The paper presents the methods of determination of the actual operation of solid fuel heating boilers in Poland. The analysis was based on an average annual distribution of the actual power outputs of the solid fuel heating boilers operated in four selected locations in Poland. Based on said data, three characteristic percent shares have been estimated of the nominal power outputs, at which the heating boilers in Poland operate throughout the year (divided into four characteristic portions—the seasons of the year). Additionally, for the analysis, the authors took into account the average annual temperature amplitude and the annual air quality information for the discussed locations and analyzed 30 solid fuel heating boilers in terms of their performance in the laboratory certification tests. In the final stage of the investigations, the authors initiated laboratory tests on the application of the combustion quality analyzers and their potential benefits.