Voltage source inverters (VSIs) are an integral part of electrical vehicles (EVs) to enhance the reliability of the supply power to critical loads in vehicle to load (V2L) applications. The inherent properties of sliding mode control (SMC) makes it one of the best available options to achieve the desired voltage quality under variable load conditions. The intrinsic characteristic of robustness associated with SMC is generally achieved at the cost of unwanted chattering along the sliding surface. To manage this compromise better, optimal selection of sliding surface coefficient is applied with the proposed composite exponential reaching law (C-ERL). The novelty of the proposed C-ERL is associated with the intelligent mix of the exponential, power, and difference functions blended with the rotating sliding surface selection (RSS) technique for three phase two level VSI. Moreover, the proposed reaching law along with the power rate exponential reaching law (PRERL), enhanced exponential reaching law (EERL), and repetitive reaching law (RRL) were implemented on two level three phase VSI under variable load conditions. A comparative analysis strongly advocates the authenticity and effectiveness of the proposed reaching law in achieving a well-regulated output voltage with a high level of robustness, reduced chattering, and low %THD.