LAPSE:2023.15215v1
Published Article

LAPSE:2023.15215v1
Properties of Animal-Origin Ash—A Valuable Material for Circular Economy
March 2, 2023
Abstract
In the presented paper, two types of animal-origin biomass, cow dung and chicken litter, are characterized in terms of combustion-related problems and ash properties. It was found that these parameters strongly depend on the farming style. Whether it is cow dung or chicken litter, free-range raw materials are characterized by higher ash contents than industrial farming ones. Free-range samples contain chlorine at lower levels, while industrial farming samples are chlorine rich. Free-range samples are characterized by the predominant content of silica in the ash: 75.60% in cow dung and 57.11% in chicken litter, while industrial farming samples contain more calcium. Samples were classified by 11 “slagging indices” based on the ash and fuel composition to evaluate their tendencies for slagging, fouling, ash deposition and bed agglomeration. Furthermore, an assessment was made against the current EU law regulations, whether the ashes can be component materials for fertilizers. The phosphorus concentration in the investigated ashes corresponds to 4.09−23.73 wt% P2O5 and is significantly higher in industrial chicken litter samples. The concentrations of Hg, Cu, As, Ni, Cd and Pb in all samples are below the limits of the UE regulations. However, concentrations of Cr in all samples and Zn in industrial chicken litter exceed these standards.
In the presented paper, two types of animal-origin biomass, cow dung and chicken litter, are characterized in terms of combustion-related problems and ash properties. It was found that these parameters strongly depend on the farming style. Whether it is cow dung or chicken litter, free-range raw materials are characterized by higher ash contents than industrial farming ones. Free-range samples contain chlorine at lower levels, while industrial farming samples are chlorine rich. Free-range samples are characterized by the predominant content of silica in the ash: 75.60% in cow dung and 57.11% in chicken litter, while industrial farming samples contain more calcium. Samples were classified by 11 “slagging indices” based on the ash and fuel composition to evaluate their tendencies for slagging, fouling, ash deposition and bed agglomeration. Furthermore, an assessment was made against the current EU law regulations, whether the ashes can be component materials for fertilizers. The phosphorus concentration in the investigated ashes corresponds to 4.09−23.73 wt% P2O5 and is significantly higher in industrial chicken litter samples. The concentrations of Hg, Cu, As, Ni, Cd and Pb in all samples are below the limits of the UE regulations. However, concentrations of Cr in all samples and Zn in industrial chicken litter exceed these standards.
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Keywords
animal-origin biomass, ash characterization, Biomass, biomass ash, chicken litter, chlorine corrosion, cow manure, SEM, slagging
Subject
Suggested Citation
Maj I, Kalisz S, Ciukaj S. Properties of Animal-Origin Ash—A Valuable Material for Circular Economy. (2023). LAPSE:2023.15215v1
Author Affiliations
Maj I: Department of Power Engineering and Turbomachinery, Faculty of Energy and Environmental Engineering, Silesian University of Technology, 44-100 Gliwice, Poland [ORCID]
Kalisz S: Department of Power Engineering and Turbomachinery, Faculty of Energy and Environmental Engineering, Silesian University of Technology, 44-100 Gliwice, Poland [ORCID]
Ciukaj S: Department of Power Engineering and Turbomachinery, Faculty of Energy and Environmental Engineering, Silesian University of Technology, 44-100 Gliwice, Poland [ORCID]
Kalisz S: Department of Power Engineering and Turbomachinery, Faculty of Energy and Environmental Engineering, Silesian University of Technology, 44-100 Gliwice, Poland [ORCID]
Ciukaj S: Department of Power Engineering and Turbomachinery, Faculty of Energy and Environmental Engineering, Silesian University of Technology, 44-100 Gliwice, Poland [ORCID]
Journal Name
Energies
Volume
15
Issue
4
First Page
1274
Year
2022
Publication Date
2022-02-10
ISSN
1996-1073
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Original Submission
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PII: en15041274, Publication Type: Journal Article
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LAPSE:2023.15215v1
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https://doi.org/10.3390/en15041274
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