In order to investigate the difference of pore structure characteristics between mudstone and coal under different particle size conditions, samples acquired from Henan province were smashed and screened into three different particle sizes (20−40, 80−100, and >200 mesh) to conduct the experiments, using the high-pressure mercury intrusion porosimetry (MIP) and low-temperature N2 adsorption (LT-N2A) techniques. The results demonstrated that the proportion of open pores or semi-enclosed pores increased, and the pores became preferable contacted each other for both mudstone and coal during the crushing process. These variations of pore structure characteristics in the coal were beneficial to methane storage and migration. The total specific surface areas and pore volumes all showed a tendency of increasing continually for both mudstone and coal, as the particle sizes decreased from the LT-N2A test. The mudstone and coal were non-rigid aggregates with micropores, plate-shaped pores, and sl... [more]

The simultaneous pyrolysis of coal with wood was experimentally found to allow reducing concentrations of sulfur-containing substances in gases released. The objective of experimental studies is comparison of the sulphate of calcium and aluminum in the ash of coal-wood mixtures after pyrolysis of the latter in a dense “packing” of aggregate particles of these two fuels and at a few millimeters distance between particles. The 3B-grade lignite, T-grade bituminous coal and pinewood sawmill waste were chosen as feedstocks for pyrolysis experiments because they are widespread in Russia as well as many other countries. The elemental composition of all raw materials and pyrolysis residues was determined. The inorganic composition of obtained pyrolysis product in the solid phase was characterized by X-ray analysis. The content of aluminum and calcium sulfate in residue in case of simultaneous processing of coal with wood was found to be higher, compared to the processing of coal only (within t... [more]

Discriminating multiphase methane (adsorbed and free phases) in coals is crucial for evaluating the optimal gas recovery strategies of coalbed methane (CBM) reservoirs. However, the existing volumetric-based adsorption isotherm method only provides the final methane adsorption result, limiting real-time dynamic characterization of multiphase methane in the methane adsorption process. In this study, via self-designed nuclear magnetic resonance (NMR) isotherm adsorption experiments, we present a new method to evaluate the dynamic multiphase methane changes in coals. The results indicate that the T2 distributions of methane in coals involve three different peaks, labeled as P1 (T2 < 8 ms), P2 (T2 = 20−300 ms), and P3 (T2 > 300 ms) peaks, corresponding to the adsorbed phase methane, free phase methane between particles, and free phase methane in the sample cell, respectively. The methane adsorption Langmuir volumes calculated from the conventional volumetric-based method qualitatively agre... [more]

The phenomenon of coking pressure is crucial for cokemaking both in respect of a safe coke oven battery operation and a proper quality of the produced coke. In spite of that, the mechanism of this phenomenon has not been clearly explained yet. The aim of the presented research was to clarify which of the phenomena most commonly mentioned in the literature on the subject, i.e., the reduced gas permeability of the plastic layer or the swelling of plasticized coal grains, is responsible for generating internal coking pressure. To that end, laboratory equipment was developed which enabled examining the pressure generated by the bed of plasticized coal grains under conditions of a varying possibility of its expansion. The results of the examinations suggest that the swelling phenomenon of plasticized coal grains is the direct cause of coking pressure, and the coking pressure strongly depends on the possibility of plastic layer expansion. The results confirm also the migration phenomenon of... [more]

Proximate analysis of coal is of great significance to ensure the safe and economic operation of coal-fired and biomass-fired power generation units. Laser-induced breakdown spectroscopy (LIBS) assisted by chemometric methods could realize the prediction of coal proximate analysis rapidly, which makes up for the shortcomings of the traditional method. In this paper, three quantitative models were proposed to predict the proximate analysis of coal, including principal component regression (PCR), artificial neural networks (ANNs), and principal component analysis coupled with ANN (PCA-ANN). Three model evaluation indicators, such as the coefficient of determination (R2), root-mean-square error of cross-validation (RMSECV), and mean square error (MSE), were applied to measure the accuracy and stability of the models. The most accurate and stable prediction of coal proximate analysis was achieved by PCR, of which the average R2, RMSECV, and MSE values were 0.9944, 0.39%, and 0.21, respecti... [more]

The surface properties of coal, interactions with gaseous and vapour media, and knowledge of the pore structure are important in terms of preparation, use, and utilisation of coal. This publication combines new unpublished data with analyses included in earlier publications by the research team to expand and systematise information on the sorption of water vapour, methanol vapour, and the saturated and unsaturated hydrocarbons hexane, 1-hexene, heptane, 1-heptene, octane on coals of different ranks. The study showed that the affinity of coal for water and methanol is related to the content of oxygen in the coal rather than the rank of the coal. Water sorption is a multilayer phenomenon, while methanol sorption is a monolayer phenomenon. The water monolayer is greater than that of methanol for low-rank coal, but for the higher-rank coals it is the opposite. The sorption capacity of the applied hydrocarbons depends on the presence or absence of a double bond and the size of the molecule.... [more]

The United Nations Framework Convention on Climate Change Paris Agreement has been announced as a crucial step towards combating the global threat of climate change. In the light of ambitious plans for further renewable energy sources development, high demand for nonenergy materials critical for RES is greatly expected. In conclusion, future energy security will be surely based on nonenergy commodities critical for them. As this article directly relates to issues related to new technologies and energy security in new form, the main purpose of this study is to examine the impact of energy commodity prices, namely crude oil, natural gas and coal prices on selected metal prices such as aluminium, chromium, cobalt, copper, lead, nickel, silver, tin, or zinc, both before and over the Paris Agreement period. We are looking for new insights in terms of relationships between traditional fossil fuels and metals used in clean energy technologies potentially established or strengthened shortly af... [more]

Increasing awareness of climate change has induced demand for action most notably. As public demand for action on climate change increases, conversion to energy sources with lower greenhouse gas (GHG) intensity will accelerate. Experience during the COVID-19 pandemic provided insight into how atmospheric conditions will respond to lower GHG emissions. A low-carbon future will require decarbonization of the energy supply mix for electrical production and industrial processes. Coal demand likely will decrease more rapidly than other fossil energy sources, replaced by natural gas and renewable energy sources that have lower GHG intensity and that will be available readily and economically. This decline will accelerate as China focuses on its carbon neutrality goals, the U.S. re-engages in the Paris Agreement, and India moves to a lower carbon future. However, perturbations in the decline will inevitably occur in response to global issues (e.g., pandemic, military conflict). Carbon capture... [more]

The creep and stress relaxation behaviors of coal are common in coal mining. The unified constitutive model is suitable to describe and predict both the creep and relaxation evolution characteristics of rocks. The generalized Kelvin model is the core element for traditional and improved component models to reflect both the nonlinear creep and relaxation. In this paper, an improved core damage model, which could both reflect the creep and stress relaxation in relation to the damage evolution, was established based on a comparison of the traditional and improved component models, and the responding constitutive equations (creep and stress relaxation equation) at constant stress/strain were deduced. Then, the core damage model was validated to the uniaxial compressive multistage creep and stress relaxation test results of coal, showing that the model curves had great accordance with the experimental data. Moreover, the model comparisons on accuracy, parameter meaning, and popularization a... [more]

In the study of coal pore structure, the traditional test method does not consider the influence of coal particle size. During the crushing process, coal samples are affected by crushing stress. While the particle size changes, the change characteristics of pore structure and macromolecular structure are a matter for which systematic research is still lacking. In this paper, mercury injection and liquid nitrogen were used to characterize the pore structure of coal. It was found that the porosity, total pore volume and total specific surface area of the coal increased with the decrease of particle size. However, during this process, the pore volume of macropores and mesopores decreases, while the micropores and transition pores increase significantly, indicating that while the particle size decreases, macropores and mesopores are broken into micropores and transition pores. In addition, the pore structure of samples with a particle size less than 200 mesh changes significantly. With the... [more]

Currently, hydrogen energy is the most promising energy vector, while gasification is one of the major routes for its production. However, gasification suffers from various issues, including slower carbon conversion, poor syngas quality, lower heating value and higher emissions. Multiple factors affect gasification performance, such as the selection of gasifiers, feedstock’s physicochemical properties and operating conditions. In this review, the status of gasification, key gasifier technologies and the effect of solid-fuel (i.e., coal, biomass and MSW) properties on gasification performance are reviewed critically. Based on the current review, the co-gasification of coal, biomass and solid waste, along with a partial utilisation of CO2 as a reactant, are suggested. Furthermore, a technological breakthrough in carbon capture and sequestration is needed to make it industrially viable.

The main purpose of this paper is to develop possible scenarios for reducing carbon dioxide (CO2) emissions in Serbia by switching from coal-fired to natural gas-fired electricity generation by the end of 2050. Accordingly, the challenges are to establish scenarios and identify measures that are best suited to all Western Balkan countries. In particular, this paper proposes a number of energy mix scenarios that offer some options for reducing CO2 emissions while maintaining an economic way of consumption. Projections of these reduction scenarios are obtained by combining the Kaya identity with the emission factor method. A simplified methodology based on sensitivity analysis is used as a source of data to estimate the nonstatistical uncertainty limits for the projections of the reduction scenarios. The sensitivity analysis is carried out using historical data from Serbia for the period from 1990 to 2019. In addition, a direct verification of the proposed methodology is performed based... [more]

Practice shows that CO2/N2-ECBM is an effective technology to enhance coalbed methane. However, there are few field tests in which the technology is applied to enhance the gas drainage in underground coal mines, and the effect is uncertain. In this study, firstly, the reasons for the decrease of gas drainage efficiency in the exhaustion period were analyzed based on the theory of fluid mechanics. Secondly, the mechanism of N2 injection to enhance coal seam gas drainage (N2-ECGD) was discussed: with the gradual decrease of gas pressure in the drainage process, coal seam gas enters a low-pressure state, the driving force of flow is insufficient, and the drainage enters the exhaustion period. The nitrogen injection technology has triple effects of “promoting flow”, “increasing permeability” and “replacing”. Thirdly, the numerical simulations of the nitrogen pressure on drainage effect were carried out based on the fully coupled model. The results show that the higher the nitrogen pressure... [more]

Coal samples having the same diameter (50 mm) and different length-diameter ratios (l/d), i.e., 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, and 1.0 were tested under dynamic uniaxial impact compression using the Split Hopkinson Pressure Bar (SHPB) experimental system. This study evaluates: (a) The effects of l/d on the energy consumption law and fractal characteristics of coal crushing; (b) The effects of l/d and stress balance on energy dissipation; (c) The effects of l/d and energy consumption density on the fractal characteristics of coal crushing. The findings under different l/d are as follows: (1) The coal samples show similar stress−strain curve shapes in stages including elastic, plastic, and failure stage, which is an “open” shape, the proportion of plastic stage increases, and strain-softening occurs; (2) The dynamic compression dissipation energy and energy consumption ratio of coal shows the same trend, showing two stages with the increase of length-diameter ratio, which increases l... [more]

The present work focuses on the quality of char and primary tar produced from fast pyrolysis in N2 and CO2 of lignocellulosic biomasses: walnut shells (lignin-rich), straw (hemicellulose-rich) and pinewood (cellulose-rich). Heat treatments are carried out in a heated strip reactor (HSR) at 1573 and 2073 K for 3 s, with a heating rate of 104 K/s. The equipment allows for quenching the volatiles as soon as they are emitted. Chars are analyzed by thermogravimetric analysis in air. Results are compared with the products obtained from raw lignin, pure cellulose and pure hemicellulose. Cellulose and hemicellulose tars are dominated by anhydrous monosaccharides, which are scarce in straw tar and abundant in walnut shells tar. Polycyclic aromatic hydrocarbons PAHs are present in the primary products, in particular for walnut shells. The most reactive char is the one obtained from straw and the least reactive is the walnut shells char. Severe heat treatment and a CO2 atmosphere generate additio... [more]

Computer-vision-based separation methods for coal gangue face challenges due to the harsh environmental conditions in the mines, leading to the reduction of separation accuracy. So, rather than purely depending on the image features to distinguish the coal gangue, it is meaningful to utilize fixed coal characteristics like density. This study achieves the classification of coal and gangue based on their mass, volume, and weight. A dataset of volume, weight and 3_side images is collected. By using 3_side images of coal gangue, the visual perception value of the volume is extracted (ExM) to represent the volume of the object. A Support Vector Machine (SVM) classifier receives (ExM) and the weight to perform the coal gangue classification. The proposed system eliminates computer vision problems like light intensity, dust, and heterogeneous coal sources. The proposed model was tested with a collected dataset and achieved high recognition accuracy (KNN 100%, Linear SVM 100%, RBF SVM 100%, G... [more]

Although highly developed countries are trying to diversify away from coal-based energy, many economies rely on this resource. Its consumption results in the production of carbon dioxide, which promotes global warming, necessitating its sequestration. This paper presents the sorption−dilatometric relationships of hard coal samples differing in vitrinite and inertinite content. The studies were carried out under isothermal conditions (298 K) at a free pressure drop complemented by measurements under non-isothermal conditions (298 K to 323 K). The tests were performed on an original apparatus, based on the operation of an Arduino microcontroller. For the natural porosity to be preserved and for a better representation of the behaviour of the coal−gas system, samples in the form of cuboidal blocks were used, making this apparatus unique worldwide. Based on the study, it appears that the difference in petrographic composition affects the behaviour of the coal structure, influencing differe... [more]

The pore structure parameters of coal have an important influence on the exploration and development of coalbed methane. In this study, a series of pore structure parameters, including porosity, pore radius, pore throat radius, pore coordination number, pore throat ratio, and specific surface area, are identified, extracted, and calculated in the scanning electron microscopy (SEM) images of coal reservoir samples using algorithms and application programs in MATLAB. Constant rate-controlled mercury injection and low-temperature N2 adsorption experiments were carried out to determine the accuracy of the SEM image-based processing analysis results. Characterization results show that the distribution of pore radius in the target coal samples of different organic matters range from 15 nm to 500 μm with porosity of 1.87−8.31% and radius distribution of 12.7 nm to ~100 μm. A noise-reduction system was constructed to eliminate the optical noise of non-porous features and repair the space affec... [more]

Coal beneficiation processes are often based on gravitational enrichment techniques. Therefore, various types of jigs are often used in this area. A number of factors determine the quality of the final product. Therefore, proper and systematic monitoring of such a process is necessary. The present work examined the effect of the hutch water amount and the amount of processed coal (system capacity) on the yield and ash grade in individual density−size fractions. A statistical method in the form of the Kruskal−Wallis test and the Friedman test was used to evaluate the process. These tests were proposed as universal and reliable alternatives to classical analysis of variance (ANOVA) analysis. The performed analysis allowed for the determination of what process conditions should be selected in order to obtain certain effects. Therefore, it allowed us to apply certain combinations of hutch water amount, system capacity and particle characteristics to maximize the expected effects. The appli... [more]

The influence of high-rank coal’s pore characteristics on the physical properties, gas-bearing properties, and exploitation of coal reservoirs is becoming more and more prominent. How to establish the classification to describe the pore networks combining quantitative and qualitative characteristics has emerged as a major problem, which may offer a scientific foundation to deepen the understanding of this issue. In this research, the structure and fractal characteristics of reservoir pores were determined after analyzing 20 high-rank coal samples from Xinjing Coal Mine in the Qinshui Basin with the application of the high-pressure mercury intrusion method (HPMI) and argon ion polishing−field emission scanning electron microscopy (AIP−FESEM). The results show that the tested coal samples were bipolar distributed, with transitional pores and micropores dominating the pore volume, followed by macropores. The Menger sponge fractal models manifested two or three distinct straight-line segme... [more]

The characteristics of the collisions of droplets with the surfaces of particles and substrates of promising oil−water slurry components (oil, water and coal) were experimentally studied. Particles of coals of different ranks with significantly varying surface wettability were used. The following regimes of droplet−particle collisions were identified: agglomeration, stretching separation and stretching separation with child droplets. The main characteristics of resulting child droplets were calculated. Droplet−particle interaction regime maps in the B = f(We) coordinates were constructed. Equations to describe the boundaries of transitions between the droplet−particle interaction regimes (B = nWe) were obtained. The calculated approximation coefficients make it possible to predict threshold shifts in transition boundaries between the collision regimes for different fuel mixture components. Differences in the characteristics of secondary atomization of droplets interacting with particle... [more]

The low permeability of coal seams has always been the main bottleneck restricting coalbed methane drainage. In this paper, a coal seam anti-reflection technology with solid-propellant blasting was proposed, and the composition and proportion of the solid propellants were determined based on the principle of oxygen balance. The authors designed a solid-propellant blasting damage fracture experiment of simulation coal, tested the impact pressure on a blast hole wall, measured the ultrasonic wave velocity, explosive strain and crack propagation velocity, and then revealed the blasting damage fracture process and mechanism of coal based on the experimental results and damage fracture mechanics theory. The history curve of impact pressure time can be divided into three processes including the slow pressurization process, dramatic increase process, and nonlinear pressure relief process. The pressure distribution along the whole blasting hole was uneven, and the peak pressure was relatively... [more]

The main source of mercury (Hg) anthropogenic emissions is the combustion of hard and lignite coal in power plants. Reduction of Hg emissions from coal-based power production systems involves Hg removal from the fuel before combustion/gasification by thermal treatment (i.e., low-temperature pyrolysis). Herein, we present the results of laboratory and bench-scale studies on Hg removal from coal via thermal fuel treatment. The influence of the process temperature and coal residence time in the reaction zone on Hg removal efficiency and fuel parameters is studied. The properties of the process products are analyzed as follows: proximate and ultimate analysis for solids as well as H2, N2, CO, CO2, CH4, organic compounds C2−C5, density, and HHV for gaseous. The results show a substantial reduction of Hg in the fuel using a low-temperature pyrolysis process. At moderate pyrolysis temperature provided Hg removal efficiencies of up to 50% for hard coal and over 90% for lignite, with a moderate... [more]

The reduction of carbon emissions from the energy industry chain and the coordinated development of the energy supply chain have attracted widespread attention. This paper conducts a systematic review of the existing literature on the energy industry chain and energy supply chain. Based on the analytical results, this paper finds that research gaps exist in the studies of energy consumption structure and resource consumption in energy industry chain. In addition, the studies of coordinated operation mechanisms, risk control and the impact of government policies on the energy supply chain still have some shortcomings. Furthermore, this paper shows that the exploitation and utilization of renewable energy and the sustainable development of the energy industry chain and supply chain have become the major focus of scholars and governments in recent years. Accordingly, this article finally presents the future research prospects and provides managerial insights for policy makers and enterpri... [more]

The most common methods of reducing mercury emissions are the use of fixed bed granular sorbents and sorbent injection. However, both of these methods have disadvantages, such as increasing the flow resistance or the need to remove the sorbent from flue gas, respectively. These disadvantages can be eliminated by using sorbents permanently bound to construction materials (fixed sorbent materials—FSMs) or mixed with construction materials (sorbent polymer composites—SPCs). The approach is unique in the world literature as well as the development of three stands and procedures enabling the testing of FSMs or SPC materials based on Tarflen as a construction material. In order to further tests of FSMs and SPCs, the system for laboratory tests and two systems for industrial tests are developed. These stands and procedures enable determination of the influence of: FSM or SPC module shapes, flue gas properties (e.g., composition, temperature, flow rate), and mercury concentration on the effect... [more]