LAPSE:2023.34310
Published Article
LAPSE:2023.34310
Modelling Carbon Corrosion during a PEMFC Startup: Simulation of Mitigation Strategies
Bolahaga Randrianarizafy, Pascal Schott, Mathias Gerard, Yann Bultel
April 25, 2023
This paper presents a study of the carbon support corrosion and mitigation strategies through the use of a pseudo-3D model. This model consists in coupling a 2D model along the channel with another model perpendicular to the flow at the rib/channel scale. Simulations offer a deeper understanding of the corrosion through the analysis of the local conditions. Rib/channel heterogeneities show the higher degradation in the zones facing the anodic rib. These results are validated qualitatively on literature data by analysis of SEM images and carbon dioxide concentration at the cathode outlet. Three mitigation strategies are studied using the model. The first one consists in speeding up the hydrogen filling of the cell. The second strategy involves an external electrical resistance to create a current leak during the startup. Third, a design study of the rib/channel is performed to minimize the cathode degradation. Whatever the mitigation strategy, it consists in reducing either the duration or the magnitude of the high cathode electrode potential.
Keywords
carbon corrosion, mitigation strategies, Modelling, multiphysics simulations, PEM fuel cell
Suggested Citation
Randrianarizafy B, Schott P, Gerard M, Bultel Y. Modelling Carbon Corrosion during a PEMFC Startup: Simulation of Mitigation Strategies. (2023). LAPSE:2023.34310
Author Affiliations
Randrianarizafy B: LITEN, CEA, Univ. Grenoble Alpes, F-38054 Grenoble, France
Schott P: LITEN, CEA, Univ. Grenoble Alpes, F-38054 Grenoble, France
Gerard M: LITEN, CEA, Univ. Grenoble Alpes, F-38054 Grenoble, France
Bultel Y: LEPMI, Grenoble INP, CNRS, Univ. Savoie Mont Blanc, F-38000 Grenoble, France
Journal Name
Energies
Volume
13
Issue
9
Article Number
E2338
Year
2020
Publication Date
2020-05-08
Published Version
ISSN
1996-1073
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Original Submission
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PII: en13092338, Publication Type: Journal Article
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doi:10.3390/en13092338
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Apr 25, 2023
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