As the electric vehicle (EV) market continues to grow, wireless charging technologies are constantly evolving. Considering the limitations of traditional charging methods, the adoption of wireless charging technology is an essential strategy, and the distribution of wireless charging systems is expected to accelerate in the global market with initiatives such as international standards for wireless charging systems. With regard to this technological trend, this study experimentally analyzed the effects of the boost coil and the alignment of the transmitting and receiving coils on the transmission efficiency in wireless power transfer systems. The boost coil amplifies the magnetic field using a high-frequency signal and transfers the field to the receiving coil. Moreover, simulations were conducted based on the theory that using the boost coil could increase the efficiency of wireless power transfer, and the impact of the alignment between the transmitting and receiving coils on the transmission efficiency was also analyzed.