Abstract
To realize a carbon negative power production technology, it is interesting the option of coupling a Chemical Loping Combustor to a gas turbine. The development of this technology foreseen in the project GTCLC-NEG has some technical barriers, the most important of which is the operation of the chemical looping combustor at high temperature and high pressure conditions. To overcome these limits CFD modeling can be performed to optimize the behavior of the combustor and its design process. This work models the FUEL reactor of a chemical looping combustion plant working in batch mode and based on the reactor available at the Instituto de Carboquimica in Zaragoza, Spain. It is used an oxygen carrier mainly based on 60% mass Fe2O3 and 40% mass Al2O3. Biomethane is fed to the bottom of the fluidized bed with different velocities and mass flows and the composition of the gases at the outlet of the fuel reactor is measured. The results show that it is possible to model a 2 min duration reduction cycle by running the model for a time comprised between a minimum of 4 h and a maximum of 2 days of simulation. Another important result is the modeling of the chemical reactions happening in the reactor. Kinetics is modelled based on Activation energy (66 kJ/mol) and Pre-exponential factor (4.34 × 101 m3n mol−n s−1). The simple kinetic scheme gives reasonable first approximations and can be used to determine the duration of the reaction, the composition of the exhaust gases and the biofuel conversion.