LAPSE:2023.1716v1
Published Article

LAPSE:2023.1716v1
Impact of Hydrogen Liquefaction on Hydrogen Fuel Quality for Transport Applications (ISO-14687:2019)
February 21, 2023
Abstract
Decarbonisation of the energy sector is becoming increasingly more important to the reduction in climate change. Renewable energy is an effective means of reducing CO2 emissions, but the fluctuation in demand and production of energy is a limiting factor. Liquid hydrogen allows for long-term storage of energy. Hydrogen quality is important for the safety and efficiency of the end user. Furthermore, the quality of the hydrogen gas after liquefaction has not yet been reported. The purity of hydrogen after liquefaction was assessed against the specification of Hydrogen grade D in the ISO-14687:2019 by analysing samples taken at different locations throughout production. Sampling was carried out directly in gas cylinders, and purity was assessed using multiple analytical methods. The results indicate that the hydrogen gas produced from liquefaction is of a higher purity than the starting gas, with all impurities below the threshold values set in ISO-14687:2019. The amount fraction of water measured in the hydrogen sample increased with repeated sampling from the liquid hydrogen tank, suggesting that the sampling system used was affected by low temperatures (−253 °C). These data demonstrate for the first time the impact of liquefaction on hydrogen purity assessed against ISO-14687:2019, showing that liquified hydrogen is a viable option for long-term energy storage whilst also improving quality.
Decarbonisation of the energy sector is becoming increasingly more important to the reduction in climate change. Renewable energy is an effective means of reducing CO2 emissions, but the fluctuation in demand and production of energy is a limiting factor. Liquid hydrogen allows for long-term storage of energy. Hydrogen quality is important for the safety and efficiency of the end user. Furthermore, the quality of the hydrogen gas after liquefaction has not yet been reported. The purity of hydrogen after liquefaction was assessed against the specification of Hydrogen grade D in the ISO-14687:2019 by analysing samples taken at different locations throughout production. Sampling was carried out directly in gas cylinders, and purity was assessed using multiple analytical methods. The results indicate that the hydrogen gas produced from liquefaction is of a higher purity than the starting gas, with all impurities below the threshold values set in ISO-14687:2019. The amount fraction of water measured in the hydrogen sample increased with repeated sampling from the liquid hydrogen tank, suggesting that the sampling system used was affected by low temperatures (−253 °C). These data demonstrate for the first time the impact of liquefaction on hydrogen purity assessed against ISO-14687:2019, showing that liquified hydrogen is a viable option for long-term energy storage whilst also improving quality.
Record ID
Keywords
Energy Storage, ISO-14687:2019, liquified hydrogen
Subject
Suggested Citation
Hookham MJF, Le Gendre E, Coulpier C, Carré M, Morris ASO, Moore N, Hristova Y, Bacquart T. Impact of Hydrogen Liquefaction on Hydrogen Fuel Quality for Transport Applications (ISO-14687:2019). (2023). LAPSE:2023.1716v1
Author Affiliations
Hookham MJF: National Physical Laboratory, Teddington, London TW11 0LW, UK [ORCID]
Le Gendre E: Air Liquide Innovation Campus Paris, 78350 Paris, France
Coulpier C: Air Liquide Innovation Campus Paris, 78350 Paris, France [ORCID]
Carré M: Air Liquide Innovation Campus Paris, 78350 Paris, France
Morris ASO: National Physical Laboratory, Teddington, London TW11 0LW, UK
Moore N: National Physical Laboratory, Teddington, London TW11 0LW, UK
Hristova Y: National Physical Laboratory, Teddington, London TW11 0LW, UK
Bacquart T: National Physical Laboratory, Teddington, London TW11 0LW, UK [ORCID]
Le Gendre E: Air Liquide Innovation Campus Paris, 78350 Paris, France
Coulpier C: Air Liquide Innovation Campus Paris, 78350 Paris, France [ORCID]
Carré M: Air Liquide Innovation Campus Paris, 78350 Paris, France
Morris ASO: National Physical Laboratory, Teddington, London TW11 0LW, UK
Moore N: National Physical Laboratory, Teddington, London TW11 0LW, UK
Hristova Y: National Physical Laboratory, Teddington, London TW11 0LW, UK
Bacquart T: National Physical Laboratory, Teddington, London TW11 0LW, UK [ORCID]
Journal Name
Processes
Volume
10
Issue
9
First Page
1697
Year
2022
Publication Date
2022-08-26
ISSN
2227-9717
Version Comments
Original Submission
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PII: pr10091697, Publication Type: Journal Article
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LAPSE:2023.1716v1
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https://doi.org/10.3390/pr10091697
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Feb 21, 2023
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