-(2-Hydroxyethyl) piperazine (HEPZ) has a chemical structure similar to PZ and has less volatility. It is not easy to volatilize in a continuous operation device. It is studied to replace PZ as a promotor to increase the CO2 capture rate. This paper researches the lowest energy consumption and absorbent loss of HEPZ/H2O in the absorption-regeneration process, and compares it with another five amines, including PZ, MEA, 1-MPZ, AMP and DMEA. Based on the thermodynamic model, this work establishes a process simulation based on the equilibrium stage, assuming that all stages of the absorption and desorption towers reach thermodynamic equilibrium and CO2 recovery in the absorption tower is 90%. By optimizing the process parameters, the lowest thermodynamic energy consumption and absorbent loss of process operation are obtained. Our results show that HEPZ as a promotor to replace PZ and MEA has significant economic value. The lowest reboiler energy consumption of HEPZ with the optimal proces... [more]

The novel modified absorption heat pump (MAHP) with the H2O-LiBr working mixture for cogeneration applications is introduced. The MAHP can simultaneously produce electric energy and heat revaluation. The proposed system has the particularity that it can be powered by alternative thermal sources (such as solar energy, biomass, geothermal) or industrial waste heat, thus promoting the production and efficient use of clean energy. The effects of pressure ratio (RP), source or supply temperature (TGH), and the energy revaluation gradient (GTL) are analyzed. The critical parameters of the proposed system are evaluated, including thermal efficiency (ηTh), exergetic efficiency (ηEx), revaluated heat (Q˙A), as well as net power produced (˙Wnet). For the MAHP analysis, RP and TGH operating ranges were chosen at 1.1−15.0 and 100−160 °C, respectively. The results show that ηEx of 87% can be obtained, having the maximum performance in TGH of 120 °C, RP of 1.1, and GTL of 35 °C. The ηTh varies betwe... [more]

The enhancement of mass transfer is very important in CO2 absorption, and a rotating zigzag bed (RZB) is a promising device to intensify the gas−liquid mass transfer efficiency. In this study, the mass transfer characteristics in an RZB in relation to the overall gas-phase volumetric mass-transfer coefficient (KGa) were investigated with a CO2−NaOH system. A mathematical model was established to illustrate the mechanism of the gas−liquid mass transfer with irreversible pseudo-first-order reaction in the RZB. The effects of various operating conditions on KGa were examined. Experimental results show that a rise in the liquid flow rate, inlet gas flow rate, rotational speed, absorbent temperature, and absorbent concentration was conducive to the mass transfer between gas and liquid in the RZB. It was found that the rotational speed had the largest impact on KGa in the RZB. The KGa predicted by the model agreed well with that by the experiments, with deviations generally within 10%. There... [more]

The effects of a hydrogen bond acceptor and hydrogen bond donor on carbon dioxide absorption via natural deep eutectic solvents were studied in this work. Naturally occurring non-toxic deep eutectic solvent constituents were considered; choline chloride, b-alanine, and betaine were selected as hydrogen bond acceptors; lactic acid, malic acid, and fructose were selected as hydrogen bond donors. Experimental gas absorption data were collected via experimental methods that uses gravimetric principles. Carbon dioxide capture data for an isolated hydrogen bond donor and hydrogen bond acceptor, as well as natural deep eutectic solvents, were collected. In addition to experimental data, a theoretical study using Density Functional Theory was carried out to analyze the properties of these fluids from the nanoscopic viewpoint and their relationship with the macroscopic behavior of the system, and its ability for carbon dioxide absorption. The combined experimental and theoretical reported appro... [more]

The Effectiveness-Number of Transfer Unit method (ε-NTU method) was applied to determine the overall mass transfer coefficient, KLa, of operating gas-liquid absorbers treating Volatile Organic Compounds (VOCs). This method requires the knowledge of the operating conditions (gas flow rate, QG; liquid flow rate, QL; scrubber volume V), the measurement of gaseous concentrations at the inlet, CGin, and at the outlet, CGout, of the contactor (in order to determine the effectiveness of the absorber ε) and the calculation of the Henry coefficient of the VOC between the gas and the liquid phases (HVOC). Coupled with the “equivalent absorption capacity„ concept, the ε-NTU method was used to determine KLa of absorbers contacting a gas and a mixture of water and a Non Aqueous Phase, successfully. The method, validated from literature data for configurations countercurrent scrubbers and stirred tank reactors, could be used to simply determine the overall mass transfer coefficient of systems for wh... [more]