Industry 5.0 presents itself as a strategy that puts the human factor at the centre of production, where the well-being of the worker is prioritized, as well as more sustainable and resilient production systems. For human centricity, it is necessary to empower human beings and, respectively, industrial operators, to improve their individual skills and competences in collaboration or cooperation with digital technologies. This research’s main purpose and distinguishing point are to determine whether Industry 5.0 is truly human-oriented and how human centricity can be created with Industry 5.0 technologies. For that, this systematic literature review article analyses and clarifies the concepts and ideologies of Industry 5.0 and its respective technologies (Artificial Intelligence, Robotics, Human-robot collaboration, Digitalization), as well as the strategies of human centricity, with the aim of achieving sustainable and resilient systems, especially for the worker.