LAPSE:2023.24192
Published Article
LAPSE:2023.24192
Heterogeneous Catalysis in (Bio)Ethanol Conversion to Chemicals and Fuels: Thermodynamics, Catalysis, Reaction Paths, Mechanisms and Product Selectivities
March 27, 2023
In gas/solid conditions, different chemicals, such as diethylether, ethylene, butadiene, higher hydrocarbons, acetaldehyde, acetone and hydrogen, can be produced from ethanol with heterogeneous catalytic processes. The focus of this paper is the interplay of different reaction paths, which depend on thermodynamic factors as well as on kinetic factors, thus mainly from catalyst functionalities and reaction temperatures. Strategies for selectivity improvements in heterogeneously catalyzed processes converting (bio)ethanol into renewable chemicals and biofuels are also considered.
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Garbarino G, Pampararo G, Phung TK, Riani P, Busca G. Heterogeneous Catalysis in (Bio)Ethanol Conversion to Chemicals and Fuels: Thermodynamics, Catalysis, Reaction Paths, Mechanisms and Product Selectivities. (2023). LAPSE:2023.24192
Author Affiliations
Garbarino G: Department of Civil, Chemical and Environmental Engineering, Chemical Engineering Pole, University of Genoa, via Opera Pia 15, I-16145 Genoa, Italy; National Interuniversity Consortium of Materials Science and Technology, University of Genoa Research Unit
Pampararo G: Department of Chemistry and Industrial Chemistry, University of Genoa, via Dodecaneso 31, I-16146 Genoa, Italy
Phung TK: Department of Chemical Engineering, School of Biotechnology, International University, Ho Chi Minh City, Vietnam; Vietnam National University, Ho Chi Minh City, Vietnam [ORCID]
Riani P: National Interuniversity Consortium of Materials Science and Technology, University of Genoa Research Unit, University of Genoa, via Dodecaneso 31, I-16146 Genoa, Italy; Department of Pharmacy, University of Genoa, viale Cembrano, I-16148 Genoa, Italy [ORCID]
Busca G: Department of Civil, Chemical and Environmental Engineering, Chemical Engineering Pole, University of Genoa, via Opera Pia 15, I-16145 Genoa, Italy; National Interuniversity Consortium of Materials Science and Technology, University of Genoa Research Unit [ORCID]
Pampararo G: Department of Chemistry and Industrial Chemistry, University of Genoa, via Dodecaneso 31, I-16146 Genoa, Italy
Phung TK: Department of Chemical Engineering, School of Biotechnology, International University, Ho Chi Minh City, Vietnam; Vietnam National University, Ho Chi Minh City, Vietnam [ORCID]
Riani P: National Interuniversity Consortium of Materials Science and Technology, University of Genoa Research Unit, University of Genoa, via Dodecaneso 31, I-16146 Genoa, Italy; Department of Pharmacy, University of Genoa, viale Cembrano, I-16148 Genoa, Italy [ORCID]
Busca G: Department of Civil, Chemical and Environmental Engineering, Chemical Engineering Pole, University of Genoa, via Opera Pia 15, I-16145 Genoa, Italy; National Interuniversity Consortium of Materials Science and Technology, University of Genoa Research Unit [ORCID]
Journal Name
Energies
Volume
13
Issue
14
Article Number
E3587
Year
2020
Publication Date
2020-07-11
Published Version
ISSN
1996-1073
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PII: en13143587, Publication Type: Journal Article
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LAPSE:2023.24192
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doi:10.3390/en13143587
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Mar 27, 2023
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