LAPSE:2024.1296
Published Article
LAPSE:2024.1296
Transition Metal Complexes with Amino Acids, Peptides and Carbohydrates in Catalytic Asymmetric Synthesis: A Short Review
June 21, 2024
The present review is devoted to the application of transition metal complexes with such ligands as amino acids, peptides and carbohydrates in catalysis. The literature published over the past 20 years is surveyed. Among the distinctive features of these ligands are their versatility, optical activity, stability and availability. Furthermore, depending on the specific synthetic task to be solved, these ligands open up almost infinite opportunity for modification. Largely thanks to their multifaceted reactivity, transition metal complexes with amino acids, peptides and carbohydrates can catalyze most of the known chemical reactions affording optically pure compounds. In this review, the emphasis is placed upon C(sp3)−H activation, cross-coupling and hydrogenation (including traditional hydrogenation in the presence of hydrogen gas and hydrogenation with hydrogen transfer) reactions. The choice is not accidental, since these reactions on the one hand display the catalytic versatility of the above complexes, and on the other hand, they are widely employed in industry.
Keywords
amino acid, asymmetric synthesis, carbohydrate, Catalysis, ligand, modified, organic catalytic synthesis, transition metal complex
Subject
Suggested Citation
Titova Y. Transition Metal Complexes with Amino Acids, Peptides and Carbohydrates in Catalytic Asymmetric Synthesis: A Short Review. (2024). LAPSE:2024.1296
Author Affiliations
Titova Y: A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of Russian Academy of Sciences, 1 Favorsky Street, 664033 Irkutsk, Russia [ORCID]
Journal Name
Processes
Volume
12
Issue
1
First Page
214
Year
2024
Publication Date
2024-01-18
Published Version
ISSN
2227-9717
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Original Submission
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PII: pr12010214, Publication Type: Review
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LAPSE:2024.1296
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doi:10.3390/pr12010214
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Jun 21, 2024
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Jun 21, 2024
 
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