LAPSE:2023.31417
Published Article

LAPSE:2023.31417
Aspects Regarding the Modelling and Optimization of the Transesterification Process through Temperature Control of the Chemical Reactor
April 18, 2023
Abstract
Currently, biofuels represent a solution for the European Union in the transportation sector in order to reduce the greenhouse gas (GHG) emissions and the dependency of fossil fuels. Biodiesel from vegetable oils is a solution for countries with low GDP per capita to strengthen the internal agriculture, provide jobs, and reduce the use of fossil fuels. In this study, we model and simulate a temperature regulator designed for the biodiesel transesterification process in a discontinuous batch reactor, using methanol and a homogenous basic catalyst. The simulation was based on the kinetical model of the transesterification reaction and the mathematical model of the reactor. We considered molar ratios of alcohol/oil of 6:1 and 9:1, respectively, to shift the reaction equilibrium towards the production of fatty acid methyl esters. In the design of the simulation, the methanol boiling point was considered a restriction, therefore, temperatures below 65 °C were imposed. The results demonstrate that the increase in temperature results in a decrease in the reaction time and a higher yield, especially for the 6:1 molar ratio reaction, and that the optimum temperature for the batch reactor is of 60 °C. Automatic control improves the performance and costs of production.
Currently, biofuels represent a solution for the European Union in the transportation sector in order to reduce the greenhouse gas (GHG) emissions and the dependency of fossil fuels. Biodiesel from vegetable oils is a solution for countries with low GDP per capita to strengthen the internal agriculture, provide jobs, and reduce the use of fossil fuels. In this study, we model and simulate a temperature regulator designed for the biodiesel transesterification process in a discontinuous batch reactor, using methanol and a homogenous basic catalyst. The simulation was based on the kinetical model of the transesterification reaction and the mathematical model of the reactor. We considered molar ratios of alcohol/oil of 6:1 and 9:1, respectively, to shift the reaction equilibrium towards the production of fatty acid methyl esters. In the design of the simulation, the methanol boiling point was considered a restriction, therefore, temperatures below 65 °C were imposed. The results demonstrate that the increase in temperature results in a decrease in the reaction time and a higher yield, especially for the 6:1 molar ratio reaction, and that the optimum temperature for the batch reactor is of 60 °C. Automatic control improves the performance and costs of production.
Record ID
Keywords
biofuel, reactor, temperature control, transesterification
Subject
Suggested Citation
Stanescu RC, Leahu CI, Soica A. Aspects Regarding the Modelling and Optimization of the Transesterification Process through Temperature Control of the Chemical Reactor. (2023). LAPSE:2023.31417
Author Affiliations
Stanescu RC: Department of Automotive and Transport Engineering, Transilvania University of Brasov, 500036 Brasov, Romania [ORCID]
Leahu CI: Department of Automotive and Transport Engineering, Transilvania University of Brasov, 500036 Brasov, Romania [ORCID]
Soica A: Department of Automotive and Transport Engineering, Transilvania University of Brasov, 500036 Brasov, Romania
Leahu CI: Department of Automotive and Transport Engineering, Transilvania University of Brasov, 500036 Brasov, Romania [ORCID]
Soica A: Department of Automotive and Transport Engineering, Transilvania University of Brasov, 500036 Brasov, Romania
Journal Name
Energies
Volume
16
Issue
6
First Page
2883
Year
2023
Publication Date
2023-03-21
ISSN
1996-1073
Version Comments
Original Submission
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PII: en16062883, Publication Type: Journal Article
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LAPSE:2023.31417
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https://doi.org/10.3390/en16062883
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Apr 18, 2023
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