LAPSE:2023.36193
Published Article
LAPSE:2023.36193
Interplay between Thermally Induced Aragonite−Calcite Transformation and Multistep Dehydration in a Seawater Spiral Shell (Euplica scripta)
Taiga Tone, Nobuyoshi Koga
July 4, 2023
While heating a seawater spiral shell (Euplica scripta), thermally induced aragonite−calcite (A−C) transformation occurred within the temperature region of multistep thermal dehydration. Here, the kinetic interplay between the A−C transformation and thermal dehydration was studied as a possible cause of the reduction in the A−C transformation temperatures. The kinetics of the A−C transformation was systematically investigated under isothermal conditions by powder X-ray diffractometry and under linear nonisothermal conditions by Fourier transform infrared spectroscopy. The thermal dehydration was characterized as a partially overlapping, three-step process by thermogravimetry−differential thermal analysis coupled with mass spectroscopy for the evolved gases. The A−C transformation occurred in the temperature range of the final part of the second dehydration step and the initial part of the third dehydration step. The kinetics of A−C transformation and thermal dehydration were characterized by contracting geometry-type models, in which the respective transformations were regulated by a constant linear advancement rate and diffusional removal of water vapor, respectively. Based on the kinetic results, the mutual interaction of those thermally induced processes is discussed as a possible cause of the reduction in the A−C transformation temperature.
Keywords
aragonite–calcite transformation, biomineralized aragonite, kinetics, mechanistic relationship, multistep thermal dehydration
Subject
Suggested Citation
Tone T, Koga N. Interplay between Thermally Induced Aragonite−Calcite Transformation and Multistep Dehydration in a Seawater Spiral Shell (Euplica scripta). (2023). LAPSE:2023.36193
Author Affiliations
Tone T: Department of Science Education, Division of Educational Sciences, Graduate School of Humanities and Social Sciences, Hiroshima University, 1-1-1 Kagamiyama, Higashi-Hiroshima 739-8524, Japan
Koga N: Department of Science Education, Division of Educational Sciences, Graduate School of Humanities and Social Sciences, Hiroshima University, 1-1-1 Kagamiyama, Higashi-Hiroshima 739-8524, Japan [ORCID]
Journal Name
Processes
Volume
11
Issue
6
First Page
1650
Year
2023
Publication Date
2023-05-29
Published Version
ISSN
2227-9717
Version Comments
Original Submission
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PII: pr11061650, Publication Type: Journal Article
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LAPSE:2023.36193
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doi:10.3390/pr11061650
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Jul 4, 2023
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CC BY 4.0
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Jul 4, 2023
 
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Calvin Tsay
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