A series of theoretical and experimental studies was carried out with the aim of a direct comparison of the thermal and microwave destruction of peat during pyrolysis. Different heating mechanisms in these processes were investigated in the framework of simulations conducted using a commercial 3D software package, CST Studio Suite, to define their specific features. Based on these simulations, identical reactors were constructed exploiting an electric element and a microwave complex as a heat source, and an experimental technique was developed that allows these processes to be correctly compared under similar conditions. Using these reactors based on different heat sources, comparative experiments on peat pyrolysis were performed, and the results of the theoretical analysis were confirmed. As a result, the advantages of microwave exposure were demonstrated to achieve a more uniform and deep fragmentation of peat, increase the reaction rate and reduce the processing time, with high ener... [more]

The treatment of chabazite (CHA), a natural zeolite, with the alkaline hydrothermal method to improve its ion-exchange capacity is a widely adopted route by environmental scientists for the purpose of better ammonium (NH4+) removal from wastewater. This work addresses a noteworthy trend in environmental science, where researchers, impressed by the increased ion-exchange capacity achieved through alkaline hydrothermal treatment, often bypass the thorough material characterization of treated CHA. The prevalent misconception attributes the improved features solely to the parent zeolitic framework, neglecting the fact that corrosive treatments like this can induce significant alterations in the framework and those must be identified with correct nomenclature. In this work, alkaline-mediated hydrothermally treated CHA has been characterized through X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), solid-state magic-angle spinning nuclear magnetic resonance (MAS... [more]

FeNi films were prepared using the DC magnetron sputtering technique with an oblique deposition arrangement. Multilayers with different orientations of the magnetic anisotropy axes were obtained thanks to a rotary sample holder inside the vacuum chamber. Magnetic properties were studied using magneto−optical Kerr microscopy and a vibrating sample magnetometer. Single-layered FeNi films having thicknesses as high as 10 nm and 40 nm show in-plane uniaxial easy magnetization axes produced by the oblique incidence of incoming components of the beams. Magnetic anisotropy field for four-layered samples with orthogonal uniaxial magnetic anisotropy axes in the adjacent layers and the thickness of individual layers of 10 nm and 40 nm turned out to be less than in single-layered films. The magnetic properties peculiarities of the eight-layered sample FeNi (10 nm) × 8 obtained by rotation of the sample holder by 45° before deposition of each subsequent layer suggest the formation of a helix-like... [more]

An overview of the composition of wolframite ores of the Akchatau deposit and the technologies for processing concentrates using NaOH and Na2CO3 by hydro- and pyrometallurgical methods is given, and the disadvantages associated with both the technology and the equipment are noted. To develop a technology for processing Akchatau wolframite concentrates, samples of ore materials were taken, the chemical and mineralogical composition of the samples was studied, and enrichment was carried out to obtain rich concentrates. The kinetics of the sintering of the wolframite concentrate with soda was investigated, the dependences of the degree of transformation of the tungsten minerals into sodium tungstate were obtained, and the rate constants, the order of the reaction, and the values of the apparent activation energy were calculated. The results of sintering an enlarged sample of wolframite concentrate with soda in a muffle furnace are presented. After the subsequent leaching, studies were car... [more]

Solid−liquid flows are encountered in various industrial and natural environments. The internal structure of such flows is highly sensitive to the grading of the solid particles present. In this experimental study, an extended stereometric method is employed to assess the distributions of velocity of particles of different fractions, distinguished by different colors, in vertical and nearly horizontal granular flows. In the vertical flow experiments, mixtures comprising three fractions of lightweight particles, characterized by a very similar density, size, and shape, were tested. The results affirmed the method’s ability to discern particle velocity differences on the order of millimeters per second, establishing its suitability for characterizing nearly horizontal open-channel flows with bimodal mixtures that are stratified and exhibit more complex velocity distributions. Tilting flume experiments, incorporating additional measurements of water velocity distribution, allowed for the... [more]

In order to achieve efficient photocatalytic N2 reduction activity for ammonia synthesis, a photochemical strategy was used in this work. UiO-66 was prepared through the solvothermal method and further loaded with Au nanoparticles (Au NPs) onto the UiO-66 (Zr) framework. The experimental results verified that there were metal−support interactions between Au NPs and UiO-66; this could facilitate charge transfer among Au NPs and UiO-66, which was beneficial to enhance the photocatalytic activity. The best N2 fixation effect of Au/UiO-66 with a loading of 1.5 wt% was tested, with a photocatalytic yield of ammonia of 66.28 μmol g−1 h−1 while maintaining good stability. The present work provides a novel approach to enhancing photocatalytic N2 fixation activity by loading NPs onto UiO-66.

Corrosion fatigue test is the most direct and effective method to study the corrosion fatigue characteristics of sucker rod. At present, the commonly used test method is the high frequency fatigue test, but the working state of sucker rod is typical low-frequency and high-cycle corrosion fatigue, and the test with high frequency will reduce the impact of corrosion. Alloy steel 4330 is widely used in coalbed gas well high strength sucker rod, but the research on its low frequency corrosion fatigue life is relatively few. Therefore, in this paper, the corrosion fatigue test method of axial low-frequency and high-cycle was adopted to study the corrosion fatigue characteristics of 4330 steel sucker rod through the corrosion fatigue test under different typical corrosion media, temperature, and stress levels. The results show that the fatigue life of 4330 sucker rod drops sharply when the Cl− concentration in high salinity well fluid exceeds the threshold value of 155 mg/L. When this thresh... [more]

The soil-water retention curve (SWRC) is fundamental in presenting the hydromechanical characteristics of soils, which are closely connected with soil deformation, permeability, and shear strength. The Fredlund and Xing (FX) model accurately fits the SWRCs of different types of soils over a wide suction range. However, experimental comparisons of the fitting showed that the obtained parameters differ from the physical meanings assigned by Fredlund and Xing. To address this issue, the traditional FX model has been improved, resulting in the proposal of a two-step FX model. Firstly, the FX model is applied without taking the correction coefficient c(ψ) into account to fit the measured SWRC. The values for α, n, and m are then determined and substituted into the FX model to refit the experimental data. Finally, the last parameter Cr can be obtained. The curves resulting from these two steps have a good agreement with the experimental results, and the obtained parameters align better with... [more]

Improving the hydrophilicity and mechanical strength of membranes in water treatment applications remains challenging. In this study, modified vermiculite (VT-M) and a hydrophilic polyvinylpyrrolidone (PVP) were introduced into a polyethyleneimine-functionalized polyvinylidene fluoride composite membrane (PVDF/PEI) to prepare a comprehensively modified mixed-matrix PVDF composite membrane adsorbent that exhibited high mechanical strength and excellent hydrophilicity. The modified composite membrane featured good tensile properties, with a maximum tensile strength of 2.093 MPa, which was 2.5 times that of the PVDF/PEI membrane. After 7 s, the water contact angle of the composite membrane decreased to 0°, leading to significantly improved hydrophilicity. The modified composite membrane exhibited excellent adsorption selectivity for mercury ions, with a fitted maximum adsorption capacity of 807 mg/g. In a mixed-metal ion solution, the selectivity of the membrane for Hg(II) ions was 1.2 ×... [more]

It is known that highly efficient catalysts for the catalytic oxidation of aromatic hydrocarbons can be obtained based on magnetic nanoparticles. The development of nanosized magnetically controlled catalysts for the oxidation of aromatic hydrocarbons with oxygen deserves especially close attention in the territory of the Republic of Kazakhstan, which does not have its own industrial production of oxygen-containing compounds. The aim of this work is to create catalysts based on Fe and Co nanoparticles stabilized with polymers: polyvinylpyrrolidone, chitosan, and polyethylenimine, study them by methods of physico-chemical research, and conduct preliminary tests of catalysts to predict their effectiveness. Magnetic nanoparticles were prepared by the co-precipitation method. Based on the results of the SEM analysis, it was concluded that polymers form composites together with metal nanocrystals. According to preliminary data, the most efficient oxidation of phenol in a non-flowing glass g... [more]

In geopolymer bricks (GPBs), fly ash content, which is waste from power plants, is converted into bricks by chemical treatment. GPBs can be dried by using appropriate curing methods. Conventionally, electric oven curing is one of the prominent methods. Using a solar dryer instead of an electric oven provides the added advantage of saving high-grade electrical energy. So, in this work, a solar dryer with the phase change material (PCM) paraffin wax and without a PCM is used for curing applications. GPBs gain an added advantage when compared to conventional bricks like cement and sand bricks in terms of strength. A GPB has been taken as a specimen for comparing the compressive strength, tensile split strength, and flexural strength of electrical-energy-based curing and solar-energy-based curing. It has been experimentally observed that solar-energy-based curing with and without a PCM exhibits higher compressive strength, higher tensile split strength, and flexural strength when compared... [more]

Xylose is nowadays converted into xylitol, a popular special chemical sweetener. Xylitol can be used not only in the pharmaceutical and food industries, but also in cosmetics and synthetic resins because of its countless properties. Conventionally, xylitol is produced by slurry reactors operating in batch with dispersed or supported catalysts. Hydrogen is continuously fed to maintain a constant pressure. In this work, the kinetics of the reaction were investigated to find the optimal operating conditions to minimize the by-products obtained. Given the great performances shown by the new Ru/SiO2 sol−gel derived catalyst in glucose hydrogenation, in this work the mentioned catalyst was tested in the hydrogenation of xylose to xylitol both in batch and in continuous production to prove its stability and activity.

This paper presents a detailed analysis of the relation between physical characteristics and defects of green coffee beans and the sensory profile that influence the sensory notes of fragrance, aroma, flavor, and aftertaste of coffee. Machine learning models were used to identify the variables of importance and identify the ways in which these variables affect the sensory note of coffee, to determine which algorithm and its hyperparameters have greater precision in determining the sensory values of coffee such as floral, fruity, herbal, nutty, caramel, chocolate, spicy, resinous, pyrolytic, earthy, fermented, and phenolic. The result indicates the relationship and importance that exist between the physical variables, defects, and size of the green coffee bean, with respect to their respective sensory notes. The data of the proposed system demonstrate that by combining the scores of several experts, a precision can be achieved analogously to that obtained by cupping experts; therefore,... [more]

The well productivity of high-waxy reservoirs is highly influenced by temperature changes. A decrease in temperature can cause the precipitation of wax from the crude oil, leading to a decrease in the formation’s drainage capacity and a drop in oil production. In this study, the wax precipitation of crude oil is characterized by rheological properties tests and differential scanning calorimetry (DSC) thermal analysis. The wax damage characteristics of cores and the relative permeability curves at different temperatures were investigated through coreflood experiments. Furthermore, nanoemulsion is selected as a chemical agent for injection fluid. The nuclear magnetic resonance (NMR) scanning technique is used to investigate the effects of oil recovery enhancement at different pores by increasing temperature and adding nanoemulsion. By comparing the changes in T2 spectra and the distribution pattern of residual oil before and after liquid injection, the results have shown that both increa... [more]

Granite residual soil typically forms complex pore structures and exhibits high water sensitivity due to physical and chemical weathering processes. Changes in initial compaction conditions significantly affect the mechanical and hydraulic properties of in situ granite residual soil subgrades, with these variations fundamentally related to changes in pore structure and soil−water characteristics. This study investigates the pore structure and bimodal soil−water characteristic curve (SWCC) of a compacted granite residual soil through laboratory tests and mercury intrusion porosimetry tests. Nine initial conditions were selected based on potential in situ compaction conditions of subgrades, and their effects on the pore size distribution (PSD) and SWCC were thoroughly analyzed. The results show strong correlations between bimodal pore structure and SWCC. The size and volume of inter-aggregate pores exhibit noticeable changes with initial conditions, affecting SWCC within the low and midd... [more]

The cement strength between the cement and the formation is a key factor in determining the cementation sealing capacity. In the shale formation, due to the organic matter content, the cementing quality between the formation and the cement ring is poor, which affects the quality of cementing. It is easy to cause problems such as annulus pressure. To improve the quality of cementing, this paper investigates the effect of amino silane coupling agents, vinyl silane coupling agents and aluminium−zirconate coupling agents on the interface cementation of rock and cement under different conditions. Meanwhile, the effects of different coupling agent compounding on improving the cementation interface cement strength under different temperature and concentration conditions were investigated. This led to the development of a composite interface enhancer. The composite interface enhancer can improve the bond strength between cement and rock by 189.22%. A preflush fluid system was developed to effe... [more]

Vehicle fuel leaks can adversely affect the performance of asphalt pavements. To study the mechanisms of fuel corrosion damage in asphalt, four asphalt binders were selected in this study, and the evolution of their rheological and microscopic properties was investigated. Fuel corrosion caused continuous mass loss in asphalt binders. Base asphalt lost more than 50% of its mass after 24 h of fuel corrosion, while modified asphalts had better resistance. According to dynamic shear rheometer tests and multiple stress creep recovery tests, modifiers improved the high-temperature rheological properties of these asphalt binders. As the degree of fuel corrosion deepened, the indexes characterizing the high-temperature performance deteriorated. Rubber-modified asphalt showed the best resistance to high-temperature deformation, while the performance of LDPE-modified asphalt was more stable. In contrast, fuel corrosion improved the resistance of asphalt binders to low-temperature cracking to som... [more]

A generalized Padé-type expression is proposed for Henry’s constant of gases in ionic liquids. The constants are determined using an equation of state, and generalized expressions for the Henry’s constants of the gases in the ionic liquids are proposed. The solute gases included in the study were oxygen, hydrogen, and carbon monoxide in three solvent ionic liquids ([MDEA][Cl], [Bmim][PF6], and [Hmim][TF2N]). The Valderrama−Patel−Teja equation of state with the mixing rules of Kwak and Mansoori are employed to correlate the solubility data, to examine the thermodynamic consistency of the experimental data, and to determine the fugacity (fi) for each concentration (xi) of the solute gas in the liquid phase. From these data, the fugacity coefficients (fiL/xi) are determined to obtain Henry´s constant as Hi = lim(fiL/xi) when xi→0. The calculated Henry’s constants are correlated in terms of the temperature and acentric factor of the gases to finally obtain a generalized expression for Henr... [more]

In this research, hydrofluoric acid (HF) was used as a leaching agent to remove silicon impurities from titanium dioxide powder regenerated from a spent SCR catalyst. Further, the effects of HF concentration, liquid−solid ratio, leaching temperature, and leaching time on the leaching rate of regenerated titanium dioxide powder were investigated. The results revealed that the leaching rate of silicon in alkali-leached samples could reach 99.47% under the following conditions: 4% HF concentration, a leaching temperature of 50 °C, and a liquid−solid ratio of 5:1. When compared under identical experimental conditions, the silicon leaching rate in the alkali leached sample using HF surpassed that of the spent SCR catalyst. This suggests that high-temperature alkali leaching led to the degradation of the catalyst and the glass fiber within it, rendering this process more favorable for silicon leaching.

In this study, the thermal transition of seaweed Saccharina latissima (raw and blanched) during drying and quality stabilization was considered in view of understanding physico-chemical changes, color changes, sorption changes and thermal property changes with respect to drying kinetics. The variations in the effective moisture diffusivity coefficient with shrinkage changes and temperature lie between 1.0 and 5.0 × 10−10 m2 s−1 (raw) and 0.5 and 3.6 × 10−10 m2 s−1 (blanched), respectively. Noticeable physical and chemical changes were observed during longer drying times, especially in the case of blanched seaweeds. At the temperature of 38.0 °C, a more yellow-colored product was obtained from raw form input materials. The blanched seaweeds accumulated moisture in a linear manner with an increase in the relative humidity of the drying air in the range of 20.0~80.0%, which resulted in high level of hysteresis between the sorption and desorption behavior. Shrinkage changes during the dryi... [more]

Pool boiling heat transfer is recognized as an exceptionally effective method, widely applied across various industries. The adoption of non-azeotropic binary mixtures aligns with the environmental objectives of modern industrial development and enhances the coefficient of performance (COP) in numerous systems. Therefore, investigating the boiling heat transfer characteristics of these mixtures is crucial to improving their industrial usability. In this study, mixtures of ethylene glycol and deionized water (EG/DW) in varying concentrations were chosen as the working fluids. A comprehensive experimental setup was developed, followed by a series of experiments to assess their pool boiling performance. Simultaneously, the thermophysical parameters of these mixtures underwent detailed examination and analysis. The research revealed that the concentration of EG in the mixture markedly affects its thermal properties and temperature glide, both of which are crucial in influencing the heat tr... [more]

In catalysis, the design and application of supported nanoparticle catalysts is a cornerstone for addressing contemporary challenges in environmental remediation, sustainable synthesis, and analytical methodologies [...]

Conventional fluid loss additives have difficultly controlling the water loss of cement−metakaolin slurry with semi-saturated brine cement slurry and limiting it to less than 50 mL (30 min)−1. This paper describes the development of an anti-salt fluid loss additive for metakaolin−cement systems. This study adopted the aqueous solution polymerization method; selected four kinds of monomers, namely 2-Acrylamido-2-methylpropane sulfonic acid (AMPS), N,N-Dimethylacrylamide (DMAA), acrylamide (AM), and methyl acrylate (MA); and performed a single-factor experiment on the proportion of monomer, reaction temperature, initiator dosage, and developed fluid loss additive, which has a high salt tolerance and temperature tolerance. This fluid loss additive can resist salt until saturation, and it can control fluid loss in 24 mL·(30 min)−1 when its dosage is 2%. The fluid loss additive can achieve the effect of fluid loss reduction by increasing the filtrate viscosity, forming a flexible elastic ad... [more]

Nonwoven fabrics with appropriate hydrophilicity and potent antimicrobial properties hold important promise for hygiene applications. However, existing materials with certain limitations and complex manufacturing steps, along with the unavoidable use of chemicals in the process, are limited to a certain extent in terms of the balance between comfort and antimicrobial properties. In this paper, a polyimide (PI) fiber was reported to be used for the preparation of PI composite nonwoven fabrics (5-P), which can effectively enhance the surface hydrodynamic and antimicrobial properties of the nonwoven by a one-step plasma treatment on one side. After treatment, the one-sided water contact angle (WCA) changed from 121.5° to 68.5°, and the permeation volume from 0.7 to 2.1 g, with a relative increase of 181.9%. Meanwhile, the reverse osmosis amount was only 0.5 g, achieving rapid permeation while keeping a low reverse osmosis amount. The antimicrobial experiment showed that plasma-treated 5-P... [more]

The focus of this review article is to present a retrospective analysis of copper applications focusing on ions and nanoparticles as broad-spectrum antimicrobials. Copper nanoparticles are presented as an alternative to rising antibiotic resistance. The basic mechanisms of bacterial, fungal, and viral inactivation, which explain their potential, are presented. The green biosynthesis of copper nanoparticles using biomaterials is also presented and considered a very promising trend for future biotechnology and medical applications.