework, the generator side converter is controlled by means of a current vector control method in a cascade structure with the synchronous reference frame (dq- frame). In the proposed control scheme, the dc link voltage is controlled by the generator side converter. For load side converter control, the concept of virtual synchronous generator control method is adopted to support a smooth power transient during the... [more]

In marine sediments, seawater influences the phase behavior of natural gas hydrate. As a porous medium, the water distribution and physical properties of montmorillonite are influenced by the salt ions in seawater. In this work, the bound-water content in, and crystal structure of, montmorillonite is measured to investigate the effect of salt ions on the water distribution in montmorillonite. It can be determined from the results that the bound-water content in montmorillonite decreases as the salt-ion concentration increases. Salt ions affect the intercalation of water molecules in montmorillonite, and they then inhibit the expansion effect of montmorillonite. Next, the phase behaviors of methane hydrate in montmorillonite with NaCl solution are investigated using high-pressure micro-differential scanning calorimetry. The phase behavior of hydrate in montmorillonite with NaCl solution is discussed. In montmorillonite with NaCl solution, the phase equilibrium temperatures and the conve... [more]

In order to minimize the peak load of electric vehicles (EVs) and enhance the resilience of fast EV charging stations, several sizing methods for deployment of the stationary energy storage system (ESS) have been proposed. However, methods for assessing the optimality of the obtained results and performance of the determined sizes under different conditions are missing. In order to address these issues, a two-step approach is proposed in this study, which comprises of optimality analysis and performance evaluation steps. In the case of optimality analysis, random sizes of battery and converter (scenarios) are generated using Monte Carlo simulations and their results are compared with the results of sizes obtained from sizing methods. In order to carry out this analysis, two performance analysis indices are proposed in this study, which are named the cost index and the power index. These indices respectively determine the performance of the determined sizes in terms of total network cos... [more]

The trade-off between economic growth and ecological improvement has always become an important and difficult issue for many countries, especially for developing countries. Due to a long-term extensive economic growth pattern, the regional resource allocation deviates from the optimal, especially the existence of energy misallocation, which hinders the maximization of economic output. Therefore, considering the characteristics and heterogeneity of resource endowments in different regions and increasing renewable energy consumption, that is, promoting energy transition, is it capable of sustainable development under China’s actual conditions? The exploration of the issue is a core step in the research of the impact of renewable energy on industrial green transformation. Based on the panel data of 30 regions in China from 2009 to 2016, this paper constructs a threshold model from the perspective of regional energy misallocation and empirically tests the nonlinear mechanism of renewable e... [more]

The fastest-growing renewable source of energy is solar photovoltaic (PV) energy, which is likely to become the largest electricity source in the world by 2050. In order to be a viable alternative energy source, PV systems should maximise their efficiency and operate flawlessly. However, in practice, many PV systems do not operate at their full capacity due to several types of anomalies. We propose tailored algorithms for the detection of different PV system anomalies, including suboptimal orientation, daytime and sunrise/sunset shading, brief and sustained daytime zero-production, and low maximum production. Furthermore, we establish simple metrics to assess the severity of suboptimal orientation and daytime shading. The proposed detection algorithms were applied to a set of time-series of electricity production in Portugal, which are based on two periods with distinct weather conditions. Under favourable weather conditions, the algorithms successfully detected most of the time-series... [more]

This study performs energetic and exergetic comparisons between the steam methane reforming and steam methanol reforming technologies combined with HT-PEMFC and a carbon capture/liquefaction system for use in hydrogen-fueled ships. The required space for the primary fuel and captured/liquefied CO2 and the fuel cost have also been investigated to find the more advantageous system for ship application. For the comparison, the steam methane reforming-based system fed by LNG and the steam methanol reforming-based system fed by methanol have been modeled in an Aspen HYSYS environment. All the simulations have been conducted at a fixed Wnet, electrical (475 kW) to meet the average shaft power of the reference ship. Results show that at the base condition, the energy and exergy efficiencies of the methanol-based system are 7.99% and 1.89% higher than those of the methane-based system, respectively. The cogeneration efficiency of the methane-based system is 7.13% higher than that of the methan... [more]

Precise pressure core motion, including translation and rotation, is the basis and core part of the Analysis and Transfer System of Natural Gas Hydrate Pressure Core, which is crucial to nondestructive analyses, core cutting, and transfer. This paper mainly proposes a driving device, whereby a pressure core, up to 3 m long, can be transferred from pressure core drilling tools to proceed to nondestructive analyses and transferring the cores into other chambers. The lead screw is one of the most important components of this driving device. Therefore, the modal analyses of the lead screw are performed, which can help researchers to analyze the stability of this device. The analyzed data shows that the different positions of the slider have a great impact on the natural frequency of the lead screw. Furthermore, the lead screw with a support slider has a larger natural frequency than that without a support slider. According to data analysis, we can derive that the device with the support sl... [more]

Despite the strengthening of vehicle emissions standards and test methods, nitrogen oxide (NOx) emissions from on-road mobile sources are not being notably reduced. The introduction of real driving emission (RDE) regulations is expected to reduce the discrepancy between emission regulations and actual air pollution. To analyze the effects of RDE regulations on heavy-duty diesel vehicles, pollutants emitted while driving were measured using a portable emission measurement system (PEMS) for Euro 5 and Euro 6 vehicles, which were produced before and after RDE regulations, respectively. NOx emissions were compared as a function of emissions allowance standards, gross vehicle weight (GVW), average vehicle speed, and ambient temperature. NOx emissions from Euro 6 vehicles were found to be low, regardless of GVW; emissions from both vehicular categories increased with a decline in the average speed. To reflect real road driving characteristics more broadly in the RDE test method for heavy-dut... [more]