LAPSE:2023.34865
Published Article
LAPSE:2023.34865
Preparation of an Anodic Alumina-Supported Ni Catalyst and Development of a Catalytic Plate Reformer for the Steam Reforming of Methane
Shan Dong, Yi Lin, Jiajun Hu, Chenglin Gu, Leilin Ding, Xinjian Zhang, Shi Jiang, Yu Guo
April 28, 2023
A plate-type Al/Fe−Cr alloy/Al-clad substrate was used to prepare a sandwich-structured plate-type anodic alumina catalyst by anodization, post-modification treatment, and metal loading. The as-prepared plate-type catalyst was utilized in the design of a catalytic plate reactor for a methane steam reforming reaction, and a 3D model was developed to simulate the performance of tube-type and box-type reformers. The experimental results of the preparation of the clad materials showed that the hydrothermal treatment and subsequent high-temperature calcination transformed the amorphous skeletal alumina in the conventional anodic alumina layer into γ-alumina, and significantly increased its specific surface area. Simulation results showed that the temperature difference between the channel wall and the center of the gas phase of the thin-walled catalyst was only 30% of that of the particulate catalyst, indicating the potential advantages of the catalytic plate reactor in terms of heat transfer and energy saving. When the length-to-diameter ratio (or length-to-width ratio) of the reaction channel is small and the channel height is large, insufficient transverse mass transfer and backmixing are two major factors affecting reformer performance. For the tube-type channels, a length-to-diameter ratio of 10~35, and a diameter of 5~20 represent favorable choices. In contrast, for the box-type channel, the length-to-width ratio and the height should be set to 2~4 and 2~5 mm, respectively. Additionally, for box-type channels, the number of gas inlet ports has a significant effect on the reformer performance, and the distribution state provided by two inlet ports is close to the ideal distribution state.
Keywords
3D model, anodic alumina, backmixing, Simulation, steam reforming of methane
Suggested Citation
Dong S, Lin Y, Hu J, Gu C, Ding L, Zhang X, Jiang S, Guo Y. Preparation of an Anodic Alumina-Supported Ni Catalyst and Development of a Catalytic Plate Reformer for the Steam Reforming of Methane. (2023). LAPSE:2023.34865
Author Affiliations
Dong S: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, 30 Puzhunan Road, Nanjing 211816, China
Lin Y: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, 30 Puzhunan Road, Nanjing 211816, China
Hu J: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, 30 Puzhunan Road, Nanjing 211816, China
Gu C: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, 30 Puzhunan Road, Nanjing 211816, China
Ding L: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, 30 Puzhunan Road, Nanjing 211816, China
Zhang X: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, 30 Puzhunan Road, Nanjing 211816, China
Jiang S: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, 30 Puzhunan Road, Nanjing 211816, China
Guo Y: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, 30 Puzhunan Road, Nanjing 211816, China
Journal Name
Energies
Volume
16
Issue
8
First Page
3426
Year
2023
Publication Date
2023-04-13
Published Version
ISSN
1996-1073
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PII: en16083426, Publication Type: Journal Article
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doi:10.3390/en16083426
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