The paper presents the combustion profile of selected fuels as a result of thermogravimetric analysis. The main purpose of this study was to investigate a mixture of different types of fuel and the influence of the use of a fuel additive on the combustion process profile. As a fuel additive, halloysite was used to investigate the thermogravimetric profiles. It was confirmed that the main combustion parameters such as ignition temperature, burnout temperature, and maximum peak temperature correlated accordingly with different combustibility indices such as the ignition index, the burnout index, and the combustion indices. Furthermore, the present study provided a comparison of selected methods for analyzing non-isothermal solid-state kinetic data and investigated the kinetics of thermal decomposition to describe the ongoing process. Two non-isothermal model methods (Kissinger and Ozawa) were used to calculate the Arrhenius parameters. The effect of heating rate and the addition of halloysite as a fuel additive on decomposition were studied.