Abstract
The COD reduction in gas to liquid (GTL) process water was optimized using response surface methodology (RSM). The biodegradation process was carried out in a spouted bed bioreactor (SBBR) using Pseudomonas aeruginosa immobilized in polyvinyl alcohol (PVA) gel. Different factors affecting the biological treatment of GTL process water (PW) were investigated. Three variables including PVA volume fraction, initial COD, and pH were investigated in the batch experiments. The biodegradation experiments were carried out by varying the initial COD values from 1000 to 3000 mg/L, pH from 5 to 8, and PVA v% from 20 to 30%. The maximum COD reduction was estimated to occur at an initial COD of 2595 mg/L, PVA v% of 27%, and pH of 7.3. At optimum conditions, the bioreactor system was able to achieve a maximum COD reduction of 89%, which is quite close to the RSM prediction value of 90%. The optimum operating conditions were used to carry out continuous biodegradation, and the results indicated that the COD reduction increased from 60% to 62% with an increase in the air flow rate from 2 to 3.3 La/Lr.min. However, by increasing the liquid flow rate from 2.1 to 4.2 mL/min and back to 2.1 mL/min, the COD reduction decreased from 66% to 39%. The system responded quickly to the change in liquid flow rate and returned to the initial COD level. This indicates that the system is highly stable and can easily recover.