LAPSE:2023.6511v1
Published Article

LAPSE:2023.6511v1
Organic Waste Gasification by Ultra-Superheated Steam
February 23, 2023
Abstract
The perspective of the emerging environmentally friendly and economically efficient detonation gun technology for the high-temperature gasification of organic wastes with ultra-superheated mixture of steam and carbon dioxide is discussed. The technology is readily scalable and allows the establishment of a highly reactive atmospheric-pressure environment in a compact water-cooled gasifier due to very high local temperature (above 2000 °C), intense in situ shock-induced fragmentation of feedstock, and high-speed vortical convective flows enhancing interphase exchange processes. These unique and distinctive features of the technology can potentially provide the complete conversion of solid and liquid wastes into syngas, consisting exclusively of hydrogen and carbon monoxide; microparticles, consisting of environmentally safe simple oxides and salts of mineral residues, as well as aqueous solutions of oxygen-free acids such as HCl, HF, H2S, etc., and ammonia NH3. A small part of the syngas product (ideally approximately 10%) can be used for replacing a starting fuel (e.g., natural gas) for the production of a detonation-born gasifying agent, while the rest can be utilized for the production of electricity, heat, and/or chemicals.
The perspective of the emerging environmentally friendly and economically efficient detonation gun technology for the high-temperature gasification of organic wastes with ultra-superheated mixture of steam and carbon dioxide is discussed. The technology is readily scalable and allows the establishment of a highly reactive atmospheric-pressure environment in a compact water-cooled gasifier due to very high local temperature (above 2000 °C), intense in situ shock-induced fragmentation of feedstock, and high-speed vortical convective flows enhancing interphase exchange processes. These unique and distinctive features of the technology can potentially provide the complete conversion of solid and liquid wastes into syngas, consisting exclusively of hydrogen and carbon monoxide; microparticles, consisting of environmentally safe simple oxides and salts of mineral residues, as well as aqueous solutions of oxygen-free acids such as HCl, HF, H2S, etc., and ammonia NH3. A small part of the syngas product (ideally approximately 10%) can be used for replacing a starting fuel (e.g., natural gas) for the production of a detonation-born gasifying agent, while the rest can be utilized for the production of electricity, heat, and/or chemicals.
Record ID
Keywords
Carbon Dioxide, detonation, gasification, organic waste, Syngas, ultra-superheated steam
Subject
Suggested Citation
Frolov SM. Organic Waste Gasification by Ultra-Superheated Steam. (2023). LAPSE:2023.6511v1
Author Affiliations
Frolov SM: Department of Combustion and Explosion, Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, Moscow 119991, Russia [ORCID]
Journal Name
Energies
Volume
16
Issue
1
First Page
219
Year
2022
Publication Date
2022-12-25
ISSN
1996-1073
Version Comments
Original Submission
Other Meta
PII: en16010219, Publication Type: Journal Article
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LAPSE:2023.6511v1
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https://doi.org/10.3390/en16010219
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Feb 23, 2023
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