In order to determine a way to be able to shorten the smelting time of low-carbon ferrochrome alloys and to strengthen the temperature control capability of the AOD converter during the smelting process, this article establishes a mechanism model of the rate of oxygen supply and carbon content change in the smelting process as well as the temperature of the reaction fluid in the converter. The physical and chemical reactions of the smelting process and the actual smelting data are used as the basis. The temperature and carbon content in the smelting converter are considered as the output quantity and the rate of oxygen supply is considered as the input quantity. An expert internal model control framework is built. In addition, an adaptive parameter adjustment mechanism is added to the control framework, taking into account data such as the maximum gas supply rate and the maximum limiting temperature of the actual production process. This method improves the smelting speed and smelting accuracy compared to the general internal mode control method. Finally, according to this method, with the use of the built low-carbon ferrochrome alloy centralized control system for smelting, the system shortens the smelting time by 12.79% compared with the general method and controls the converter temperature below 1950 K, which achieves the expected goal according to the simulation and actual smelting results.