LAPSE:2023.35207
Published Article
LAPSE:2023.35207
Extension of the Equilibrium Stage Model to Include Rigorous Liquid Holdup Calculations for Reactive Distillation
Lionel Noll, Louis van der Ham, Stijn Oudenhoven, Antoon ten Kate, Gerrald Bargeman, Sascha Kersten
April 28, 2023
An extension of the equilibrium stage model to improve its applicability to reactive distillation is presented. The significant aeration of the liquid holdup on trays leads to the amount of clear liquid present being significantly less than the volume available. Tray hydraulic correlations are incorporated by leveraging the existing inside-out algorithm to rigorously calculate the liquid holdup on distillation trays, turning this parameter into an additional model output and eliminating the need to estimate this parameter beforehand. Application of this extended model shows that the aeration of the liquid holdup cannot be neglected for systems where the reaction kinetics limit the reactive productivity, and leads to column designs where additional reactive trays are needed to provide adequate reactive capacity. The workflow of this model provides a more robust path to obtaining reactive distillation column and tray designs that comply with liquid holdup requirements and tray hydraulic limitations.
Keywords
liquid holdup modelling, Reactive Distillation, reactive tray design
Suggested Citation
Noll L, van der Ham L, Oudenhoven S, ten Kate A, Bargeman G, Kersten S. Extension of the Equilibrium Stage Model to Include Rigorous Liquid Holdup Calculations for Reactive Distillation. (2023). LAPSE:2023.35207
Author Affiliations
Noll L: Sustainable Process Technology Group, Process and Catalysis Engineering Cluster, Faculty of Science and Technology, University of Twente, Drienerlolaan 5, 7522 NB Enschede, The Netherlands [ORCID]
van der Ham L: Sustainable Process Technology Group, Process and Catalysis Engineering Cluster, Faculty of Science and Technology, University of Twente, Drienerlolaan 5, 7522 NB Enschede, The Netherlands
Oudenhoven S: Nouryon, Zutphenseweg 10, 7418 AJ Deventer, The Netherlands
ten Kate A: Nouryon, Zutphenseweg 10, 7418 AJ Deventer, The Netherlands [ORCID]
Bargeman G: Nobian, Zutphenseweg 10, 7418 AJ Deventer, The Netherlands; Membrane Science and Technology Cluster, Faculty of Science and Technology, University of Twente, Drienerlolaan 5, 7522 NB Enschede, The Netherlands
Kersten S: Sustainable Process Technology Group, Process and Catalysis Engineering Cluster, Faculty of Science and Technology, University of Twente, Drienerlolaan 5, 7522 NB Enschede, The Netherlands
Journal Name
Processes
Volume
11
Issue
4
First Page
1131
Year
2023
Publication Date
2023-04-06
Published Version
ISSN
2227-9717
Version Comments
Original Submission
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PII: pr11041131, Publication Type: Journal Article
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LAPSE:2023.35207
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doi:10.3390/pr11041131
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Apr 28, 2023
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CC BY 4.0
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