LAPSE:2023.9256
Published Article

LAPSE:2023.9256
Tri-Reforming of Methane: Thermodynamics, Operating Conditions, Reactor Technology and Efficiency Evaluation—A Review
February 27, 2023
Abstract
The production of syngas with optimal energy usage, a minimal environmental impact, and an adjustable H2/CO molar ratio is possible using tri-reforming of methane (TRM). Despite the number of studies dedicated to the TRM process, this process is still in its infancy, with many technical obstacles to overcome. Except for its kinetics and catalysts, which have been reviewed elsewhere, the TRM process is evaluated thoroughly in this work. First, feasibility studies of TRM and the TRM process are presented. Second, the impacts of various operating conditions on the rate of gas conversions, syngas production, and coke formation are discussed. Third, different reactor configurations are compared. This review then goes through the energy and energetic efficiency, economic, environmental, and safety aspects of the TRM process. Finally, a research path for the future is suggested.
The production of syngas with optimal energy usage, a minimal environmental impact, and an adjustable H2/CO molar ratio is possible using tri-reforming of methane (TRM). Despite the number of studies dedicated to the TRM process, this process is still in its infancy, with many technical obstacles to overcome. Except for its kinetics and catalysts, which have been reviewed elsewhere, the TRM process is evaluated thoroughly in this work. First, feasibility studies of TRM and the TRM process are presented. Second, the impacts of various operating conditions on the rate of gas conversions, syngas production, and coke formation are discussed. Third, different reactor configurations are compared. This review then goes through the energy and energetic efficiency, economic, environmental, and safety aspects of the TRM process. Finally, a research path for the future is suggested.
Record ID
Keywords
CO2 emission mitigation, operational conditions, syngas production, tri-reforming of methane
Subject
Suggested Citation
Soleimani S, Lehner M. Tri-Reforming of Methane: Thermodynamics, Operating Conditions, Reactor Technology and Efficiency Evaluation—A Review. (2023). LAPSE:2023.9256
Author Affiliations
Soleimani S: K1-MET GmbH, Stahlstraße 14, 4020 Linz, Austria; Chair of Process Technology and Industrial Environmental Protection, Montanuniversität Leoben, Franz-Josef-Str. 18, A-8700 Leoben, Austria [ORCID]
Lehner M: Chair of Process Technology and Industrial Environmental Protection, Montanuniversität Leoben, Franz-Josef-Str. 18, A-8700 Leoben, Austria
Lehner M: Chair of Process Technology and Industrial Environmental Protection, Montanuniversität Leoben, Franz-Josef-Str. 18, A-8700 Leoben, Austria
Journal Name
Energies
Volume
15
Issue
19
First Page
7159
Year
2022
Publication Date
2022-09-28
ISSN
1996-1073
Version Comments
Original Submission
Other Meta
PII: en15197159, Publication Type: Review
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LAPSE:2023.9256
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https://doi.org/10.3390/en15197159
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Feb 27, 2023
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