Degraded lands are potential areas for obtaining biomass which can serve as an energy source after its conversion into biogas. Thus, the studies on biogas production from maize and cocksfoot biomasses obtained from degraded soil supplemented with additions of new zeolite substrate (Z-ion as the nutrient carrier) and on arable soil (reference soil) were carried out during batch digestion tests. It was found that the biogas and biomethane potentials and specific energy of the test species growing in degraded soil enriched with Z-ion additions (1% and 5% v/v in the cases of cocksfoot and maize, respectively) did not differ significantly from the values of these parameters that were found for the plants growing in arable soil. The application of Z-ion to the degraded soil (especially in a dose of 5% v/v) resulted in an increase in the nitrogen content and decrease (below the lower optimum value) in the C/N ratio in the plant biomass. However, these changes did not negatively influence the final values of the biogas or methane potentials or the specific energy found for the maize biomass. Therefore, the study results indicated the usefulness of Z-ion substrate for improving the growth conditions for energy crops in degraded soils and, as a consequence, obtaining a plant feedstock suitable for the digestion process.