LAPSE:2023.24571
Published Article
LAPSE:2023.24571
Improved Electrical and Structural Stability in HTL-Free Perovskite Solar Cells by Vacuum Curing Treatment
Salvatore Valastro, Emanuele Smecca, Salvatore Sanzaro, Filippo Giannazzo, Ioannis Deretzis, Antonino La Magna, Youhei Numata, Ajay Kumar Jena, Tsutomu Miyasaka, Antonio Gagliano, Alessandra Alberti
March 28, 2023
Device engineering with proper material integration into perovskite solar cells (PSCs) would extend their durability provided a special care is spent to retain interface integrity during use. In this paper, we propose a method to preserve the perovskite (PSK) surface from solvent-mediated modification and damage that can occur during the deposition of a top contact and furtherly during operation. Our scheme used a hole transporting layer-free top-contact made of Carbon (mostly graphite) to the side of hole extraction. We demonstrated that the PSK/graphite interface benefits from applying a vacuum-curing step after contact deposition that allowed mitigating the loss in efficiency of the solar devices, as well as a full recovery of the electrical performances after device storage in dry nitrogen and dark conditions. The device durability compared to reference devices was tested over 90 days. Conductive atomic force microscopy (CAFM) disclosed an improved surface capability to hole exchange under the graphite contact after vacuum curing treatment.
Keywords
CAFM, durability, I-V (current -voltage) curve, interfaces, perovskite, photovoltaics, recovery, stability, storage, vacuum treatment, X-ray diffraction (XRD)
Suggested Citation
Valastro S, Smecca E, Sanzaro S, Giannazzo F, Deretzis I, La Magna A, Numata Y, Jena AK, Miyasaka T, Gagliano A, Alberti A. Improved Electrical and Structural Stability in HTL-Free Perovskite Solar Cells by Vacuum Curing Treatment. (2023). LAPSE:2023.24571
Author Affiliations
Valastro S: CNR-IMM, 95121 Catania, Italy; Department of Electrical, Electronic and Computer Engineering, University of Catania, 95125 Catania, Italy [ORCID]
Smecca E: CNR-IMM, 95121 Catania, Italy
Sanzaro S: CNR-IMM, 95121 Catania, Italy
Giannazzo F: CNR-IMM, 95121 Catania, Italy [ORCID]
Deretzis I: CNR-IMM, 95121 Catania, Italy
La Magna A: CNR-IMM, 95121 Catania, Italy
Numata Y: Graduate School of Engineering, Toin University of Yokohama, Yokohama, Kanagawa 225-8503, Japan
Jena AK: Graduate School of Engineering, Toin University of Yokohama, Yokohama, Kanagawa 225-8503, Japan
Miyasaka T: Graduate School of Engineering, Toin University of Yokohama, Yokohama, Kanagawa 225-8503, Japan
Gagliano A: Department of Electrical, Electronic and Computer Engineering, University of Catania, 95125 Catania, Italy
Alberti A: CNR-IMM, 95121 Catania, Italy
Journal Name
Energies
Volume
13
Issue
15
Article Number
E3953
Year
2020
Publication Date
2020-08-01
Published Version
ISSN
1996-1073
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PII: en13153953, Publication Type: Journal Article
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LAPSE:2023.24571
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doi:10.3390/en13153953
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Mar 28, 2023
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