LAPSE:2023.24122
Published Article
LAPSE:2023.24122
Halide Pb-Free Double−Perovskites: Ternary vs. Quaternary Stoichiometry
March 27, 2023
Abstract
In view of their applicability in optoelectronics, we review here the relevant structural, electronic, and optical features of the inorganic Pb-free halide perovskite class. In particular, after discussing the reasons that have motivated their introduction in opposition to their more widely investigated organic-inorganic counterparts, we highlight milestones already achieved in their synthesis and characterization and show how the use of ab initio ground and excited state methods is relevant in predicting their properties and in disclosing yet unsolved issues which characterize both ternary and quaternary stoichiometry double-perovskites.
In view of their applicability in optoelectronics, we review here the relevant structural, electronic, and optical features of the inorganic Pb-free halide perovskite class. In particular, after discussing the reasons that have motivated their introduction in opposition to their more widely investigated organic-inorganic counterparts, we highlight milestones already achieved in their synthesis and characterization and show how the use of ab initio ground and excited state methods is relevant in predicting their properties and in disclosing yet unsolved issues which characterize both ternary and quaternary stoichiometry double-perovskites.
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Keywords
ab-initio ground and excited state analysis, lead-free inorganic halide perovskites, optoelectronic applications, photovoltaics
Subject
Suggested Citation
Palummo M, Varsano D, Berríos E, Yamashita K, Giorgi G. Halide Pb-Free Double−Perovskites: Ternary vs. Quaternary Stoichiometry. (2023). LAPSE:2023.24122
Author Affiliations
Palummo M: Dipartimento di Fisica and INFN, Universitá di Roma “Tor Vergata”, Via della Ricerca Scientifica 1, 00133 Roma, Italy [ORCID]
Varsano D: Centro S3, Istituto Nanoscienze-Consiglio Nazionale delle Ricerche (CNR-NANO), Via Campi 213/A, 41125 Modena, Italy [ORCID]
Berríos E: Instituto de Química y Bioquímica, Facultad de Ciencias, Universidad de Valparaíso, Avenida Gran Bretaña, 1111 Playa Ancha, Valparaíso 2360102, Chile
Yamashita K: Element Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, Nishikyo-ku, Kyoto 615-8245, Japan
Giorgi G: Department of Civil and Environmental Engineering, University of Perugia (DICA), Via G. Duranti, 93, 06125 Perugia, Italy; CNR-SCITEC, 06123 Perugia, Italy [ORCID]
Varsano D: Centro S3, Istituto Nanoscienze-Consiglio Nazionale delle Ricerche (CNR-NANO), Via Campi 213/A, 41125 Modena, Italy [ORCID]
Berríos E: Instituto de Química y Bioquímica, Facultad de Ciencias, Universidad de Valparaíso, Avenida Gran Bretaña, 1111 Playa Ancha, Valparaíso 2360102, Chile
Yamashita K: Element Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, Nishikyo-ku, Kyoto 615-8245, Japan
Giorgi G: Department of Civil and Environmental Engineering, University of Perugia (DICA), Via G. Duranti, 93, 06125 Perugia, Italy; CNR-SCITEC, 06123 Perugia, Italy [ORCID]
Journal Name
Energies
Volume
13
Issue
14
Article Number
E3516
Year
2020
Publication Date
2020-07-08
ISSN
1996-1073
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Original Submission
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PII: en13143516, Publication Type: Review
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LAPSE:2023.24122
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https://doi.org/10.3390/en13143516
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Mar 27, 2023
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