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Records Added in July 2019
Records added in July 2019
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129. LAPSE:2019.0757
Robustness Area Technique Developing Guidelines for Power System Restoration
July 26, 2019 (v1)
Subject: Process Operations
Keywords: energy function, power system restoration, power system stability, voltage stability
This paper proposes a novel energy based technique called the Robustness Area (RA) technique that measures power system robustness levels, as a helper for planning Power System Restorations (PSRs). The motivation is on account of the latest blackouts in Brazil, where the local Independent System Operator (ISO) encountered difficulties related to circuit disconnections during the restoration. The technique identifies vulnerable and robust buses, pointing out system areas that should be firstly reinforced during PSR, in order to enhance system stability. A Brazilian power system restoration area is used to compare the guidelines adopted by the ISO with a more suitable new plan indicated by the RA tool. Active power and reactive power load margin and standing phase angle show the method efficiency as a result of a well balanced system configuration, enhancing the restoration performance. Time domain simulations for loop closures and severe events also show the positive impact that the pro... [more]
130. LAPSE:2019.0756
Performance Evaluation of a Solar-Powered Regenerative Organic Rankine Cycle in Different Climate Conditions
July 26, 2019 (v1)
Subject: Process Design
Keywords: carbon dioxide emissions, Organic Rankine Cycle, primary energy consumption, regenerative ORC, solar ORC
A model to evaluate the performance of a solar powered regenerative Organic Rankine Cycle (R-ORC) using five dry organic fluids: RC318, R227ea, R236ea, R236fa, and R218, is presented in this paper. The system is evaluated in two locations in the U.S.: Jackson, MS and Tucson, AZ. The weather data for each location is used to determine the heat available from the solar collector that could be used by the R-ORC to generate power. Results from the R-ORC performance are compared with a basic ORC using first and second law criteria as well as primary energy consumption (PEC) and carbon dioxide emission (CDE) savings for both locations. An economic analysis to determine the maximum capital cost for a desired payback period is presented in this paper. A parametric analysis is also performed to study the effect of the turbine efficiency as well as the open feed organic fluid heater intermediate pressure on the system performance. Results indicate that the R-ORC is able to generate more power th... [more]
131. LAPSE:2019.0755
Dynamic Exergy Analysis for the Thermal Storage Optimization of the Building Envelope
July 26, 2019 (v1)
Subject: Process Design
Keywords: building envelope, dynamic exergy analysis, Energy Storage
As a measure of energy “quality”, exergy is meaningful for comparing the potential for thermal storage. Systems containing the same amount of energy could have considerably different capabilities in matching a demand profile, and exergy measures this difference. Exergy stored in the envelope of buildings is central in sustainability because the environment could be an unlimited source of energy if its interaction with the envelope is optimised for maintaining the indoor conditions within comfort ranges. Since the occurring phenomena are highly fluctuating, a dynamic exergy analysis is required; however, dynamic exergy modelling is complex and has not hitherto been implemented in building simulation tools. Simplified energy and exergy assessments are presented for a case study in which thermal storage determines the performance of seven different wall types for utilising nocturnal ventilation as a passive cooling strategy. Hourly temperatures within the walls are obtained with the ESP-r... [more]
132. LAPSE:2019.0754
The Economy-Carbon Nexus in China: A Multi-Regional Input-Output Analysis of the Influence of Sectoral and Regional Development
July 26, 2019 (v1)
Subject: Energy Policy
Keywords: China, CO2 emission, economic growth, multi-regional input-output
China has become the world’s largest carbon dioxide (CO₂) emitter. Sectoral production activities promote economic development while also adding considerably to national CO₂ emissions. Due to their different sectoral structures, each region shows different levels of economic development and CO₂ emissions. The Chinese government hopes to achieve the dual objectives of economic growth and CO₂ emissions reduction by encouraging those sectors that have high economic influence and low environmental influence. Based on the above background, this study constructed an inter-regional sectoral economic influence coefficient (REIC) and a CO₂ emissions influence coefficient (RCIC) based on the basic multi-regional input-output (MRIO) model to analyse the economy-carbon nexus of 17 sectors in 30 regions in China in 2010. The results showed that most Chinese sectors and regions had low CO₂ emissions influences in 2010. However, some sectors showed negative environmental influences. Specifically, the... [more]
133. LAPSE:2019.0753
Assessing the Feasibility of Global Long-Term Mitigation Scenarios
July 26, 2019 (v1)
Subject: Energy Policy
Keywords: climate change mitigation, low-carbon scenarios, mitigation feasibility
This study explores the critical notion of how feasible it is to achieve long-term mitigation goals to limit global temperature change. It uses a model inter-comparison of three integrated assessment models (TIAM-Grantham, MESSAGE-GLOBIOM and WITCH) harmonized for socio-economic growth drivers using one of the new shared socio-economic pathways (SSP2), to analyse multiple mitigation scenarios aimed at different temperature changes in 2100, in order to assess the model outputs against a range of indicators developed so as to systematically compare the feasibility across scenarios. These indicators include mitigation costs and carbon prices, rates of emissions reductions and energy efficiency improvements, rates of deployment of key low-carbon technologies, reliance on negative emissions, and stranding of power generation assets. The results highlight how much more challenging the 2 °C goal is, when compared to the 2.5⁻4 °C goals, across virtually all measures of feasibility. Any delay i... [more]
134. LAPSE:2019.0752
A States of Matter Search-Based Approach for Solving the Problem of Intelligent Power Allocation in Plug-in Hybrid Electric Vehicles
July 26, 2019 (v1)
Subject: Planning & Scheduling
Keywords: gravitational search (GSA), intelligent management, nature-inspired, particle swarm optimization (PSO), Plug-in Hybrid Electric Vehicles (PHEV), smart grid, state of matter search (SMS)
Recently, many researchers have proved that the electrification of the transport sector is a key for reducing both the emissions of green-house pollutants and the dependence on oil for transportation. As a result, Plug-in Hybrid Electric Vehicles (or PHEVs) are receiving never before seen increased attention. Consequently, large-scale penetration of PHEVs into the market is expected to take place in the near future, however, an unattended increase in the PHEVs needs may cause several technical problems which could potentially compromise the stability of power systems. As a result of the growing necessity for addressing such issues, topics related to the optimization of PHEVs’ charging infrastructures have captured the attention of many researchers. Related to this, several state-of-the-art swarm optimization methods (such as the well-known Particle Swarm Optimization (PSO) or the recently proposed Gravitational Search Algorithm (GSA) approach) have been successfully applied in the opti... [more]
135. LAPSE:2019.0751
Structural Identifiability of Equivalent Circuit Models for Li-Ion Batteries
July 26, 2019 (v1)
Subject: System Identification
Keywords: equivalent circuit models, lithium ion battery modelling, structural identifiability
Structural identifiability is a critical aspect of modelling that has been overlooked in the vast majority of Li-ion battery modelling studies. It considers whether it is possible to obtain a unique solution for the unknown model parameters from experimental data. This is a fundamental prerequisite of the modelling process, especially when the parameters represent physical battery attributes and the proposed model is utilised to estimate them. Numerical estimates for unidentifiable parameters are effectively meaningless since unidentifiable parameters have an infinite number of possible numerical solutions. It is demonstrated that the physical phenomena assignment to a two-RC (resistor⁻capacitor) network equivalent circuit model (ECM) is not possible without additional information. Established methods to ascertain structural identifiability are applied to 12 ECMs covering the majority of model templates used previously. Seven ECMs are shown not to be uniquely identifiable, reducing the... [more]
136. LAPSE:2019.0750
New Approaches to Circulating Current Controllers for Modular Multilevel Converters
July 26, 2019 (v1)
Subject: Process Control
Keywords: circulating current, modular multilevel converter (MMC), power quality, repetitive controller, resonant controller
In the next years, modular multilevel converters (MMCs) are going to be a next generation multilevel converters for medium to high voltage conversion applications, such as medium voltage motor drives, medium voltage flexible AC transmission systems (FACTS) and high voltage direct current transmission. They provide advantages such as high modularity, availability, low generation of harmonics, etc. However, the circulating current distorts the leg currents and increases the rated current of power devices, which further increases system cost. This paper focuses on analysis and suppression of these currents in a MMC using two algorithms for tracking of harmonics. For this work resonant controllers and repetitive controllers have been selected. Both controllers are analyzed and simulations results are presented. Moreover, the controllers have been tested and validated for a three phase MMC operating as an inverter using a real processing platform based on Zynq by Xilinx and designed to cont... [more]
137. LAPSE:2019.0749
Equivalence of Primary Control Strategies for AC and DC Microgrids
July 26, 2019 (v1)
Subject: Energy Management
Keywords: decentralized control, distributed generation (DG), inertia emulation, microgrids, power sharing, primary control, stability, virtual synchronous machine (VSM), virtual-impedance
Microgrid frequency and voltage regulation is a challenging task, as classical generators with rotational inertia are usually replaced by converter-interfaced systems that inherently do not provide any inertial response. The aim of this paper is to analyse and compare autonomous primary control techniques for alternating current (AC) and direct current (DC) microgrids that improve this transient behaviour. In this context, a virtual synchronous machine (VSM) technique is investigated for AC microgrids, and its behaviour for different values of emulated inertia and droop slopes is tested. Regarding DC microgrids, a virtual-impedance-based algorithm inspired by the operation concept of VSMs is proposed. The results demonstrate that the proposed strategy can be configured to have an analogous behaviour to VSM techniques by varying the control parameters of the integrated virtual-impedances. This means that the steady-state and transient behaviour of converters employing these strategies c... [more]
138. LAPSE:2019.0748
An Analysis of Different Solar-Assisted Heating Systems and Their Effect on the Energy Performance of Multifamily Buildings—A Swedish Case
July 26, 2019 (v1)
Subject: Process Design
Keywords: district heating, energy performance of buildings, heat pump, incentive schemes, solar-assisted
Today, the household sector in the European Union and in Sweden accounts for approximately 25% and 22% of the final energy demand, respectively, and the sector will continue to grow in the next decades. To limit the impact on the energy demand of buildings, the European Union has introduced the Energy Performance of Building Directive. In Sweden, a proposal for building regulations adapted to the Energy Performance of Buildings Directive has been released, but no decision on implementation of it has been made. In this article, a real building is simulated to evaluate how different combinations of heating and decentralized energy generation systems are affecting the specific energy demand of the building. Also, an analysis on how the Swedish incentive schemes affect the choice of decentralized energy generation systems is conducted. Furthermore, it is investigated if it is necessary to adopt the incentive schemes to steer towards systems that reduce the specific energy demand of the bui... [more]
139. LAPSE:2019.0747
Modeling and Vulnerability Analysis of Cyber-Physical Power Systems Considering Network Topology and Power Flow Properties
July 26, 2019 (v1)
Subject: Energy Management
Keywords: cascading failure, complex network theory, cyber-physical power system (CPPS), interdependence, vulnerability analysis
Conventional power systems are developing into cyber-physical power systems (CPPS) with wide applications of communication, computer and control technologies. However, multiple practical cases show that the failure of cyber layers is a major factor leading to blackouts. Therefore, it is necessary to discuss the cascading failure process considering cyber layer failures and analyze the vulnerability of CPPS. In this paper, a CPPS model, which consists of cyber layer, physical layer and cyber-physical interface, is presented using complex network theory. Considering power flow properties, the impacts of cyber node failures on the cascading failure propagation process are studied. Moreover, two vulnerability indices are established from the perspective of both network structure and power flow properties. A vulnerability analysis method is proposed, and the CPPS performance before and after cascading failures is analyzed by the proposed method to calculate vulnerability indices. In the cas... [more]
140. LAPSE:2019.0746
Numerical Investigation of the Time-Dependent and the Proppant Dominated Stress Shadow Effects in a Transverse Multiple Fracture System and Optimization
July 26, 2019 (v1)
Subject: Process Operations
Keywords: 3D numerical modeling, hydro-mechanical coupling, Optimization, time-dependent and proppant dominated stress shadow effect, transverse multiple fracture
In this paper, a numerical study is conducted to investigate the stress shadow effects (stress reorientation and change) during hydraulic fracturing in a transverse multiple fracture system. A numerical model is used for the numerical study. It is a 3D model and can simulate the fracture operation from injection begin to full closure (fracture contact). Therefore, there is no need to assume the fracture geometry for the investigation of the stress shadow effects (unlike previous studies). In the numerical study, the first and second operations in a fictive transverse multiple fracture system are simulated, meanwhile the stress shadow effects and their influences on the propagation and proppant placement of the second fracture are investigated. According to the results, the following conclusions are discerned: (1) most proppants are located in the lower part of the reservoir, even below the perforation; (2) the stress shadow effects are time-dependent and proppant dominated; (3) the str... [more]
141. LAPSE:2019.0745
Integrated Equivalent Circuit and Thermal Model for Simulation of Temperature-Dependent LiFePO₄ Battery in Actual Embedded Application
July 26, 2019 (v1)
Subject: Modelling and Simulations
Keywords: battery management system, cell model, convective thermal model, lithium-ion battery, state-of-charge
A computational efficient battery pack model with thermal consideration is essential for simulation prototyping before real-time embedded implementation. The proposed model provides a coupled equivalent circuit and convective thermal model to determine the state-of-charge (SOC) and temperature of the LiFePO₄ battery working in a real environment. A cell balancing strategy applied to the proposed temperature-dependent battery model balanced the SOC of each cell to increase the lifespan of the battery. The simulation outputs are validated by a set of independent experimental data at a different temperature to ensure the model validity and reliability. The results show a root mean square (RMS) error of 1.5609 × 10−5 for the terminal voltage and the comparison between the simulation and experiment at various temperatures (from 5 °C to 45 °C) shows a maximum RMS error of 7.2078 × 10−5.
142. LAPSE:2019.0744
Field Synergy Analysis and Optimization of the Thermal Behavior of Lithium Ion Battery Packs
July 26, 2019 (v1)
Subject: Modelling and Simulations
Keywords: battery pack, electric vehicle, field synergy principle, temperature uniformity
In this study, a three dimensional (3D) modeling has been built for a lithium ion battery pack using the field synergy principle to obtain a better thermal distribution. In the model, the thermal behavior of the battery pack was studied by reducing the maximum temperature, improving the temperature uniformity and considering the difference between the maximum and maximum temperature of the battery pack. The method is further verified by simulation results based on different environmental temperatures and discharge rates. The thermal behavior model demonstrates that the design and cooling policy of the battery pack is crucial for optimizing the air-outlet patterns of electric vehicle power cabins.
143. LAPSE:2019.0743
Design and Optimization of an Inductively Coupled Power Transfer System for the Underwater Sensors of Ocean Buoys
July 26, 2019 (v1)
Subject: Process Design
Keywords: buoy, inductively coupled power transfer system, mutual inductance, optimal parameters
Batteries are commonly used as the power source of present underwater sensors of ocean buoys. However, batteries need to be frequently replaced, which is costly. To implement the real-time power supply for a buoy’s underwater sensor, a new inductively coupled power transfer (ICPT) system that consists of two couplers and a closed cable is proposed in this paper. The special closed cable, which is the both mooring cable and transmission media, is designed to diminish the influence of changes on impedance. A model of the particular ICPT system is established. Optimization of system parameters are carried out based on the model and verified by means of the simulations. Resonant compensation is used to improve the power transfer performance. Finally, many experiments are implemented to compare with the original prototype. It is confirmed that this system can help solve the difficulty of the energy limit to a buoy’s underwater sensor.
144. LAPSE:2019.0742
Day-Ahead Scheduling Considering Demand Response as a Frequency Control Resource
July 26, 2019 (v1)
Subject: Planning & Scheduling
Keywords: day-ahead scheduling, demand response (DR), frequency control, unit commitment
The development of advanced metering technologies makes demand response (DR) able to provide fast response services, e.g., primary frequency control. It is recognized that DR can contribute to the primary frequency control like thermal generators. This paper proposes a day-ahead scheduling method that considers DR as a frequency control resource, so that the DR resources can be dispatched properly with other resources. In the proposed method, the objective of frequency control is realized by defining a frequency limit equation under a supposed contingency. The frequency response model is used to model the dynamics of system frequency. The nonlinear frequency limit equation is transformed to a linear arithmetic equation by piecewise linearization, so that the problem can be solved by mixed integer linear programming (MILP). Finally, the proposed method is verified on numerical examples.
145. LAPSE:2019.0741
A Frequency Control Approach for Hybrid Power System Using Multi-Objective Optimization
July 26, 2019 (v1)
Subject: Energy Management
Keywords: frequency control, full-order observer, hybrid power system, multi-objective optimization, supply balance
A hybrid power system uses many wind turbine generators (WTG) and solar photovoltaics (PV) in isolated small areas. However, the output power of these renewable sources is not constant and can diverge quickly, which has a serious effect on system frequency and the continuity of demand supply. In order to solve this problem, this paper presents a new frequency control scheme for a hybrid power system to ensure supplying a high-quality power in isolated areas. The proposed power system consists of a WTG, PV, aqua-electrolyzer (AE), fuel cell (FC), battery energy storage system (BESS), flywheel (FW) and diesel engine generator (DEG). Furthermore, plug-in hybrid electric vehicles (EVs) are implemented at the customer side. A full-order observer is utilized to estimate the supply error. Then, the estimated supply error is considered in a frequency domain. The high-frequency component is reduced by BESS and FW; while the low-frequency component of supply error is mitigated using FC, EV and D... [more]
146. LAPSE:2019.0740
Effect on Torque and Thrust of the Pointed Tip Shape of a Wind Turbine Blade
July 26, 2019 (v1)
Subject: Process Design
Keywords: National Renewable Energy Laboratory (NREL) Phase VI, pointed tip blade, separation and transition, shear-stress-transport (SST) Gamma-Theta turbulent model, wind energy, wind turbine blade
This paper presents the effect of the tip shape of a wind turbine blade on aerodynamic forces, including the effects of separation, transition and stall. A National Renewable Energy Laboratory (NREL) Phase-VI wind turbine blade was used, in which the shape of the tip was modified to a pointed tip. Computational fluid dynamics (CFD) simulations were employed for the analysis and the results were compared with the original NREL blade CFD and experimental data using ANSYS CFX (Ansys Inc., Delaware, PA, USA). To predict the separation and separation-induced transition on both near wall and far away, the shear-stress-transport (SST) Gamma-Theta turbulent model was used. The stall onset of a 20° angle of attack and its effects were also analyzed and presented. The value of torque with the pointed tip blade was found to be 3%⁻8% higher than the original NREL blade showing the benefit of the pointed tip. Normal force coefficient is lower at the tip for the pointed tip blade, which results in l... [more]
147. LAPSE:2019.0739
Tie-Line Bias Control Applicability to Load Frequency Control for Multi-Area Interconnected Power Systems of Complex Topology
July 26, 2019 (v1)
Subject: Energy Management
Keywords: load frequency control, ring network, tie-line bias control (TBC) applicability, topology
The tie-line bias control (TBC) method has been widely used in the load frequency control (LFC) of multi-area interconnected systems. However, it should be questioned whether the conventional TBC can still apply to LFC when considering the complication of structures of power systems. LFC, in essence, is to stabilize system frequency/tie-line power by controlling controlled outputs’ area control error (ACE). In this paper, relations between LFC control variables and controlled outputs are expressed as a system of equations, based on which an exemplary ring network is studied. Sufficient and necessary conditions for TBC applicability is presented, and a novel LFC mode is proposed for a general ring network where TBC cannot work. Finally, TBC applicability to multi-area systems with general topology is studied, and a general LFC mode is proposed for systems where TBC is not definitely applicable, thus rendering routines that may guide LFC design of future power systems with more complex t... [more]
148. LAPSE:2019.0738
A Mixed Logical Dynamical-Model Predictive Control (MLD-MPC) Energy Management Control Strategy for Plug-in Hybrid Electric Vehicles (PHEVs)
July 26, 2019 (v1)
Subject: Energy Management
Keywords: driving intention, mixed integer linear programming (MILP), mixed logic dynamical model, model predictive control (MPC), nonlinear auto-regressive (NAR) neural network
Plug-in hybrid electric vehicles (PHEVs) can be considered as a hybrid system (HS) which includes the continuous state variable, discrete event, and operation constraint. Thus, a model predictive control (MPC) strategy for PHEVs based on the mixed logical dynamical (MLD) model and short-term vehicle speed prediction is proposed in this paper. Firstly, the mathematical model of the controlled PHEV is set-up to evaluate the energy consumption using the linearized models of core power components. Then, based on the recognition of driving intention and the past vehicle speed data, a nonlinear auto-regressive (NAR) neural network structure is designed to predict the vehicle speed for known driving profiles of city buses and the predicted vehicle speed is used to calculate the total required torque. Next, a MLD model is established with appropriate constraints for six possible driving modes. By solving the objective function with the Mixed Integer Linear Programming (MILP) algorithm, the opt... [more]
149. LAPSE:2019.0737
Ensemble Prediction Model with Expert Selection for Electricity Price Forecasting
July 26, 2019 (v1)
Subject: Intelligent Systems
Keywords: electricity price forecasting, ensemble model, expert selection
Forecasting of electricity prices is important in deregulated electricity markets for all of the stakeholders: energy wholesalers, traders, retailers and consumers. Electricity price forecasting is an inherently difficult problem due to its special characteristic of dynamicity and non-stationarity. In this paper, we present a robust price forecasting mechanism that shows resilience towards the aggregate demand response effect and provides highly accurate forecasted electricity prices to the stakeholders in a dynamic environment. We employ an ensemble prediction model in which a group of different algorithms participates in forecasting 1-h ahead the price for each hour of a day. We propose two different strategies, namely, the Fixed Weight Method (FWM) and the Varying Weight Method (VWM), for selecting each hour’s expert algorithm from the set of participating algorithms. In addition, we utilize a carefully engineered set of features selected from a pool of features extracted from the p... [more]
150. LAPSE:2019.0736
Detection of Internal Short Circuit in Lithium Ion Battery Using Model-Based Switching Model Method
July 26, 2019 (v1)
Subject: Process Monitoring
Keywords: battery safety, internal short circuit resistance, model updating method
Early detection of an internal short circuit (ISCr) in a Li-ion battery can prevent it from undergoing thermal runaway, and thereby ensure battery safety. In this paper, a model-based switching model method (SMM) is proposed to detect the ISCr in the Li-ion battery. The SMM updates the model of the Li-ion battery with ISCr to improve the accuracy of ISCr resistance R I S C f estimates. The open circuit voltage (OCV) and the state of charge (SOC) are estimated by applying the equivalent circuit model, and by using the recursive least squares algorithm and the relation between OCV and SOC. As a fault index, the R I S C f is estimated from the estimated OCVs and SOCs to detect the ISCr, and used to update the model; this process yields accurate estimates of OCV and R I S C f . Then the next R I S C f is estimated and used to update the model iteratively. Simulation data from a MATLAB/Simulink model and experimental data verify that this algor... [more]
151. LAPSE:2019.0735
Experimental Analysis and Full Prediction Model of a 5-DOF Motorized Spindle
July 26, 2019 (v1)
Subject: Other
Keywords: experimental analysis, magnetic bearing, Modelling, prediction model, suspension force
The cost and power consumption of DC power amplifiers are much greater than that of AC power converters. Compared to a motorized spindle supported with DC magnetic bearings, a motorized spindle supported with AC magnetic bearings is inexpensive and more efficient. This paper studies a five-degrees-of-freedom (5-DOF) motorized spindle supported with AC hybrid magnetic bearings (HMBs). Most models of suspension forces, except a “switching model”, are quite accurate, but only in a particular operating area and not in regional coverage. If a “switching model” is applied to a 5-DOF motorized spindle, the real-time performance of the control system can be significantly decreased due to the large amount of data processing for both displacement and current. In order to solve this defect, experiments based on the “switching model” are performed, and the resulting data are analyzed. Using the data analysis results, a “full prediction model” based on the operating state is proposed to improve rea... [more]
152. LAPSE:2019.0734
An Optimal Augmented Monotonic Tracking Controller for Aircraft Engines with Output Constraints
July 26, 2019 (v1)
Subject: Process Control
Keywords: aircraft engines, genetic algorithms, min-max control, optimal augmented monotonic tracking control (OAMTC)
This paper proposes a novel min-max control scheme for aircraft engines, with the aim of transferring a set of regulated outputs between two set-points, while ensuring a set of auxiliary outputs remain within prescribed constraints. In view of this, an optimal augmented monotonic tracking controller (OAMTC) is proposed, by considering a linear plant with input integration, to enhance the ability of the control system to reject uncertainty in system parameters and ensure no crossing limits. The key idea is to use the eigenvalue and eigenvector placement method and genetic algorithms to shape the output responses. The approach is validated by numerical simulation. The results show that the designed OAMTC controller can achieve a satisfactory dynamic and steady performance and keep the auxiliary outputs within constraints in the transient regime.
153. LAPSE:2019.0733
Thermochemical Storage of Middle Temperature Wasted Heat by Functionalized C/Mg(OH)₂ Hybrid Materials
July 26, 2019 (v1)
Subject: Materials
Keywords: carbon nanotubes, exfoliated graphite, graphene oxide, magnesium hydroxide, thermochemical storage
For the thermochemical performance implementation of Mg(OH)₂ as a heat storage medium, several hybrid materials have been investigated. For this study, high-performance hybrid materials have been developed by exploiting the authors’ previous findings. Expanded graphite (EG)/carbon nanotubes (CNTs)-Mg(OH)₂ hybrid materials have been prepared through Mg(OH)₂ deposition-precipitation over functionalized, i.e., oxidized, or un-functionalized EG or CNTs. The heat storage performances of the carbon-based hybrid materials have been investigated through a laboratory-scale experimental simulation of the heat storage/release cycles, carried out by a thermogravimetric apparatus. This study offers a critical evaluation of the thermochemical performances of developed materials through their comparison in terms of heat storage and output capacities per mass and volume unit. It was demonstrated that both EG and CNTs improves the thermochemical performances of the storage medium in terms of reaction r... [more]
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