LAPSE:2023.25754
Published Article
LAPSE:2023.25754
2D Simulation for CH4 Internal Reforming-SOFCs: An Approach to Study Performance Degradation and Optimization
Emilio Audasso, Fiammetta Rita Bianchi, Barbara Bosio
March 29, 2023
Solid oxide fuel cells (SOFCs) are a well-developed technology, mainly used for combined heat and power production. High operating temperatures and anodic Ni-based materials allow for direct reforming reactions of CH4 and other light hydrocarbons inside the cell. This feature favors a wider use of SOFCs that otherwise would be limited by the absence of a proper H2 distribution network. This also permits the simplification of plant design avoiding additional units for upstream syngas production. In this context, control and knowledge of how variables such as temperature and gas composition are distributed on the cell surface are important to ensure good long-lasting performance. The aim of this work is to present a 2D modeling tool able to simulate SOFC performance working with direct internal CH4 reforming. Initially thermodynamic and kinetic approaches are compared in order to tune the model assuming a biogas as feed. Thanks to the introduction of a matrix of coefficients to represent the local distribution of reforming active sites, the model considers degradation/poisoning phenomena. The same approach is also used to identify an optimized catalyst distribution that allows reducing critical working conditions in terms of temperature gradient, thus facilitating long-term applications.
Keywords
2D local control, active site degradation, cell design optimization, CH4 internal reforming, solid oxide fuel cell
Suggested Citation
Audasso E, Bianchi FR, Bosio B. 2D Simulation for CH4 Internal Reforming-SOFCs: An Approach to Study Performance Degradation and Optimization. (2023). LAPSE:2023.25754
Author Affiliations
Audasso E: Department of Civil, Chemical and Environmental Engineering, University of Genova, Via Opera Pia 15, 16145 Genova, Italy
Bianchi FR: Department of Civil, Chemical and Environmental Engineering, University of Genova, Via Opera Pia 15, 16145 Genova, Italy
Bosio B: Department of Civil, Chemical and Environmental Engineering, University of Genova, Via Opera Pia 15, 16145 Genova, Italy
Journal Name
Energies
Volume
13
Issue
16
Article Number
E4116
Year
2020
Publication Date
2020-08-09
Published Version
ISSN
1996-1073
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Original Submission
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PII: en13164116, Publication Type: Journal Article
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LAPSE:2023.25754
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doi:10.3390/en13164116
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