LAPSE:2023.35765
Published Article
LAPSE:2023.35765
Numerical Modeling and Simulation of the Solid Oxide Cell Stacks and Metal Interconnect Oxidation with OpenFOAM
May 23, 2023
Solid oxide cells are capable of efficiently converting various chemical energy carriers to electricity and vice versa. The urgent challenge nowadays is the faster degradation rate compared with other fuel cell/electrolyzer technologies. To understand the degradation mechanisms, simulation of a solid oxide cell is helpful. Since most previous research developed models using commercial software, such as COMSOL and ANSYS Fluent, a gap for knowledge transfer is being gradually formed between academia and industry due to licensing issues. This paper introduces a multiphysics model, developed by a computational code, openFuelCell2. The code is implemented with an open-source library, OpenFOAM. It accounts for momentum transfer, mass transfer, electrochemical reactions and metal interconnect oxidation. The model can precisely predict I−V curves under different temperatures, fuel humidity and operation modes. Comparison between OpenFOAM and COMSOL simulations shows good agreement. The metal interconnect oxidation is modeled, which can predict the thickness of the oxide scale under different protective coatings. Simulations are conducted by assuming an ultra-thin film resistance on the rib surface. It is revealed that coatings fabricated by atmospheric plasma spraying can efficiently prevent metal interconnect oxidation, with a contribution of only 0.53 % to the total degradation rate.
Keywords
metal interconnect oxidation, multiphysics modeling, OpenFOAM, openFuelCell2, solid oxide cell
Suggested Citation
Yu S, Zhang S, Schäfer D, Peters R, Kunz F, Eichel RA. Numerical Modeling and Simulation of the Solid Oxide Cell Stacks and Metal Interconnect Oxidation with OpenFOAM. (2023). LAPSE:2023.35765
Author Affiliations
Yu S: Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich GmbH, D-52425 Jülich, Germany; Institute of Physical Chemistry, RWTH Aachen University, D-52074 Aachen, Germany [ORCID]
Zhang S: Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich GmbH, D-52425 Jülich, Germany [ORCID]
Schäfer D: Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich GmbH, D-52425 Jülich, Germany [ORCID]
Peters R: Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich GmbH, D-52425 Jülich, Germany [ORCID]
Kunz F: Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich GmbH, D-52425 Jülich, Germany [ORCID]
Eichel RA: Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich GmbH, D-52425 Jülich, Germany; Institute of Physical Chemistry, RWTH Aachen University, D-52074 Aachen, Germany [ORCID]
Journal Name
Energies
Volume
16
Issue
9
First Page
3827
Year
2023
Publication Date
2023-04-29
Published Version
ISSN
1996-1073
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Original Submission
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PII: en16093827, Publication Type: Journal Article
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LAPSE:2023.35765
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doi:10.3390/en16093827
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May 23, 2023
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CC BY 4.0
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May 23, 2023
 
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May 23, 2023
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Original Submitter
Calvin Tsay
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