The interconnection between optimal control theory and the theory of energy-shaping control is described in our paper. For linear and nonlinear systems, the application of the theory of optimal control for the synthesis of parameters of energy-shaping control matrices is demonstrated in detail. The use of a Riccati equation allows us to form an optimality criterion and to synthesize the energy-shaping control system that provides the desired transient processes. The proposed approach was applied to the synthesis of control influences for electric vehicle subsystems, such as a two-mass system and a permanent magnets synchronous motor. The results of computer simulation studies, as well as those conducted on real experimental installations, are given in this paper.