This paper proposes a novel model-free super-twisting nonlinear sliding mode control (MFSTNLSMC) strategy with an improved smoothing extended state observer (SESO) for permanent magnet synchronous motor (PMSM) drives. First of all, the improved SESO is introduced to estimate the unknown term of the PMSM ultra-local model. Secondly, a novel nonlinear sliding mode surface (NLSMS) is designed, which can effectively overcome the disadvantages of simple and rough signal processing of the conventional linear sliding mode surface. At the same time, a super-twisting (ST) structure is chosen to suppress the chattering phenomenon and improve system robustness. Then, the Lyapunov stability theorem is used to prove the stability of the proposed control algorithm. Finally, both comparative simulations and experimental demonstrations verify the excellent speed tracking performance and robustness of the proposed control strategy.