Effective water management increases the performance of proton exchange membrane fuel cells (PEMFCs). The liquid droplet movement mechanism in the cathode channel, the gas-liquid two-phase flow pattern, and the resulting pressure drop are important to water management in PEMFCs. This work employed computational fluid dynamics (CFD) with a volume of fluid (VOF) to simulate the effects of two operating parameters on the liquid water flow in the cathode flow channel: Gas diffusion layer (GDL) pore shape for water emergence, and distance between GDL pores. From seven pore shapes considered in this work, the longer the windward side of the micropore is, the larger the droplet can grow, and the duration of droplet growth movement will be longer. In the cases of two micropores for water introduction, a critical pore distance is noted for whether two droplets coalesce. When the micropore distance was shorter than this critical value, different droplets coalesce after the droplets grew to a cer... [more]

Heat generation and therefore thermal transport plays a critical role in ensuring performance, ageing and safety for lithium-ion batteries (LIB). Increased battery temperature is the most important ageing accelerator. Understanding and managing temperature and ageing for batteries in operation is thus a multiscale challenge, ranging from the micro/nanoscale within the single material layers to large, integrated LIB packs. This paper includes an extended literature survey of experimental studies on commercial cells investigating the capacity and performance degradation of LIB. It compares the degradation behavior in terms of the influence of operating conditions for different chemistries and cell sizes. A simple thermal model for linking some of these parameters together is presented as well. While the temperature appears to have a large impact on ageing acceleration above room temperature during cycling for all studied cells, the effect of SOC and C rate appear to be rather cell depend... [more]

Energy-storage metabolites such as neutral lipids and carbohydrates are valuable compounds for liquid biofuel production. The aim of this work is to elucidate the main biological responses of two algae species known for their effective energy-rich compound accumulation in nitrogen limitation and day−night cycles: Nannochloropsis gaditana, a seawater species, and Parachlorella kessleri, a freshwater species. Lipid and carbohydrate production are investigated, as well as cell resistance to mechanical disruption for energy-rich compound release. Nitrogen-depleted N. gaditana showed only a low consumption of energy-storage molecules with a non-significant preference for neutral lipids (TAG) and carbohydrates in day−night cycles. However, it did accumulate significantly fewer carbohydrates than P. kessleri. Following this, the highest levels of productivity for N. gaditana in chemostat cultures at four levels of nitrogen limitation were found to be 3.4 and 2.2 × 10−3 kg/m2·d for carbohydrat... [more]

This paper presents an optimal design for a nanogrid/microgrid for desert camps in the city of Hafr Al-Batin in Saudi Arabia. The camps were designed to operate as separate nanogrids or to operate as an interconnected microgrid. The hybrid nanogrid/microgrid considered in this paper consists of a solar system, storage batteries, diesel generators, inverter, and load components. To offer the designer/operator various choices, the problem was formulated as a multi-objective optimization problem considering two objective functions, namely: the cost of electricity (COE) and the loss of power supply probability (LPSP). Furthermore, various component models were implemented, which offer a variety of equipment compilation possibilities. The formulated problem was then solved using the multi-objective evolutionary algorithm, based on both dominance and decomposition (MOEA/DD). Two cases were investigated corresponding to the two proposed modes of operation, i.e., nanogrid operation mode and mi... [more]

About ten hydroelectric power plants realized from 1970 to 1990 in Romania are confronted with stator overheating. The developed mathematical model analyzes the voltage stability based on modal analysis of the Jacobian matrix, identifying the hazardous modes of variation between voltage and flow rate, correlated with the characteristics of the analyzed generators and their response to these variations. Vulnerable elements in the system for inductive and capacitive modes of operation are identified. In these conditions, hydro generators cannot attend the secondary voltage control, not even for a frequency power dependency control. The elaborated mathematical model was tested at the hydroelectric power plants Gilceag, Mariselu, and Susag with similar functioning conditions. The necessary conditions for stator ventilation and variation of flow hydrodynamic parameters during the operation were established. The theoretical model was tested with an experimental method applied separately for... [more]

Swirling flow with the formation of a precessing vortex core (PVC) in the draft tube model of a hydroturbine was studied. Experiments were performed on an aerodynamic setup under transient operating conditions of the hydroturbine. The turbine operating conditions were varied by continuously changing the flow rate at a constant runner speed. The transition from the partial load regime, when a precessing vortex core is formed, to the best efficiency point without a core is considered. Applied to this task, a comparison of the windowed Fourier transform with wavelet analysis is given. The dependence of the PVC lifetime in the transient regime correlates with the transient time. It is shown that the velocity profiles and the spectrum of pressure pulsations in transient regimes change quasistatically between part-load operation and the best efficiency point of the turbine. The phase-averaged velocity distributions in the transient regimes show that a transient regime is a sequence of quasis... [more]

Using numerical methods, studies have been carried out to determine the effect of the introduction of the technology of two-stage combustion of high-ash Karaganda coal on the main characteristics of heat and mass transfer processes in the furnace of the BKZ-75 boiler at Shakhtinskaya TPP (Kazakhstan). Various regimes of supplying additional air into the combustion space, the volume of which varied from 0% (traditional basic version) to 30% of the total volume of air required for fuel combustion, have been investigated using 3D computer modeling methods. The performed computational experiments made it possible to obtain the distributions of the total velocity vector, temperature fields, concentration fields of carbon monoxide CO and nitrogen dioxide NO2 over the entire volume of the furnace and at the outlet from it. The introduction of the two-stage combustion technology made it possible to optimize the combustion of high-ash coal, since in this case there is an increase in the tempera... [more]

In this manuscript, we report a detailed physico-chemical comparison between the α- and β-polymorphs of the NaMnO2 compound, a promising material for application in positive electrodes for secondary aprotic sodium batteries. In particular, the structure and vibrational properties, as well as electrochemical performance in sodium batteries, are compared to highlight differences and similarities. We exploit both laboratory techniques (Raman spectroscopy, electrochemical methods) and synchrotron radiation experiments (Fast-Fourier Transform Infrared spectroscopy, and X-ray diffraction). Notably the vibrational spectra of these phases are here reported for the first time in the literature as well as the detailed structural analysis from diffraction data. DFT+U calculations predict both phases to have similar electronic features, with structural parameters consistent with the experimental counterparts. The experimental evidence of antisite defects in the beta-phase between sodium and mangan... [more]

This paper presents the first systematic comparison between south-facing monofacial and bifacial photovoltaic (PV) modules, as well as between south-facing bifacial and vertical east-west facing bifacial PV modules in Alaska. The state’s solar industry, driven by the high price of energy and dropping equipment costs, is quickly growing. The challenges posed by extreme sun angles in Alaska’s northern regions also present opportunities for unique system designs. Annual bifacial gains of 21% were observed between side by side south-facing monofacial and bifacial modules. Vertical east-west bifacial modules had virtually the same annual production as south-facing latitude tilt bifacial modules, but with different energy production profiles.

Photovoltaic-thermal (PV/T) collectors have gained a lot of attention in recent years due to their substantial advantages as compared to ST or PV systems alone and even to other non-solar technologies. However, PV/Ts are still not as popular in industry or construction and they are not even known to major players implementing solar energy installations. In this article, a general presentation of PV/Ts and a review of their applications are given. First, different heat extraction media (e.g., air, water, bi-fluid, etc.) and hybrid design configurations of hybrid PV/T collectors are addressed. Next, the main applications of PV/T collectors are discussed in order to highlight their feasibility and usefulness and to raise awareness for adoption in the industry and buildings sector. Applications include desalination, air-conditioning, drying, trigeneration, etc. This paper should be considered as a reference form of PV/Ts to extract key points for future research and development as well as... [more]

In smart cities, it is expected that transport, communication as well as the movement of people and goods will take place in the shortest possible time while maintaining a high level of safety. In recent years, due to the significant increase in the number of passengers and vehicles on the road and the capacity limitations of transport networks, it has become necessary to use new technologies for intelligent control and traffic management. Intelligent transport systems use advanced technologies in the field of data gathering, information processing, and traffic control to meet current transport needs. To be able to effectively control and manage road traffic, it is necessary to have reliable mathematical models that allow for a faithful representation of the real traffic conditions. Models of this type are usually the basis of complex algorithms used in practice in road traffic control. The application of appropriate models reflecting the behavior of road users contributes to the reduc... [more]

The dynamic of the world’s crude oil market has drastically changed over the last decade [...]

A comprehensive review of different thermal energy storage materials for concentrated solar power has been conducted. Fifteen candidates were selected due to their nature, thermophysical properties, and economic impact. Three key energy performance indicators were defined in order to evaluate the performance of the different molten salts, using Solar Salt as a reference for low and high temperatures. The analysis provided evidence that nitrate-based materials are the best choice for the former and chloride-based materials are best for the latter instead of fluoride and carbonate-based candidates, mainly due to their low cost.

Recently, biomass application as a renewable energy source is increasing worldwide. However, its availability differs in dependence on the location and climate, therefore, agricultural residues as cow dung (CD) are being considered to supply heat and/or power installation. This paper aims at a wide evaluation of CD fuel properties and its prospect to apply in the form of pellets to direct combustion installations. Therefore, the proximate, ultimate composition and calorific value were analyzed, then pelletization and combustion tests were performed, and the ash characteristics were tested. It was found that CD is a promising source of bioenergy in terms of LHV (16.34 MJ·kg−1), carbon (44.24%), and fixed carbon (18.33%) content. During pelletization, CD showed high compaction properties and at a moisture content of 18%,and the received pellets’ bulk density reached ca. 470 kg·m−3 with kinetic durability of 98.7%. While combustion, in a fixed grate 25 kW boiler, high emissions of CO, SO2... [more]

Early warning of a potential rockburst risk and its area of occurrence helps to take effective and targeted measures to mitigate rockburst hazards. This study investigates the microseismic (MS) spatial-temporal precursory characteristic parameters in a typical steeply inclined and extremely thick coal seam (SIETCS) with high rockburst risk and proposes three spatial/temporal quantification parameters and a spatial-temporal early warning method. Analysis results of temporal parameters show that the sharp-rise-sharp-drop variation in total daily energy and event count can be regarded as a precursor for high energy tremor. The appearance of peak values of both energy deviation (≥20) and event count deviation (≥1) can be regarded as precursors that indicate imminent rockburst danger. A laboratory acoustic emission (AE) experiment reveals that precursor characteristics obtained from the study can be feasibly used to warn the rockburst risk. The spatial evolution laws of spatial parameters s... [more]

In this study, a holistic energy, economic and environmental assessment was performed on a prosumer-based district heating system, including scenarios with varying district size, retrofitting stages and system configurations. A modeling framework was built which comprises a thermal network design and simulation model; a building energy demand model for districts; and supply and storage technology models that allow assessing system solar fraction, equivalent annual cost and greenhouse gas emissions of district heating systems (DHS). Furthermore, the approach allows comparing the performance of a DHS with individual heating systems (IHS) for the district with the same set of technology options (rooftop-mounted solar thermal collectors, gas boilers and thermal storage tanks). The framework was applied to a Swiss case study. The results of the case study show that DHS often outperform IHS; however, parameters such as the district size, the retrofitting stage of buildings and the system con... [more]

This paper deals with energy efficiency examined through an integrated model that links energy with environment, technology, and urbanisation as related areas. Our main goal is to discover how efficiently developed countries use primary energy and electricity (secondary energy). We additionally want to find out how the inclusion of environmental care and renewable energy capacity affects efficiency. For that purpose, we set up an output-oriented BCC data envelopment analysis that employs a set of input variables with non-negative values to calculate the efficiency scores on minimising energy use and losses as well as environmental emissions for a sample of 30 OECD member states during the period from 2001 to 2018. We develop a couple of baseline models in which we find that countries have mean inefficiency margins of 16.1% for primary energy and from 10.8 to 13.5% for electricity. The results from the extended models show that taking care about environment does not affect efficiency in... [more]

The paper presents a new design solution for the multi-cylinder compressed air engine, described in the PL 216801 patent. A characteristic feature of the engine is its double-piston operation with pistons working in pairs in opposition and a reciprocating movement in toroidal cylinders. The energy of compressed air was used more effectively in the described engine than in the solutions known so far. Comparing the engine built in accordance with the PL 216801 patent with the parameters of the MP165 and MP3000 engines, lower air consumption in relation to the power generated on the shaft is demonstrated. The described engine uses only one crankshaft and one straight complex shaft, which constitutes an innovative combination of pistons, while maintaining the same engine operation as in the case of two crankshafts operating with phase shift and working chamber shift. Such a solution results in a reduction in the harmful space occurring at the beginning of the power stroke to the value clos... [more]

Exploitation of conventional energy resources has caused a deliberate increase in the emitted carbon in the atmosphere, which catalyzes global warming trends. This is a matter of concern, especially in Qatar, where fossil fuels (oil and gas) are largely relied upon for power production. The dependency on such resources could be gradually reduced by utilizing clean and renewable energy. Resource characterization is an important step to evaluate the potentiality of available renewable energy sources. Wind energy is one among them, which has not been assessed reliably so far in Qatar. We analyzed the wind energy potential along the onshore and offshore areas of Qatar using 40 years (1979−2018) of hourly wind data extracted from the ECMWF Reanalysis v5 (ERA5) database. Monthly, seasonal, annual, and decadal mean wind power densities have been derived. Reliability tests have been carried out at select onshore and offshore locations. Trends and inter-annual variability have been assessed. Th... [more]

Adaptive and flexible control techniques have recently been examined as methods of controlling flow and reducing the potential noise in vertical axis wind turbines. Two-Dimensional (2D) fluid flow simulation around rod-airfoil is addressed in this study as a simple component of the wind turbine by using Unsteady Reynolds Averaged Navier−Stokes (URANS) equations for prediction of noise using Ffowcs Williams-Hawkings (FW-H) analogy. To control the flow and reduce noise, the active controlling vibration rod method is utilized with a maximum displacement ranging from 0.01 C to 1 C (C: airfoil chord). Acoustic assessment indicates that the leading edge of the blade produces noise, that by applying vibration in cylinder, blade noise in 0.1 C and 1 C decreases by 22 dB and 35 dB, respectively. Applying vibration is aerodynamically helpful since it reduces the fluctuations in the airfoil lift force by approximately 48% and those in the rod by about 46%. Strouhal assessment (frequency) shows th... [more]

Energy consumed for air conditioning in residential and tertiary sectors accounts for a large share of global use. To reduce the environmental impacts burdening the covering of such demands, the adoption of renewable energy technologies is increasing. In this regard, this paper evaluates the energy and environmental benefits achievable by integrating a dish-Stirling concentrator into energy systems used for meeting the air conditioning demand of an office building. Two typical reference energy plants are assumed: (i) a natural gas boiler for heating purposes and air-cooled chillers for the cooling periods, and (ii) a reversible heat pump for both heating and cooling. For both systems, a dish-Stirling concentrator is assumed to operate first in electric-mode and then in a cogenerative-mode. Detailed models are adopted for plant components and implemented in the TRNSYS environment. Results show that when the concentrator is operating in electric-mode the electricity purchased from the gr... [more]

For the first time in dye-sensitized solar cell (DSSC) technology, a di-carbazole-based dye was synthesized and evaluated for its usage as a potential sensitizer for the development of wavelength selective semi-transparent DSSCs for greenhouses-oriented applications. The dye was designed to demonstrate a blue light absorption, allowing a high transmittance in the red region of the visible light, even after its adsorption on the anode semiconductor, which is the most important one for the photosynthetic action of the plants. The application of the new dye to DSSCs was examined using either a high-performance iodide-based electrolyte or a highly transparent iodine-free electrolyte to determine a good balance between electric power generation and device transparency. The spectral engineered DSSCs demonstrated quite promising characteristics, providing a high external quantum efficiency (higher than 70%) in the whole blue−green region of the visible light, while allowing high transparency... [more]

In this study, oil production and retention were observed and compared in 72 reservoir simulation cases, after which an economic analysis for various CO2 and oil prices was performed. Reservoir simulation cases comprise different combinations of water alternating gas (WAG) ratios, permeabilities, and well distances. These models were set at three different depths; thus different pressure and temperature conditions, to see the impact of miscibility on oil production and CO2 sequestration. Those reservoir conditions affect oil production and CO2 retention differently. The retention trend dependence on depth was not monotonic—optimal retention relative to the amount of injected CO2 could be achieved at middle depths and mediocre permeability as well. Results reflecting different reservoir conditions and injection strategies are shown, and analysis including the utilization factor and the net present value was conducted to examine the feasibility of different scenarios. The analysis presen... [more]

This manuscript shows the use of natural polysaccharides such as starch and cellulose as a carbon source for fuel cells. To achieve this, two innovative methods of obtaining hydrogen have been shown: by adsorption and by enzyme. The carbonization path of the material results in excellent sorption properties and allows gas with high efficiency to be obtained. The enzymatic method for the degradation of the compound is more expensive because specific enzymes (such as laccase, tyrosinase) must be used, but it allows greater control of the properties of the obtained material. A scientific novelty is the use of natural raw materials, the use of which increases the biodegradability of the electrochemical system and also reduces the cost of raw materials and increases the range of their acquisition. Energy should be generated where it is used. Another goal is decentralization, and thanks to the proposed solutions, hydrogen cells represent an innovative alternative to today’s energy giants—als... [more]

Despite significant advancements in fenestration technology in the last two decades, the thermal transmittance of fenestration products is still significantly higher than that of walls. This corresponds to 60% of the total energy loss of a modern building envelope through the windows. Hence, further development and improvements of fenestration products are necessary. Increasingly stringent codes and standards for fenestration stimulate industry to work on improved solutions. Thus, it is crucial that assessment techniques are able to account for innovations accurately. The thermal effects of non-continuous hardware in window frames are currently ignored by international rating procedures. A preliminary investigation conducted by our team showed significant performance degradation in two of the three out-opening casement profiles caused by the presence of operating hardware. Frames with the structure made of vinyl and fiberglass consist of many air cavities that are penetrated by operati... [more]