LAPSE:2019.1149
Published Article
LAPSE:2019.1149
Valorization of Swine Manure into Hydrochars
Zac Lentz, Praveen Kolar, John J. Classen
November 24, 2019
There is a significant interest in valorizing swine manure that is produced in enormous quantities. Therefore, considering the high moisture content in swine manure, the objective of this research was to convert manure slurry into hydrochars via hydrothermal carbonization and analyze the yields, pH, energy contents, and thermal and oxidation kinetic parameters. Experiments were performed in triplicate in 250 mL kettle reactors lined with polypropylene at 180 °C, 200 °C, 240 °C, 220 °C, and 260 °C for 24 h. Analyses of the results indicated that the process temperature affected the hydrochar yields, with yield generally decreasing with increasing temperature, but it had little effect on the composition of the hydrochar. The hydrochars were found to have higher volatile contents and H/C and O/C ratios and about 85% of the energy compared to coal. However, the presence of high fraction (35−38%) of ash in hydrochars is a serious concern and needs to be addressed before the complete utilization of hydrochars as fuels. The surface characterization of hydrochars coupled with wet chemistry experiments indicated that hydrochars were equipped with nitrogen functional groups with points of zero charges between 6.76 and 7.85, making them suitable as adsorbents and soil remediation agents and energy storage devices.
Keywords
char, characterization, hydrothermal carbonization, swine manure, valorization
Subject
Suggested Citation
Lentz Z, Kolar P, Classen JJ. Valorization of Swine Manure into Hydrochars. (2019). LAPSE:2019.1149
Author Affiliations
Lentz Z: Biological and Agricultural Engineering, Campus Box 7625, North Carolina State University, Raleigh, NC 27695-7625, USA
Kolar P: Biological and Agricultural Engineering, Campus Box 7625, North Carolina State University, Raleigh, NC 27695-7625, USA
Classen JJ: Biological and Agricultural Engineering, Campus Box 7625, North Carolina State University, Raleigh, NC 27695-7625, USA
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Journal Name
Processes
Volume
7
Issue
9
Article Number
E560
Year
2019
Publication Date
2019-08-23
Published Version
ISSN
2227-9717
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Original Submission
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PII: pr7090560, Publication Type: Journal Article
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LAPSE:2019.1149
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doi:10.3390/pr7090560
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Nov 24, 2019
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CC BY 4.0
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Nov 24, 2019
 
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Original Submitter
Calvin Tsay
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