Unstable combustion phenomena such as flame flashback, flame liftoff, extinction and blowout frequently take place during the operation of the bluff-body stabilized burner. Therefore, flame state monitoring is necessary for the safe operation of the bluff-body stabilized burner. In the present study, an electrical capacitance tomography (ECT) system was deployed to detect the permittivity distribution in the premixing channel and further characterize the flame states of stabilization, flashback, liftoff, extinction and blowout. A calderon-based reconstruction method was modified to reconstruct the permittivity distribution in the annular premixing channel. The detection results indicate that the permittivity in the premixing channel increases steeply when the flame flashback takes place and decreases obviously when the flame lifts off from the combustor rim. Based on the varied permittivity distribution at different flame states, a flame state index was proposed to characterize the flame state in quantification. The flame state index is 0, positive, in the range of −0.64−0, and lower than −0.64 when the flame is at the state of stable, flashback, liftoff and blowout, respectively. The flame state index at the flame state of extinction is the same as that at the flame state of liftoff. The extinction state and the blowout state can be distinguished by judging whether the flame flashback takes place before the flame is extinguished. These results reveal that the ECT system is capable of monitoring the flame state, and that the proposed flame state index can be used to characterize the flame state.