LAPSE:2023.2437
Published Article

LAPSE:2023.2437
Predicting Mass Transfer in Liquid−Liquid Extraction Columns
February 21, 2023
Abstract
In this work, the GEneralised Multifluid Modelling Approach (GEMMA) is applied to the simulation of liquid−liquid extraction in a Rotating Disc Column (RDC) and a Pulsed Sieve-plate Extraction Column (PSEC). A mass transfer modelling methodology is developed, in which the multiphase flows, droplet size distribution and dispersed phase holdup predicted with computational fluid dynamics are coupled to mass transfer correlations to predict the overall mass transfer. The numerical results for the stage-averaged dispersed phase holdup, Sauter mean droplet diameter and axial solute concentration in the RDC and PSEC agree with experimental observations. The proposed modelling method provides an accurate predictive tool for complex multiphase flows, such as those observed in intensified liquid−liquid extraction, and provides an alternative approach to column design using empirical correlations or pilot plant study.
In this work, the GEneralised Multifluid Modelling Approach (GEMMA) is applied to the simulation of liquid−liquid extraction in a Rotating Disc Column (RDC) and a Pulsed Sieve-plate Extraction Column (PSEC). A mass transfer modelling methodology is developed, in which the multiphase flows, droplet size distribution and dispersed phase holdup predicted with computational fluid dynamics are coupled to mass transfer correlations to predict the overall mass transfer. The numerical results for the stage-averaged dispersed phase holdup, Sauter mean droplet diameter and axial solute concentration in the RDC and PSEC agree with experimental observations. The proposed modelling method provides an accurate predictive tool for complex multiphase flows, such as those observed in intensified liquid−liquid extraction, and provides an alternative approach to column design using empirical correlations or pilot plant study.
Record ID
Keywords
Computational Fluid Dynamics, droplet population balance, liquid–liquid extraction, mass transfer, multiphase flows, pulsed column, pulsed sieve-plate extraction column, rotating disc column, solvent extraction
Subject
Suggested Citation
Fells A, De Santis A, Colombo M, Theobald DW, Fairweather M, Muller F, Hanson B. Predicting Mass Transfer in Liquid−Liquid Extraction Columns. (2023). LAPSE:2023.2437
Author Affiliations
Fells A: School of Chemical and Process Engineering, University of Leeds, Leeds LS2 9JT, UK [ORCID]
De Santis A: School of Chemical and Process Engineering, University of Leeds, Leeds LS2 9JT, UK
Colombo M: Department of Mechanical Engineering, University of Sheffield, Sir Frederick Mappin Building, Mappin Street, Sheffield S1 3JD, UK [ORCID]
Theobald DW: School of Chemical and Process Engineering, University of Leeds, Leeds LS2 9JT, UK
Fairweather M: School of Chemical and Process Engineering, University of Leeds, Leeds LS2 9JT, UK
Muller F: School of Chemical and Process Engineering, University of Leeds, Leeds LS2 9JT, UK
Hanson B: School of Chemical and Process Engineering, University of Leeds, Leeds LS2 9JT, UK
De Santis A: School of Chemical and Process Engineering, University of Leeds, Leeds LS2 9JT, UK
Colombo M: Department of Mechanical Engineering, University of Sheffield, Sir Frederick Mappin Building, Mappin Street, Sheffield S1 3JD, UK [ORCID]
Theobald DW: School of Chemical and Process Engineering, University of Leeds, Leeds LS2 9JT, UK
Fairweather M: School of Chemical and Process Engineering, University of Leeds, Leeds LS2 9JT, UK
Muller F: School of Chemical and Process Engineering, University of Leeds, Leeds LS2 9JT, UK
Hanson B: School of Chemical and Process Engineering, University of Leeds, Leeds LS2 9JT, UK
Journal Name
Processes
Volume
10
Issue
5
First Page
968
Year
2022
Publication Date
2022-05-12
ISSN
2227-9717
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Original Submission
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PII: pr10050968, Publication Type: Journal Article
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LAPSE:2023.2437
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https://doi.org/10.3390/pr10050968
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Feb 21, 2023
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