PSE Community.org

LAPSE:2023.2974

Surface Hydrophobic Modification of Biochar by Silane Coupling Agent KH-570

Muxi Zhang, Hongxiang Zhu, Beidou Xi, Yuxin Tian, Xiaojie Sun, Hongxia Zhang, Beibei Wu

February 21, 2023

Abstract
Biochar-amended soil cover (BSC) in landfills can improve the oxidation of methane. However, adding biochar can cause a larger amount of rainwater to enter the soil cover and landfill because it increases the permeability of the soil cover, which increases leachate production. Improving the hydrophobicity and waterproof ability of BSC is expected to reduce rainwater that goes into landfills. Silane coupling agent KH-570 is used to modify biochar to improve its hydrophobicity and waterproof ability after being added to the soil cover. The waterproofness of hydrophobic biochar-amended soil cover (HBSC) was studied by conducting a precipitation simulation test. Results showed that the optimum hydrophobicity of the surface-modified biochar was obtained when the mass fraction of KH-570 was 7%, the biochar dosage was 7 g, and the modification temperature was 60 °C. In these conditions, the contact angle was 143.99° and the moisture absorption rate was 0.10%. The analysis results of thermogravimetric, X-ray diffractometer and scanning electron microscopy before and after the biochar modification showed that KH-570 formed a hydrophobic organic coating layer on the biochar surface, indicating that the surface hydrophobic modification of biochar was successfully carried out by silane coupling agent. The waterproof ability of HBSC was significantly better than that of BSC in the simulated precipitation test.

Record ID

LAPSE:2023.2974

Keywords

biochar, hydrophobic modification, landfill cover, silane coupling agents

Subject

Modelling and Simulations

Suggested Citation

Zhang M, Zhu H, Xi B, Tian Y, Sun X, Zhang H, Wu B. Surface Hydrophobic Modification of Biochar by Silane Coupling Agent KH-570. (2023). LAPSE:2023.2974

Author Affiliations

Zhang M: Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology, Guilin University of Technology, Guilin 541004, China; Guangxi Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area, Guilin University o
Zhu H: College of Light Industry and Food Engineering, Guangxi University, Nanning 530004, China
Xi B: Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology, Guilin University of Technology, Guilin 541004, China; Guangxi Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area, Guilin University o
Tian Y: Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology, Guilin University of Technology, Guilin 541004, China; Guangxi Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area, Guilin University o
Sun X: Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology, Guilin University of Technology, Guilin 541004, China; Guangxi Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area, Guilin University o
Zhang H: Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology, Guilin University of Technology, Guilin 541004, China; Guangxi Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area, Guilin University o
Wu B: Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology, Guilin University of Technology, Guilin 541004, China; Guangxi Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area, Guilin University o

Journal Name

Processes

Volume

Issue

First Page

301

Year

2022

Publication Date

2022-02-02

DOI:

https://doi.org/10.3390/pr10020301